Freezing point and thermal conductivity of tropical fruit pulps: Mango and papaya

The freezing point depression of mango and papaya pulps was measured by using a simple apparatus, consisting of two major sections: a freezing vessel and a data acquisition system. The thermal conductivity of both pulps as a function of frozen water fraction and temperature was also investigated by using a coaxial dual-cylinder apparatus. Thermal conductivity above the initial freezing point was well fitted by polynomial equations. Below the freezing point, the thermal conductivity was strongly affected by both the frozen water fraction and temperature. Simple equations in terms of frozen water fraction and temperature could be fitted to the experimental data of freezing point depression and thermal conductivity.

Qualidade fisiológica de sementes de Sebastiania commersoniana (Baill.) Smith & Downs (branquilho - Euphorbiaceae) durante o armazenamento

This paper aims to evaluate the physiological quality of Sebastiania commersoniana seeds stored in cloth bag, plastic bag and glass container and kept in two conditions: laboratory workbench and cold chamber (4 ± 2°C e 80% relative humidity - RH) for 531 days. Periodically, samples were taken in order to determine the moisture content and to perform germination tests. The experimental design was completely randomized, in factorial scheme of 3 × 2 (wrappings × conditions), for each period of storage evaluated (0, 158, 271, 389 and 531 days of storage). Supplementary, a polynomial regression was adjusted in order to describe the physiological quality of the seeds for the different conditions during the experimental period. The results lead to the following considerations: a) storage under variable temperature and air humidity (laboratory workbench) can be used for periods of over five and a half months, with the seeds stored in cloth bag, plastic bag or glass container; b) the physiological quality of the seeds was not hardly altered when stored in cold chamber in cloth bag, plastic bag and glass container for over 18 months.

Uso de modelos lineales y no lineales para el estudio de la curva de lactancia en búfalos Murrah y sus cruces en sistemas de cría extensiva en el estado de São Paulo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Radial basis function networks with quantized parameters

A RBFN implemented with quantized parameters is proposed and the relative or limited approximation property is presented. Simulation results for sinusoidal function approximation with various quantization levels are shown. The results indicate that the network presents good approximation capability even with severe quantization. The parameter quantization decreases the memory size and circuit complexity required to store the network parameters leading to compact mixed-signal circuits proper for low-power applications. ©2008 IEEE.

Crystal and supramolecular structures of dysprosium(III) 2-methoxybenzoate tetrahydrate

The compound dysprosium(III) 2-metoxybenzoate, {[Dy(2-MeO-Bz)2μ-(2-MeO-Bz)(H2O)2]2·4H2O}n (2-MeO-Bz = 2- methoxybenzoate), was synthesized from a reaction mixture containing DyCl3 and Na(2-MeO-Bz), and characterized by single-crystal X-ray diffraction. The molecular structure showed dinuclear units in which each Dy(III) ion is coordinated by nine oxygen atoms. The carboxylato groups are bound to the dysprosium centers in two modes: bidentate chelating and tridentate chelating-bridging. Besides this, the occurrence of hydrogen bonds involving a coordinated water molecule and carboxylato groups leads to the formation of helicoidal chains along the crystal lattice, resulting in a supramolecular one-dimensional polymer. 2008 © The Japan Society for Analytical Chemistry.

Hydrothermal synthesis and crystal structure of a copper(ii) coordination polymer with bridging dicarboxylate and diamine ligands

This work reports on the synthesis of a copper(II) coordination compound with 4,4-oxibis(benzoate) (obb) and trans-1,2- bis(4-pyridyl)ethene (bpe) ligands. The complex was characterized by single-crystal X-ray diffraction, which showed a 3D polymeric structure. Each copper center is surrounded by four oxygen atoms at the basal plane and one nitrogen atom and one copper atom at the axial positions, revealing a distorted octahedral geometry. Four carboxylic groups bridge two copper atoms, forming a cage-like structure, with the distance between the metallic centers being 2.656(1)Å. 2008 © The Japan Society for Analytical Chemistry.

Crystal and molecular structure of dinuclear palladium(II) complex containing nitrogen and phosphorus donor ligands, [Pd2(N3)4(PPh3)2(μ-ted)]

The dinuclear azido-palladium(II) complex [Pd2(N3)4(PPh3)2(μ-ted)], where PPh3 = triphenylphosphine and ted = triethylenediamine, was synthesized and characterized by single-crystal X-ray diffraction. The title compound was crystallized in a triclinic system, space group P1 with a = 11.5875(2)Å, b = 13.0817(3)Å, c = 15.2618(3)Å, α = 93.306(2)°, β =110.040(1)°, γ = 98.486(1)°, V = 2134.95(8)Å3, Z = 2. Each Pd(II) center displays a distorted squareplanar coordination environment formed by two N atoms from two trans terminally coordinated azido groups, one P atom from the phosphine and one N atom from the bridging ted ligand. 2008 © The Japan Society for Analytical Chemistry.

Calibration uncertainty estimation for internal aerodynamic balance

Aerodynamic balances are employed in wind tunnels to estimate the forces and moments acting on the model under test. This paper proposes a methodology for the assessment of uncertainty in the calibration of an internal multi-component aerodynamic balance. In order to obtain a suitable model to provide aerodynamic loads from the balance sensor responses, a calibration is performed prior to the tests by applying known weights to the balance. A multivariate polynomial fitting by the least squares method is used to interpolate the calibration data points. The uncertainties of both the applied loads and the readings of the sensors are considered in the regression. The data reduction includes the estimation of the calibration coefficients, the predicted values of the load components and their corresponding uncertainties, as well as the goodness of fit.

Third-body perturbation in the case of elliptic orbits for the disturbing body

In the present work it is presented a semi-analytical and a numerical study of the perturbation caused in a spacecraft by a third body using a double averaged analytical model with the disturbing function expanded in Legendre polynomials up to the second-order. The important reason for this procedure is to eliminate the terms due to the short time periodic motion of the spacecraft and to show smooth curves for the evolution of the mean orbital elements for a long time period. The aim of this study is to calculate the effect of lunar perturbations on the orbits of spacecrafts that are traveling around the Earth. It is presented an analysis of the stability of a near-circular orbit and a study to know under which conditions this orbit remains near-circular. A study of the equatorial orbits is also performed.

Testes de vigor para avaliação da qualidade fisiológica de sementesde Sebastiania commersoniana (Baill.) Smith & Downs.

The objective of this work was to evaluate the efficiency of different vigor tests to assess S. commersoniana seeds physiological quality during storage. Therefore, seeds were stored in cloth bags, plastic bags and glass containers for 531 days, both at room temperature and in a cold chamber. Periodically samples were taken and the following tests were conducted: standard germination, germination speed index, first count after germination, seedlings fresh and dry matter, electrical conductivity (imbibitions for 2 and 24 hours) and accelerated aging, in order to monitoring the seeds physiologic quality. Data were submitted to polynomial regression analysis, for each of the combination of packaging/storage condition. The results obtained led to the following considerations: a) the speed germination index and the accelerated aging test permitted a good evaluation of the seed-lots quality; b) the first count of germination did not allow any prediction about seed lots vigor; c) seedling fresh and dry matter did not discriminate among seed lots; d) electrical conductivity test after 2 h imbibitions was not adequate to evaluate the seed lots vigor and e) the electric conductivity test with 24 h imbibitions was more adequate to differentiate among seed lots, but with little efficiency to discriminate among seed lots with intermediate vigor or with low quality differences.

Estimación de parámetros genéticos para la producción de leche en el día del control empleando un modelo de regresión aleatoria para primeras lactancias en búfalos de la costa norte de Colombia

A total of 5575 monthly test-day yield records from 796 lactations buffaloes first in the north coast of Colombia. The model included random direct additive genetic and permanent environment effects. As fixed effects were included, contemporary groups, and age of cow at calving as covaraible, linear and quadratic effects. Test-day (PLDC) yield was 3.89 ± 1.14 kg. The PLDC ranged from 2.86 kg to 4.26 kg while the highest values towards the middle of lactation. The heritability estimates obtained for PLDC ranged from 0.23 to 0.47. Genetic correlations between PLDC, declining steadily increased the distance between PLDC. Phenotypic variances were higher in the initial PLDC and decreasing towards the end of lactation. The results found in this study indicate that there is a high genetic variability for the PLDC in the population studied using a random regression model.

Multi-trait and random regression mature weight heritability and breeding value estimates in Nelore cattle

Mature weight breeding values were estimated using a multi-trait animal model (MM) and a random regression animal model (RRM). Data consisted of 82 064 weight records from 8 145 animals, recorded from birth to eight years of age. Weights at standard ages were considered in the MM. All models included contemporary groups as fixed effects, and age of dam (linear and quadratic effects) and animal age as covariates. In the RRM, mean trends were modelled through a cubic regression on orthogonal polynomials of animal age and genetic maternal and direct and maternal permanent environmental effects were also included as random. Legendre polynomials of orders 4, 3, 6 and 3 were used for animal and maternal genetic and permanent environmental effects, respectively, considering five classes of residual variances. Mature weight (five years) direct heritability estimates were 0.35 (MM) and 0.38 (RRM). Rank correlation between sires' breeding values estimated by MM and RRM was 0.82. However, selecting the top 2% (12) or 10% (62) of the young sires based on the MM predicted breeding values, respectively 71% and 80% of the same sires would be selected if RRM estimates were used instead. The RRM modelled the changes in the (co)variances with age adequately and larger breeding value accuracies can be expected using this model. © South African Society for Animal Science.

L(+) Lactic acid production by new Lactobacillus rhamnosus B 103

L(+) Lactic acid fermentation was studied by Lactobacillus rhamnosus sp. under the effects of pH control and a lowcost nutritional medium (sugarcane juice and corn steep liquor-CSL). Central composite design (CCD) was employed to determine maximum lactic acid production at optimum values for process variables and a satisfactory fit model was realized. Statistical analysis of the results showed that the linear and quadratic terms of two variables (sugarcane juice and pH) had significant effects. The interactions between the three variables were found to contribute to the response at a significant level. A second-order polynomial regression model estimated that the maximum lactic acid production of 86.36 g/L was obtained when the optimum values of sucrose, CSL and pH were 112.65 g/L, 29.88 g/L and 6.2, respectively. Verification of the optimization showed that L(+) lactic acid production was of 85.06 g/L. Under these conditions, Y P/S and Q P values of 0.85 g/g and 1.77 g/Lh, respectively, were obtained after 48 h fermentation, with a maximal productivity of 2.2 g/L h at 30 h of process. © 2010 de Lima CJB, et al.

Métodos de interpolação para estimar o ph em solo sob dois manejos de café Arábica

There are many methods used to estimate values in places no sampled for construction of contours maps. The aim of this study was to use the methods of interpolation kriging, inverse of the square of the distance and polynomial in the representation of the spatial variability of the pH of the soil in the organic and conventional management in the culture of the coffee plantation. For that, irregular meshes were built for soil sampling in the depth of 0-0,10 meters, totaling 40 points sampling in each area. For gauging of the interpolation methods they were solitary 10% of the total of points, for each area. Initially, the data were appraised through the classic statistics (descriptive and exploratory) and spatial analysis. The method inverse square of the distance and kriging has low error in estimating dados. The method of kriging presented low variation around the average in different managements.

Kernel polynomials from L-orthogonal polynomials

A positive measure ψ defined on [a,b] such that its moments μn=∫a btndψ(t) exist for n=0,±1,±2,⋯, is called a strong positive measure on [a,b]. If 0≤apolynomials {Qn}, defined by ∫a bt-n+sQn(t)dψ(t)=0, s=0,1,⋯,n-1, is known to exist. We refer to these polynomials as the L-orthogonal polynomials with respect to the strong positive measure ψ. The purpose of this manuscript is to consider some properties of the kernel polynomials associated with these L-orthogonal polynomials. As applications, we consider the quadrature rules associated with these kernel polynomials. Associated eigenvalue problems and numerical evaluation of the nodes and weights of such quadrature rules are also considered. © 2010 IMACS. Published by Elsevier B.V. All rights reserved.