Influence of iron promoter on catalytic properties of Rh-Mn-Li/SiO2 for CO hydrogenation

The effect of iron promoter on the catalytic properties of Rh-Mn-Li/SiO2 catalyst in the synthesis Of C-2 oxygenates from syngas was investigated by means of the following techniques: CO hydrogenation reaction, temperature-programmed reduction (TPR), temperature-programmed desorption and reaction of adsorbed CO (CO-TPD and TPSR) and pulse adsorption of CO. The results showed that the addition of iron promoter could improve the activity of the catalysts. Unexpectedly, the yield of C-2 oxygenates increased greatly from 331.6 up to 457.5 g/(kg h) when 0.05% Fe was added into Rh-Mn-Li/SiO2 catalyst, while no change in the selectivity to C-2 oxygenates was observed. However, the activity and selectivity Of C-2 oxygenates were greatly decreased if the Fe amount exceeded 1.0%. The existence of a little iron decreased the reducibility of Rh precursor, while the reduction of Fe component itself became easier. CO uptake decreased with increasing the quantity of Fe addition. This phenomenon was further confirmed by CO-TPD results. The CO-TPD and TPSR results showed that only the strongly adsorbed CO could be hydrogenated, while the weakly adsorbed CO was desorbed. We propose that Fe is highly dispersed and in close contact with Rh and Mn; such arrangements were responsible for the high yield Of C-2 oxygenates. (C) 2002 Elsevier Science B.V. All rights reserved.

燕沟流域退耕地土壤有机碳、全氮和酶活性对植被恢复过程的响应

本文以黄土高原丘陵区陕北延安燕沟流域为例,研究了退耕地土壤有机碳、全氮和酶活性对植被恢复过程的响应。结果表明,随植被恢复年限的增加,植被盖度、多度和物种数均呈现先增加后减少然后又增加的趋势。同当年对照农地相比,随着植被恢复年限的增加,表层(0~20 cm)土壤有机碳、全氮、蔗糖酶、脲酶和碱性磷酸酶活性均明显增加,过氧化氢酶活性随植被恢复年限的增加变化不明显。同对照农地相比,表层土壤有机碳、全氮、蔗糖酶、脲酶和碱性磷酸酶活性分别增加了35%~184.6%、5.7%~157.4%、89.6%~566%、32.9%~331.2%和0.18%~184.8%。表层土壤有机碳和脲酶活性对植被恢复的响应是在植被恢复初期(0~8年),随植被恢复年限的增加而增加,植被恢复8~29年期间,随植被恢复年限的增加而减少,而植被恢复29 a以后,又随植被恢复年限的增加而增加。而表层土壤全氮、蔗糖酶和碱性磷酸酶活性对植被恢复的响应是在植被恢复初期(0~16年),随植被恢复年限的增加而增加,植被恢复16~29年期间,随植被恢复年限的增加而减少,植被恢复29 a以后,又随植被恢复年限的增加而增加。表层土壤蔗糖酶、脲酶和碱性磷酸酶活性与有机碳...

黄土丘陵区土壤团聚体分形特征及其对植被恢复的响应

采用计算分形维数的方法,对黄土丘陵区典型草原带土壤团聚体的分形特征及其对植被恢复的响应进行研究。结果表明:1)在植被恢复初期,土壤>10 mm粒级的团聚体含量在0~20和20~40 cm层次均较高,含量为331.4~525.6 g/kg。随植被恢复年限增加,10~7、7~5、5~3、3~2、2~1 mm粒级的团聚体绝对含量下降差异不明显。1~0.5、0.5~0.25和<0.25 mm小粒级土壤团聚体含量,在植被恢复初期(7 a)较高。2)随着植被恢复年限增加,土壤>5 mm粒级的水稳性团聚体含量相对下降很快,恢复7 a之后,大粒级土壤团聚体表现为上层含量比下层含量低的趋势。相对于干筛结果而言,土壤水稳性团聚体的粒径分布更为均匀、稳定,恢复7 a之后的土壤>0.25mm团聚体含量占到40%~50%,而>5 mm的土壤团聚体则占10%~23%。植被恢复过程中,土壤团聚体由大的团块向小颗粒的土壤团聚体转换,粒径分布更为均匀,土壤结构逐渐改善。3)不同恢复年限土壤团聚体分形维数变化范围为表层2.75~2.86,表下层2.77~2.89,变化范围小,20~40 cm土层的分形维数大于0~20 cm,恢复植被可使土壤分形...

土壤改良剂改土培肥增产效应研究综述

壤改良剂研究已是近年来国内外广泛关注的热点,在对土壤改良剂发展及其种类进行简要回顾的基础上,对土壤改良剂的改土培肥效应(物理结构、化学特性、生化特性)、作物增产效应及其施用技术进行了较为全面的分析和评述,并提出了目前存在的问题和展望了土壤改良剂的研究趋势。

论生态安全的基本概念和研究内容

安全是风险的反函数 ,通常指评价对象对于期望值状态的保障程度 ,或防止非理想的不确定性事件发生的可靠性 .生态安全可定义为人类在生产、生活与健康等方面不受生态破坏与环境污染等影响的保障程度 ,包括饮用水与食物安全、空气质量与绿色环境等基本要素 .生态安全研究的主要内容包括生态系统健康诊断、区域生态风险分析、景观安全格局、生态安全监测与预警以及生态安全管理、保障等方面 .区域生态安全研究具有宏观性和针对性的特点 ,评价标准则具有相对性和发展性 ,生态安全预警与设计要针对某一生态问题体现人类活动的能动性 .最后 ,以干旱内流区为例 ,对绿洲景观的生态安全分析和内陆河流域的生态安全保障措施进行了讨论

稀土元素示踪法在坡面土壤侵蚀垂直分布研究中的应用

通过野外全坡长侵蚀小区试验，证明了稀土元素示踪法在土壤侵蚀垂直分布研究中的可应用性。结果表明该径流小区产沙强度坡长存在三种变化模式：增长型，增长 递减型和波动型，其形成机理可能与径流过程有关。利用稀土元素在坡面的再分析，初步建立了估算坡面沟蚀率的关系式。

沈阳市苔藓植物区系初步研究

对882份标本进行鉴定,共记录沈阳市苔藓植物30科67属143种及变种,其中辽宁省新纪录种36种,东北新纪录种18种.区系分析表明本区苔藓植物以北温带成分为主(51.16%),其次为东亚成分(16.28%)和中国特有成分(12.40%),具强烈的温带性质,与该区地理位置和气候条件等相吻合,与种子植物的区系分布特点也一致.同其他城市地区苔藓植物属和种的相似性系数分析表明,沈阳市与同处辽宁省的抚顺市和鞍山市苔藓植物的亲缘性较大,而与其他城市地区亲缘性较小.

污水生态处理技术体系及应用

基于已有的研究工作基础 ,根据循环再生、和谐共存、整体优化、区域分异等污水生态处理原理 ,对慢渗生态处理系统、快渗生态处理系统、地表漫流生态处理系统、污水湿地生态处理系统、地下渗滤生态处理系统等技术体系进行了较为全面的论述与概括 ,就其应用条件进行了探讨与分析 ,以推进污水生态处理系统的技术创新和在我国各地区的广泛应用 ,为全面实施污水处理与水资源综合利用相结合的污水无害化、资源化战略提供科学依据与技术基础。

小叶白蜡接种外生菌根真菌对土壤石油烃的降解效果

采用盆栽实验研究了小叶白蜡(Fraxinus sogdiana)接种4种外生菌根真菌(E1-毛边滑锈伞(Hebeloma mesophaeusm)、E2-劣味乳菇(Lactarius insulsns)、E3-松塔牛肝菌(Stro-bilomyces floccopus)和E4-丝膜菌(Cortinarius russus)对沈抚灌区土壤石油烃的降解效果。结果表明:在白蜡不同组合双接种及混合接种中,以混合接种对土壤石油烃的降解效果最好,降解率比对照提高23.6%;其次为双接种中的E1E3和E2E4组合,降解率分别比对照提高21.0%和12.7%。接种外生菌根真菌可促进白蜡生长,尤其可明显提高其根生物量,增加侧根数,接种E1E3、E2E4和混合菌使白蜡侧根数分别增加了100%、67%和81%。相关分析表明,石油烃降解率与白蜡的侧根数呈显著相关,可能是其降解率提高的主要原因。

Red-light-emitting iridium complexes with hole-transporting 9-arylcarbazole moieties for electrophosphorescence efficiency/color purity trade-off optimizationE

The synthesis, structures, photophysics, electrochemistry and electrophosphorescent properties of new red phosphorescent cyclometalated iridium(III) isoquinoline complexes, bearing 9-arylcarbazolyl chromophores, are reported. The functional properties of these red phosphors correlate well with the results of density functional theory calculations

Red-Light-Emitting Iridium Complexes with Hole-Transporting 9-Arylcarbazole Moieties for Electrophosphorescence Efficiency/ Color Purity Trade-off Optimization

The synthesis, structures, photophysics, electrochemistry and electrophosphorescent properties of new red phosphorescent cyclometalated iridium(III) isoquinoline complexes, bearing 9-arylcarbazolyl chromophores, are reported. The functional properties of these red phosphors correlate well with the results of density functional theory calculations. The highest occupied molecular orbital levels of these complexes are raised by the integration of a carbazole unit to the iridium isoquinoline core so that the hole-transporting ability is improved in the resulting complexes relative to those with I-phenylisoquinoline ligands. All of the complexes are highly thermally stable and emit an intense red light at room temperature with relatively short lifetimes that are beneficial for highly efficient organic light-emitting diodes (OLEDs).

稀土顺丁橡胶的性能和应用

介绍了稀土钕系顺丁橡胶(NdBR)的牌号、质量指标、结构参数和性能特点,总结了NdBR在轮胎方面的应用效果,并展望了NdBR的发展前景

Efficient preparation of silver nanoplates assisted by non-polar solvents

In the paper, we report an efficient method to prepare high yield (up to 97%) of silver nanoplates. Synthesis of silver nanoplates was carried Out in a binary solvent system of N,N-dimethylformamide (DMF) and toluene, in which DMF served as the reductant and polyvinylpyrrolidone (PVP) as the capping agent. By increasing the ratio of toluene to DMF to 7:6, silver nanoplates can be Successfully synthesized; otherwise other shaped nanoparticles would be the major products. The nanoplate sample was characterized by TEM, HRTEM, SAED, XRD, AFM and UV-visible spectroscopy, proving the high nanoplate purity of this sample. The influence of toluene content, other solvents, AgNO3 concentration, preparation temperature and chloride ions was also examined, which suggests that the function of nonpolar solvents in this system is to enhance the PVP coverage on silver surface and, furthermore, to facilitate the preferential adsorption of PVP on two (I I I) facets of silver nanoplates.