Les sanctions d'une règle de droit législative incompatible avec la Charte canadienne des droits et libertés: le reading in, le reading down, l'interprétation large, l'interprétation atténuée, etc.!

Cet article a précédemment été publié par la Revue du Barreau.

From Word Embeddings to Large Vocabulary Neural Machine Translation

Dans ce mémoire, nous examinons certaines propriétés des représentations distribuées de mots et nous proposons une technique pour élargir le vocabulaire des systèmes de traduction automatique neurale. En premier lieu, nous considérons un problème de résolution d'analogies bien connu et examinons l'effet de poids adaptés à la position, le choix de la fonction de combinaison et l'impact de l'apprentissage supervisé. Nous enchaînons en montrant que des représentations distribuées simples basées sur la traduction peuvent atteindre ou dépasser l'état de l'art sur le test de détection de synonymes TOEFL et sur le récent étalon-or SimLex-999. Finalament, motivé par d'impressionnants résultats obtenus avec des représentations distribuées issues de systèmes de traduction neurale à petit vocabulaire (30 000 mots), nous présentons une approche compatible à l'utilisation de cartes graphiques pour augmenter la taille du vocabulaire par plus d'un ordre de magnitude. Bien qu'originalement développée seulement pour obtenir les représentations distribuées, nous montrons que cette technique fonctionne plutôt bien sur des tâches de traduction, en particulier de l'anglais vers le français (WMT'14).

A study of the large-scale structure of the wind of WR 134

Diverses méthodes ont été utilisées pour étudier les étoiles Wolf-Rayet (WR) dans le but de comprendre les phénomènes physiques variés qui prennent place dans leur vent dense. Pour étudier la variabilité qui n'est pas strictement périodique et ayant des caractéristiques différentes d'une époque à l'autre, il faut observer pendant des périodes de temps suffisamment longues en adopter un échantillonnage temporel élevé pour être en mesure d'identifier les phénomènes physiques sous-jacents. À l'été 2013, des astronomes professionnels et amateurs du monde entier ont contribué à une campagne d'observation de 4 mois, principalement en spectroscopie, mais aussi en photométrie, polarimétrie et en interférométrie, pour observer les 3 premières étoiles Wolf-Rayet découvertes: WR 134 (WN6b), WR 135 (WC8) et WR 137 (WC7pd + O9). Chacune de ces étoiles est intéressante à sa manière, chacune présentant une variété différente de structures dans son vent. Les données spectroscopiques de cette campagne ont été réduites et analysées pour l'étoile présumée simple WR 134 pour mieux comprendre le comportement de sa variabilité périodique à long terme dans le cadre d'une étude des régions d'interactions en corotation (CIRs) qui se retrouvent dans son vent. Les résultats de cette étude sont présentés dans ce mémoire.

Modified Large Margin Nearest Neighbor Metric Learning for Regression

The main objective of this letter is to formulate a new approach of learning a Mahalanobis distance metric for nearest neighbor regression from a training sample set. We propose a modified version of the large margin nearest neighbor metric learning method to deal with regression problems. As an application, the prediction of post-operative trunk 3-D shapes in scoliosis surgery using nearest neighbor regression is described. Accuracy of the proposed method is quantitatively evaluated through experiments on real medical data.

Molecular Genetic Characterization of Endemic Yellow Catfish, Horab rus brachysoma (Gunther)

The present study Molecular genetic characterization of endemic yellow catfish ,generated an important information on the genetic variation and stock structure of the endangered yellow catfish(Horabagrus brachysoma) endemic to the western Ghats. Three genetically discrete stocks of the species have been identified for the first time using allozymes, RAPD(Random Amplified Polymorphic DNA) and microsatelite markers and it is a significant step towards realizing the goal of management of fishery and conservation of the yellow catfish populations in the rivers of the Western Ghats region. In conclusion genetic markers were found to be powerful tools to analyze the population genetic structure of the yellow catfish. Geographic isolation by land distance,inbreading as a result of over-exploitation etc are some reasons for the genetic differenciation between the pairs and deficiency of hetrozygosity revealed by the two co dominant markers, allozyme, and microsatelites.the study emphasizes the need for stock-wise, propagation assisted-rehabilitation of the natural populations yellow catfish

A comparative study of medium and large pore zeolites in alkylation reactions

In this thesis an attempt has been made to compare the catalytic activity of some medium and large pore zeolites in a few alkylation and acylation reactions. The work reported in the present study is basically centered around the following zeolites namely, ZSM-5, mordenite, zeolite Y and beta. The major reactions carried out were benzoylation of o-xylene, propionylation of toluene and anisole and benzylation of 0xylene.The programme involves the synthesis, modifications and characterization of the zeolite catalysts by various methods. The influence of various parameters such as non-framework cations, Si/AI ratio of zeolites, temperature of the reaction, catalyst concentration, molar ratio of the reactants and recycling of the catalysts were also examined upon the conversion of reactants and the formation of the desired products in the alkylation / acylation reactions.The general conclusions drawn by us from the results obtained are summarized in the last chapter of the thesis. Zeolite beta offers interesting opportunities as a potential catalyst in alkylation reactions and the area of catalysis by medium and large pore zeolites is very fascinating and there is plenty of scope for further research in this field. Moreover, zeolite based catalysts are effective in meeting current industrial processing and more stringent environment pollution limits.

Two Dimensional Large Amplitude Quasi Solitons in Thin Helium Films

Large amplitude local density fluctuations in a thin superfluid He film is considered. It is shown that these large amplitude fluctuations travel and behave like "quasi-solitons" under collision, even when the full nonlinearity arising from the Van der Waals potential is taken into account.

Current-density-functional approach to large quantum dots in intense magnetic fields

Within current-density-functional theory, we have studied a quantum dot made of 210 electrons confined in a disk geometry. The ground state of this large dot exhibits some features as a function of the magnetic field (Beta) that can be attributed in a clear way to the formation of compressible and incompressible states of the system. The orbital and spin angular momenta, the total energy, ionization and electron chemical potentials of the ground state, as well as the frequencies of far-infrared edge modes are calculated as a function of Beta, and compared with available experimental and theoretical results.

“A comparative study of medium and large pore zeolites in alkylation reactions”

Zeolites have established themselves as industrial catalysts for over two decades for a variety of hydrocarbon processing reactions where acidity and shape selectivity are important factors. As solid catalysts, zeolites may be advantageous and superior compared to their homogenous counterparts due to their characteristic properties. It is only in recent years that the utility of zeolites for organic synthesis is recognized for producing specific organic intermediates and fine chemicals in high selectivity. In this thesis an attempt has been made to compare the catalytic activity of some medium and large pore zeolites in a few alkylation and acylation reactions. The work reported in the present study is basically centered around the following zeolites namely, ZSM-5, mordenite, zeolite Y and beta. The major reactions carried out were benzoylation of o-xylene, propionylation of toluene and anisole and benzylation of oxylene. . The programme involves the synthesis, modifications and characterization of the zeolite catalysts by various methods. The influence of various parameters such as non-framework cations, Si/Al ratio of zeolites, temperature of the reaction, catalyst concentration, molar ratio of the reactants and recycling of the catalysts were also examined upon the conversion of reactants and the formation of the desired products in the alkylation/ acylation reactions. The general conclusions drawn by us from the results obtained are summarized in the last chapter of the thesis. Zeolite beta ofi'ers interesting opportunities as a potential catalyst in alkylation reactions and the area of catalysis by medium and large pore zeolites is very fascinating and there is plenty of scope for further research in this field. Moreover, zeolite based catalysts are effective in meeting current industrial processing and more stringent environment pollution limits.

Large enhanced dielectric permittivity in polyaniline passivated core-shell nano magnetic iron oxide by plasma polymerization

Commercial samples of Magnetite with size ranging from 25–30nm were coated with polyaniline by using radio frequency plasma polymerization to achieve a core shell structure of magnetic nanoparticle (core)–Polyaniline (shell). High resolution transmission electron microscopy images confirm the core shell architecture of polyaniline coated iron oxide. The dielectric properties of the material were studied before and after plasma treatment. The polymer coated magnetite particles exhibited a large dielectric permittivity with respect to uncoated samples. The dielectric behavior was modeled using a Maxwell–Wagner capacitor model. A plausible mechanism for the enhancement of dielectric permittivity is proposed

Spray pyrolysed In2S3 thin films: A potential electron selective layer for large area inverted bulk-heterojunction polymer solar cells

In this paper, we report the results of investigations on the potential of spray pyrolysis technique in depositing electron selective layer over larger area for the fabrication of inverted bulk-heterojunction polymer solar cells. The electron selective layer (In2S3) was deposited using spray pyrolysis technique and the linear heterojunction device thus fabricated exhibited good uniformity in photovoltaic properties throughout the area of the device. An MEH-PPV:PCBM inverted bulk-heterojunction device with In2S3 electron selective layer (active area of 3.25 3.25 cm2) was also fabricated and tested under indoor and outdoor conditions. Fromthe indoor measurements employing a tungsten halogen lamp (50mW/cm2 illumination), an opencircuit voltage of 0.41V and a short-circuit current of 5.6mA were obtained. On the other hand, the outdoor measurements under direct sunlight (74mW/cm2) yielded an open-circuit voltage of 0.46V and a short-circuit current of 9.37mA