Expert systems modeling for assessing climate change impacts and adaptation in agricultural systems at regional level

Australian agriculture is very susceptible to the adverse impacts of climate change, with major shifts in temperature and rainfall projected. In this context, this paper describes a research methodology for assessing potential climate change impacts on, and formulating adaptation options for, agriculture at regional level. The methodology was developed and applied in the analysis of climate change impacts on key horticultural commodities—pome fruits (apples and pears), stone fruits (peaches and nectarines) and wine grapes—in the Goulburn Broken catchment management region, State of Victoria, Australia. Core components of the methodology are mathematical models that enable to spatially represent the degree of biophysical land suitability for the growth of agricultural commodities in the region of interest given current and future climatic conditions. The methodology provides a sound analytic approach to 1) recognise regions under threat of declines in agricultural production due to unfolding climatic changes; 2) identify alternative agricultural systems better adapted to likely future climatic conditions and 3) investigate incremental and transformational adaptation actions to improve the problem situations that are being created by climate change.

Bird flock

The work consists of a set of six, utilitarian wine glasses. Each glass features the engraving of a bird silhouette; the six engravings represent a flock of birds and also six key-poses in the animated flight-cycle of one bird. Beside the array of wine glasses sits a screen on which is displayed a looped animation of this same bird in flight. In a way, the six wine glasses represent the six animation cels of the displayed animation. Additionally, each engraved glass serves as a sight-trigger for a smart-phone or other mobile device. If one has the Aurasma app on their device and holds it up to ‘look at’ any one of the engravings, the animation of the flying bird will also be displayed on their device’s screen.

Self-cleaning wool: effect of noble metals and silica on visible-light-induced functionalities of nano TiO2 colloid

© 2014 The Textile Institute. This study intends to enhance the functionality of titanium dioxide (TiO2) nanoparticles applied to wool fabrics under visible light. Herein, TiO2, TiO2/SiO2, TiO2/Metal, and TiO2/Metal/SiO2 nanocomposite sols were synthesized and applied to wool fabrics through a low-temperature sol–gel method. The impacts of three types of noble metals, namely gold (Au), platinum (Pt), and silver (Ag), on the photoefficiency of TiO2 and TiO2/SiO2 under visible light were studied. Different molar ratios of Metal toTiO2 (0.01, 0.1, 0.5, and 1%) were employed in synthesizing the sols. Photocatalytic efficiency of fabrics was analyzed through monitoring the removal of red wine stain and degradation of methylene blue under simulated sunlight and visible light, respectively. Also, the antimicrobial activity against Escherichia coli (E. coli) bacterium and the mechanical properties of fabrics were investigated. Through applying binary and ternary nanocomposite sols to fabrics, an enhanced visible-light-induced self-cleaning property was imparted to wool fabrics. It was concluded that the presence of silica and optimized amount of noble metals had a synergistic impact on boosting the photocatalytic and antimicrobial activities of coated samples. The fabrics were further characterized using attenuated total reflectance, energy-dispersive X-ray spectrometry, and scanning electron microscopy images.

Os italianos, vinho e turismo: o vale dos vinhedos na serra gaúcha

A presente dissertação trata do enoturismo na Serra Gaúcha, tendo como um fio condutor o processo de imigração italiana para a região e a manutenção de identidades e tradições ligadas ao cultivo da uva e à produção do vinho. O cerne do argumento é a importância das tradições italianas como um fator na criação das identidades coletivas regionais e de articulação entre passado e presente. Discute-se como as tradições engendram a produção da modernidade no âmbito das empresas e das atividades turísticas na região. Argumentamos que o apelo às tradições de origem é fruto, em primeiro lugar, do processo de imigração italiana para esta região do Nordeste do Rio Grande do Sul. Em seguida mostramos como a Festa da Uva, a primeira das comemorações, reinventa a tradição e se constitui no motor e base para o turismo na região. Finalmente, mostramos como a permanência da identidade nacional italiana atua como um fator de inovação, sobretudo nas técnicas de produção do vinho e da organização das atividades empresariais na região, numa síntese entre aspectos da tradição e da pós-modernidade.

Uma Contribuição à Contabilidade das Sociedades Cooperativas: Estudo de Caso sobre a Contabilização dos Atos Cooperativos e não Cooperativos em uma Cooperativa de Produção Vinícola do Sul do Brasil, de Acordo com a Norma Brasileira de Contabilidade - NBC T 10.8.

The main goal of this study is to contribute to the understanding of the appropriate accounting treatment of the operations in cooperatives, which differentiates them from other Brazilian commercial societies. This treatment is objectively examined under the lens of the norm NBC T 10.8 of Federal Council of Accounting, which determines distinction between cooperative acts and non-cooperative acts. The theoretical foundation of this paperwork is centered in examining, from both the cooperative doctrine and the accounting theory viewpoint, the issues related to the origin, nature and purpose of the cooperatives, as well as the accounting regulation applicable to them. The author developed a method to treat adequately the norm NBC T 10.8 and applied it to a case study of a wine producer cooperative in southern Brazil. As a result of this work, it is demonstrated that NBC T 10.8 eliminated a historical deficiency that permeated the accounting practice in cooperatives, whose accounting procedures - implicit in both technical and scientific content in NBC T 10.8 ¿ are presented in a detailed manner.

Effect of the estufagem process on the chemical constituents of Madeira wines

Madeira wine is a product of well-established reputation, whose aroma and flavour is the result of unique combinations. Particularly, its maturation may include estufagem, wherein wine is usually heated at 45 °C for three months. During this period, several chemical changes may occur, so it is essential to assess its impact on the wine. In this sense, the main objective of the thesis was to evaluate the effect estufagem on the chemical constituents of Madeira wine, specifically on those molecules potentially important in the development of its typical features. Firstly, analytical methodologies capable of determining the target compounds, combining precision and reproducibility to execution effectiveness, were developed. Then various monovarietal Madeira wines were analysed during estufagem under standard and overheating conditions in order to assess its effect. The following compounds were evaluated: furans, amino acids, biogenic amines, polyphenols, organic acids and volatile compounds. In addition, the total polyphenolic composition, the antioxidant potential and the colour of these wines were also evaluated. The results show that most constituents change due to the heating process. Particularly, the heating promotes the development of 5-hydroxymethylfurfural (HMF) in sweet wines submitted to estufagem at higher temperatures. Moreover, estufagem provides the decrease of most amino acids, suggesting their involvement in the formation of the bouquet of these wines. Regarding the total polyphenol content and antioxidant potential of these wines they do not seem to be greatly affected by the heating step, however most monomeric polyphenols decrease during this process. The thermal processing of Madeira wines favours the development of the volatile composition, especially of volatiles usually reported as typical aromas of Madeira wines. Finally, it was demonstrated that the thermal degradation of sugars, especially of fructose, promotes the emergence of volatile compounds identified in baked wines.

Color measurement using a smartphone applied to Madeira wines

Computer vision is a field that uses techniques to acquire, process, analyze and understand images from the real world in order to produce numeric or symbolic information in the form of decisions [1]. This project aims to use computer vision to prepare an app to analyze a Madeira Wine and characterize it (identify its variety) by its color. Dry or sweet wines, young or old wines have a specific color. It uses techniques to compare histograms in order to analyze the images taken from a test sample inside a special container designed for this purpose. The color analysis from a wine sample using an image captured by a smartphone can be difficult. Many factors affect the captured image such as, light conditions, the background of the sample container due to the many positions the photo can be taken (different to capture facing a white wall or facing the floor for example). Using new technologies such as 3D printing it was possible to create a prototype that aims to control the effect of those external factors on the captured image. The results for this experiment are good indicators for future works. Although it’s necessary to do more tests, the first tests had a success rate of 80% to 90% of correct results. This report documents the development of this project and all the techniques and steps required to execute the tests.

Olfactory perception threshold assessment of volatile acidity in Madeira wines

Madeira wine is a fortified wine with impact in the Madeira Island’s economy. Similarly to other wines, its acidity should be well controlled in order to ensure Madeira wine quality, mostly the volatile acidity. Due to Madeira wine complex flavour, it is crucial to get a better knowledge about the volatile acidity impact in its features, namely determine the perception limit of acetic acid and ethyl acetate, as both are the main contributors for volatile acidity. Firstly, the olfactory perception threshold of volatile acidity was assessed by a trained and an untrained panel, using 5 and 10 years-old Sercial and Malvasia wines. Moreover, the current work also presents the evolution of organic acids, acetic acid and ethyl acetate during 540 days of ageing of Madeira wines (Malvasia, Bual, Verdelho and Sercial), comparing the same wines aged by both traditional ageing processes: canteiro and estufagem. Other wine samples, aged in wood casks (canteiro) for at least 5 years, were also evaluated. HS-SPME followed by GC-MS analysis was used to determine ethyl acetate concentration and IEC-HPLC-DAD was used for the organic acids determination, including acetic acid. The results indicated that acetic acid and ethyl acetate olfactory perception threshold depends essentially on wine’s age. Concerning acetic acid, the untrained panel was in average 5.45 g/L (5 years-old) and 6.22 g/L (10 years-old). Training the expert panel to recognize acetic acid odour, the values decreased for 1.44 g/L (5 years-old) and 1.87 g/L (10 years-old), but still remained higher than the established volatile acidity legal limits. Ethyl acetate threshold was similar for both panels (in average 327.97 mg/L). Both compounds tend to increase exponentially with age, being more evident in sweet wines. Organic acids in young Madeira wines depend mostly on the nature of grape varieties, but this difference is minimized with wine ageing.

Relationship between antioxidant capacity and total phenolic content of red, rosé and white wines

Phenolic compounds are one of the most important quality parameters of wines, since they contribute to wine organoleptic characteristics such as colour, astringency, and bitterness. Furthermore, several studies have pointed out that many show biological properties of interest, related to their antioxidant capacity. This antioxidant activity has been thoroughly studied and a wide variety of methods have been developed to evaluate it. In this study, the antioxidant activity of commercial Terras Madeirenses Portuguese wines (Madeira Island) was measured by three different analytical methods: [1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging assay, 2,2′-azino-bis-(3-ethylbenzothiazoline-6-sulfonic acid (ABTSradical dot+)) radical cation decolourisation, and ferric reducing/antioxidant power (FRAP) for the evaluation of reducing power (PR) and correlate them with the total phenolic content determined with the Folin–Ciocalteu’s reagent using gallic acid as a standard. The total polyphenol concentration was found to vary from 252 to 1936 mg/l gallic acid equivalents (GAE). The antiradical activity varied from 0.042 to 0.715 mM Trolox equivalents and the antioxidant capacity varied from 344 to 1105 mg/l gallic acid equivalents (GAE). For the reduction power we obtained 3.45–3.86 mM quercetin equivalents.

Changes in volatile composition of Madeira wines during their oxidative ageing

The influence of the age in the volatile composition of Madeira wines made with Boal, Malvazia, Sercial and Verdelho varieties and aged in oak barrel during 1, 11 and 25 years old was been studied. For this purpose, the evolution of volatile compounds: higher alcohols, ethyl esters, fatty acids, furan compounds, enolic compounds, γ-lactones, dioxanes and dioxolanes, of the four most utilised varieties were determined using liquid–liquid extraction with dichloromeihane. Octan-3-ol was used as internal standard. The wines made with these varieties showed great differences in sugar content and small variations on pH and alcoholic degree. The results show that during ageing, the concentration of fatty acids ethyl esters, acetates and fatty acids decrease significantly contrarily to the great increase of ethyl esters of diprotic acids. There is a strong correlation between sotolon, 2-furfural, 5-methyl-2-furfural, 5-hydroxymethyl-2-furfural and 5-ethoxymethyl-2-furfural with wine ageing. These findings indicate that these compounds can be used as ageing wine markers. Among the molecules studied, sotolon [3-hydroxy-4,5-dimethyl-2(5H)-furanone] was one of the few molecules present in concentrations above the perception threshold in Madeira wines. 5-Eihoxymethyl-2-furfural formed from 5-hydroxymethyl-2-furfural and 2-furfural, derived from sugars, are also involved in the aroma of sweet fortified white wines aged in oxidative conditions. The sensory properties change significantly after long periods of conservation.