Volcaniclastic sediments of ODP Leg 136 sites

Sediment cores recovered from three holes drilled during Ocean Drilling Program Leg 136 include volcaniclastics probably derived from the Hawaiian islands. The volcaniclastics shallower than 10 meters below seafloor are fresh and are composed of basaltic glass (sideromelane), basaltic fragments (mainly tachylite), plagioclase, olivine, pyroxene, and opaque minerals. Most of these glasses are probably products of hydrovolcanism. Visibly, some of these volcaniclastics are recognized as bedded ash layers having thicknesses that range from 5 to 10 cm. However, many volcaniclastics are disrupted by bioturbation to some degree, and are sometimes totally mixed with ambient brown clays. No visible correlative ash layer among these holes was found. It seems that many ash layers thinner than the bedded layers were disrupted by bioturbation because of the low sedimentation rate of volcaniclastics. The volcaniclastics were probably transported one of two ways: through air fall and pelagic settling or through turbidity-current transport. Other archipelagic apron volcaniclastic sediments of volcanic seamounts suggest that turbidite transport is the favored explanation of origin.

Age and chemical composition of volcanic rocks and minerals from the Vityaz Ridge

This paper reports results of geological studies carried out during two marine expeditions of R/VAkademik M.A. Lavrent'ev (Cruises 37 and 41) in 2005 and 2006 at the underwater Vityaz Ridge. Dredging has yielded various rocks from the basement and sedimentary cover of the ridge within three polygons. On the basis of radioisotope age determinations, petrochemical, and paleontological data all the rocks have been subdivided into the following complexes: volcanic rock of Paleocene, Eocene, Late Oligocene, Middle Miocene, and Pliocene-Pleistocene; volcanogenic-sedimentary rocks of Late Cretaceous - Early Paleocene, Paleogene (undifferentiated), Oligocene - Early Miocene, and Pliocene-Pleistocene. Determinations of age and chemical composition of the rocks have enabled to specify formation conditions of the complexes and to trace geological evolution of the Vityaz Ridge. Presence of young Pliocene-Pleistocene volcanites allows to conclude about the modern tectono-magmatic activity of the central part of the Pacific slope of the Kuril Islands.

Lead isotopes inthe Eastern Equatorial Pacific

The influence of atmospheric dust on climate and biogeochemical cycles in the oceans is well understood but poorly quantified. Glacial atmospheric dust loads were generally greater than those during the Holocene, as shown, for example, by the covariation of dust fluxes in the Equatorial Pacific and Antarctic ice cores. Nevertheless, it remains unclear whether these increases in dust flux were associated with changes in sources of dust, which would in turn suggest variations in wind patterns, climate or paleo-environment. Such questions can be answered using radiogenic isotope tracers of dust provenance. Here, we present a 160-kyr high-precision lead isotope time-series of dust input to the Eastern Equatorial Pacific (EEP) from core ODP Leg 138, Site 849 (0°11.59' N, 110°31.18' W). The Pb isotope record, combined with Nd isotope data, rules out contributions from Northern Hemisphere dust sources, north of the Intertropical Convergence Zone, such as Asia or North Africa/Sahara; similarly, eolian sources in Australia, Central America, the Northern Andes and Patagonia appear insignificant based upon the radiogenic isotope data. Fluctuations in Pb isotope ratios throughout the last 160 kyr show, instead, that South America remained the prevailing source of dusts to the EEP. There are two distinct South American Pb isotope end-members, constrained to be located in the south Central Volcanic Zone (CVZ, 22° S - 27.5° S) and the South Volcanic Zone (SVZ, 33° S - 43° S), with the former most likely originating in the Atacama Desert. Dust availability in the SVZ appears to be related to the weathering of volcanic deposits and the development of ash-derived Andosols, and influenced by local factors that might include vegetation cover. Variations in the dust fluxes from the two sources are in phase with both the dust flux and temperature records from Antarctican ice cores. We show that the forcing of dust provenance over time in the EEP overall is influenced by high-southerly-latitude climate conditions, leading to changes in the latitudinal position and strength of the South Westerlies as well as the coastal winds that blow northward along the Chilean margin. The net result is a modulation of dust emission from the Atacama Desert and the SVZ via a northward migration of the South Westerlies during cold periods and southward retreat during glacial terminations.

Snow depths of volcanic events and accumulation rates of firn cores from the IPY traverse, Antarctica

Volcanic signatures in ice-core records provide an excellent means to date the cores and obtain information about accumulation rates. From several ice cores it is thus possible to extract a spatio-temporal accumulation pattern. We show records of electrical conductivity and sulfur from 13 firn cores from the Norwegian-USA scientific traverse during the International Polar Year 2007-2009 (IPY) through East Antarctica. Major volcanic eruptions are identified and used to assess century-scale accumulation changes. The largest changes seem to occur in the most recent decades with accumulation over the period 1963-2007/08 being up to 25% different from the long-term record. There is no clear overall trend, some sites show an increase in accumulation over the period 1963 to present while others show a decrease. Almost all of the sites above 3200 m above sea level (asl) suggest a decrease. These sites also show a significantly lower accumulation value than large-scale assessments both for the period 1963 to present and for the long-term mean at the respective drill sites. The spatial accumulation distribution is influenced mainly by elevation and distance to the ocean (continentality), as expected. Ground-penetrating radar data around the drill sites show a spatial variability within 10-20% over several tens of kilometers, indicating that our drill sites are well representative for the area around them. Our results are important for large-scale assessments of Antarctic mass balance and model validation.

Age and isotopic and chemical compositions of volcanic rocks from the Japan and Okhotsk Seas

This paper reports results of petrographic and geochemical studies of Miocene-Pleistocene volcanic rocks that accompanied formation of deep-water basins of the Sea of Japan and Sea of Okhotsk. Geochemical types of these rocks, their geodynamic settings, and their derivation from different magmatic sources were determined. Marginal-sea basaltoids from the Sea of Japan are derivatives of fluid-enriched mantle (EMI), while volcanics from the Kuril basin were generated from mantle enriched in continental crust matter (EMU). In spite of different conditions of their genesis, they have some common geochemical features, in particular, their calc-alkaline signatures. These traces of influence of the sialic crust on magma generation confirm development of the basins of both these seas on the continental basement.

Secondary mineral assemblages in a volcanic sequence of ODP Hole 104-642E

Mineralogical and geochemical analyses of alteration products from upper and lower volcanic series recovered during ODP Leg 104 reveal variations both in composition and order of crystallization of clay minerals vesicles and voids filling and replacing glass. These results provide information about successive alteration stages of rocks and interlayered volcaniclastic sediments. The first stage, related to initial basalt-seawater interaction, is characterized by development of Fe-smectites, especially Fe-rich saponite. A second stage of intermittently superimposed subaerial weathering is marked by iron-oxides-halloysite-kaolinite formation. The third episode, interpreted as hydrothermal on the basis of O-isotopic data, is defined by postburial coprecipitation of Fe-poor, Mg-rich saponite and celadonite. A distinct final and pervasive hydrothermal stage, occurring mainly in the lower series and dominated by Al-smectites-zeolites assemblage, indicates changes toward a more reducing alteration environment.

Chemical composition of rocks and minerals from the Karymsky volcanic center, Eastern Kamchatka

The powerful eruption in the Akademii Nauk caldera on January 2, 1996 marked a new activity phase of the Karymsky volcano and became a noticeable event in the history of modern volcanism in Kamchatka. The paper reports data obtained by studying more than 200 glassy melt inclusions in phenocrysts of olivine (Fo82-72), plagioclase (An92-73), and clinopyroxene (Mg# 83-70) in basalts of the 1996 eruption. The data were used to estimate composition of the parental melt and physicochemical parameters of the magma evolution. According to our data, the parental melt corresponded to low magnesium, high aluminum basalt (SiO2 = 50.2%, MgO = 5.6%, Al2O3 = 17%) of the mildly potassium type (K2O = 0.56%) and contained much dissolved volatile components (H2O = 2.8%, S = 0.17%, and Cl = 0.11%). Melt inclusions in the minerals are similar in chemical composition, a fact testifying that the minerals crystallized simultaneously with one another. Their crystallization started at pressure ~1.5 kbar, proceeded within a narrow temperature range of 1040+/-20°C, and continued until near-surface pressure ~100 bar was reached. Degree of crystallization of the parental melt during its eruption was close to 55%. Massive crystallization was triggered by H2O degassing under pressure <1 kbar. Magma degassing in an open system resulted in escape of 82% H2O, 93% S, and 24% Cl (of their initial contents in the parental melt) to the fluid phase. Release of volatile compounds to the atmosphere during the eruption that lasted for 18 h was estimated as 1.7x10**6 t H2O, 1.4x10**5 t S, and 1.5x10**4 t Cl. Concentrations of most incompatible trace elements in the melt inclusions are close to those in the rocks and to the expected fractional differentiation trend. Melt inclusions in plagioclase were found to be selectively enriched in Li. The Li-enriched plagioclase with melt inclusions thought to originate from cumulate layers in the feeding system beneath Karymsky volcano, in which plagioclase interacted with Li-rich melts/brines and was subsequently entrapped and entrained by the magma during the 1996 eruption.