Synthesis and Structural Elucidation of Triazolylmolybdenum(VI) Oxide Hybrids and Their Behavior as Oxidation Catalysts

A large family of bifunctional 1,2,4-triazole molecular tectons (tr) has been explored for engineering molybdenum(VI) oxide hybrid solids. Specifically, tr ligands bearing auxiliary basic or acidic groups were of the type amine, pyrazole, 1H-tetrazole, and 1,2,4-triazole. The organically templated molybdenum(VI) oxide solids with the general compositions [MoO3(tr)], [Mo2O6(tr)], and [Mo2O6(tr)(H2O)2] were prepared under mild hydrothermal conditions or by refluxing in water. Their crystal structures consist of zigzag chains, ribbons, or helixes of alternating cis-{MoO4N2} or {MoO5N} polyhedra stapled by short [N–N]-tr bridges that for bitriazole ligands convert the motifs into 2D or 3D frameworks. The high thermal (235–350 °C) and chemical stability observed for the materials makes them promising for catalytic applications. The molybdenum(VI) oxide hybrids were successfully explored as versatile oxidation catalysts with tert-butyl hydroperoxide (TBHP) or aqueous H2O2 as an oxygen source, at 70 °C. Catalytic performances were influenced by the different acidic–basic properties and steric hindrances of coordinating organic ligands as well as the structural dimensionality of the hybrid.

In Börnes Aufsatz: "Juden in Frankfurt a. M." : (Börnes Schriften VI, S. 66 - 70)

L. G.

Bibliographie der Schriften Dr. M. Kayserlings s. A. : zu seinem Centenarium [17. VI. 1929]

hrsg. von Max Weisz

The Sicilian coinage of Henry VI - mint attributions reconsidered

The Sicilian Coinage of the Hohenstaufen has been studied since the 17th century. Today, with the splendid Medieval European Coinage 14 at our hands, scholars are still struggling when it comes to mint attributions for Henry’s Sicilian denari and taris: Palermo or Messina? Palermo and Messina? The coin finds from Monte Iato (PA) may shed light on this old problem: by starting from one coin type alone and examining the different subtypes and variants, we can catch a glimpse of the way coinage was organised in Sicily at the end of the 12th century.

Relation über die am 23. August 1848 stattgehabten Begebenheiten, in Bezug des VI. Bezirkes Landstraße, gegenüber der [sic!] aufgewiegelten Arbeiter: Auf Befehl des hohen Nationalgarde-Ober-Commandos wurde am besagten Tage Nachmittags Alarm geschlagen ...

Welsch (Projektbearbeiter): Schilderung der Geschehnisse bei der Niederschlagung des Arbeiteraufstandes am 23. August 1848 (aus der Sicht des Bataillonskommandanten Bodnár von der Wiener Nationalgarde)

Oral-facial-digital syndrome type VI: is C5orf42 really the major gene?

Oral-facial-digital type VI syndrome (OFDVI) is a rare phenotype of Joubert syndrome (JS). Recently, C5orf42 was suggested as the major OFDVI gene, being mutated in 9 of 11 families (82 %). We sequenced C5orf42 in 313 JS probands and identified mutations in 28 (8.9 %), most with a phenotype of pure JS. Only 2 out of 17 OFDVI patients (11.7 %) were mutated. A comparison of mutated vs. non-mutated OFDVI patients showed that preaxial and mesoaxial polydactyly, hypothalamic hamartoma and other congenital defects may predict C5orf42 mutations, while tongue hamartomas are more common in negative patients.

Influence of sample matrix on the alkaline extraction of Cr(VI) in soils and industrial materials

An accurate and efficient determination of the highly toxic Cr(VI) in solid materials is important to determine the total Cr(VI) inventory of contaminated sites and the Cr(VI) release potential from such sites into the environment. Most commonly, total Cr(VI) is extracted from solid materials following a hot alkaline extraction procedure (US EPA method 3060A) where a complete release of water-extractable and sparingly soluble Cr(VI) phase is achieved. This work presents an evaluation of matrix effects that may occur during the hot alkaline extraction and in the determination of the total Cr(VI) inventory of variably composed contaminated soils and industrial materials (cement, fly ash) and is compared to water-extractable Cr(VI) results. Method validation including multiple extractions and matrix spiking along with chemical and mineralogical characterization showed satisfying results for total Cr(VI) contents for most of the tested materials. However, unreliable results were obtained by applying method 3060A to anoxic soils due to the degradation of organic material and/or reactions with Fe2+-bearing mineral phases. In addition, in certain samples discrepant spike recoveries have to be also attributed to sample heterogeneity. Separation of possible extracted Cr(III) by applying cation-exchange cartridges prior to solution analysis further shows that under the hot alkaline extraction conditions only Cr(VI) is present in solution in measurable amounts, whereas Cr(III) gets precipitated as amorphous Cr(OH)3(am). It is concluded that prior to routine application of method 3060A to a new material type, spiking tests are recommended for the identification of matrix effects. In addition, the mass of extracted solid material should to be well adjusted to the heterogeneity of the Cr(VI) distribution in the material in question.

The GAPS programme with HARPS-N at TNG VI. The curious case of TrES-4b

We update the TrES-4 system parameters using high-precision HARPS-N radial-velocity measurements and new photometric light curves. A combined spectroscopic and photometric analysis allows us to determine a spectroscopic orbit with a semi-amplitude K = 51 +/- 3 ms(-1). The derived mass of TrES-4b is found to be M-p = 0.49 +/- 0.04 M-Jup, significantly lower than previously reported. Combined with the large radius (R-p = 1.84(-0.09)(+0.08) R-Jup) inferred from our analysis, TrES-4b becomes the transiting hot Jupiter with the second-lowest density known. We discuss several scenarios to explain the puzzling discrepancy in the mass of TrES-4b in the context of the exotic class of highly inflated transiting giant planets.

Meine Eindrücke vom VI. Zionisten-Kongress

Ernst Tuch

Die zweite Ausstellung in der Kunstsammlung der jüdischen Gemeinde zu Berlin : VI.

Moritz Stern

Rumänien und seine Juden : VI.

S. Schiffer