Annual 10Be concentrations from Lakes Tiefer See and Czechowskie AD1983-2009

Beryllium 10 concentrations (10Becon) were measured at annual resolution from varved sediment cores of Lakes Tiefer See (TSK) and Czechowskie (JC) for the period 1983-2009 (~solar cycles 22 and 23). Calibrating the 10Becon time-series against complementing proxy records from the same archive as well as local precipitation and neutron monitor data, reflecting solar forced changes in atmospheric radionuclide production, allowed (i) identifying the main depositional processes and (ii) evaluating the potential for solar activity reconstruction. 10Becon in TSK and JC sediments are significantly correlated to varying neutron monitor counts (TSK: r=0.5, p=0.05, n=16; JC: r=0.46, p=0.03, n=22). However, the further correlations with changes in organic carbon contents in TSK as well as varying organic carbon and detrital matter contents in JC point to catchment specific biases in the 10Becon time-series. In an attempt to correct for these biases multiple regression analysis was applied to extract an atmospheric 10Be production signal (10Be atmosphere). To increase the signal to noise ratio a 10Be composite record (10Be composite) was calculated from the TSK and JC 10Be atmosphere time-series. 10Becomposite is significantly correlated to variations in the neutron monitor record (r=0.49, p=0.01, n=27) and matches the expected amplitude changes in 10Be production between solar cycle minima and maxima. This calibration study on 10Be from two sites indicates the large potential but also, partly site-specific, limitations of 10Be in varved lake sediments for solar activity reconstruction.

Abundance of zooplankton based on a long-term study at the Galata transect and covers the spring-summer periods from 1967 till 2005

The dataset is based on a long-term study (38 years) at the Galata transect and covers the spring-summer periods from 1967 till 2005. The whole dataset is composed of 360 data of total zooplankton biomass and abundance . Samples were collected in discrete layers 0-10m, 10-20m, 10-25m, 25-50m, 50-70m, 50-100m, 100-150. Mesozooplankton abundance: the collected material was analysed using the method of Domov (1959). Samples were brought to volume of 25-30 ml depending upon zooplankton density and mixed intensively until all organisms were distributed randomly in the sample volume. After that 5 ml of sample was taken and poured in the counting chamber for taxomomic identification and count. Large (> 1 mm body length) and not abundant species were calculated in whole sample. Counting and measuring of organisms were made in the Dimov chamber under the stereomicroscope to the lowest taxon possible. Taxonomic identification was done at the Institute of Fishery Resource by Prof. Asen Konsulov and Institute of Oceanology by Prof. Asen Konsulov, Lyudmila Kamburska and Kremena Stefanova using the relevant taxonomic literature (Mordukhay-Boltovskoy, F.D. (Ed.). 1968, 1969,1972). Taxon-specific mesozooplankton abundance: The collected material was analysed using the method of Domov (1959). Samples were brought to volume of 25-30 ml depending upon zooplankton density and mixed intensively until all organisms were distributed randomly in the sample volume. After that 5 ml of sample was taken and poured in the counting chamber for taxomomic identification and count. Copepods and Cladoceras were identified and enumerated; the other mesozooplankters were identified and enumerated at higher taxonomic level (commonly named as mesozooplankton groups). Large (> 1 mm body length) and not abundant species were calculated in whole sample. Counting and measuring of organisms were made in the Dimov chamber under the stereomicroscope to the lowest taxon possible. Taxonomic identification was done at the Institute of Fishery Resource by prof. Asen Konsulov and Institute of Oceanology by Prof. Asen Konsulov, Lyudmila Kamburska and Kremena Stefanova using the relevant taxonomic literature (Mordukhay-Boltovskoy, F.D. (Ed.). 1968, 1969,1972).

Reference list of 120 datasets from time series station Payerne used for exploratory search

The analysis of time-dependent data is an important problem in many application domains, and interactive visualization of time-series data can help in understanding patterns in large time series data. Many effective approaches already exist for visual analysis of univariate time series supporting tasks such as assessment of data quality, detection of outliers, or identification of periodically or frequently occurring patterns. However, much fewer approaches exist which support multivariate time series. The existence of multiple values per time stamp makes the analysis task per se harder, and existing visualization techniques often do not scale well. We introduce an approach for visual analysis of large multivariate time-dependent data, based on the idea of projecting multivariate measurements to a 2D display, visualizing the time dimension by trajectories. We use visual data aggregation metaphors based on grouping of similar data elements to scale with multivariate time series. Aggregation procedures can either be based on statistical properties of the data or on data clustering routines. Appropriately defined user controls allow to navigate and explore the data and interactively steer the parameters of the data aggregation to enhance data analysis. We present an implementation of our approach and apply it on a comprehensive data set from the field of earth bservation, demonstrating the applicability and usefulness of our approach.

Geochemistry and isotopes at DSDP Hole 79-546

At Site 546, below the Mazagan Escarpment at a water depth of 4 km, 36 m of salt rock was cored from the top of one of a field of salt domes. The core was studied by thin section and a variety of geochemical procedures. The salt rock contains 0.1 to 3% carnallite and lesser amounts of sylvite and polyhalite, which with the corresponding high level of bromide place it within the potash evaporite facies. The bromide profile is of a dominantly marine evaporite deposited in moderately shallow brine which, however, was not repeatedly desiccated. A mineralogical argument suggests that the brine surface was not below sea level. An average of about 5% elastics, with dispersed anhydrite, darken the salt rock to deep shades of red, brown, and gray green. Most of the included materials are in highly deformed boudins or dispersions in the salt rock that has also undergone cataclasis in a subsequent, probably tectonic, deformation. The salt rock is slightly deficient in anhydrite, and the usual separate beds and laminae of anhydrite are virtually absent. Stable isotope ratios of sulfur and oxygen in the sulfate are clearly derived from sea water of Permian to Scythian age, in contrast to the late Triassic or Early Jurassic age of evaporites onshore in Morocco and Portugal and the corresponding evaporites offshore Maritime Canada. In contrast to those evaporites off the axis of Atlantic rifting, the salt at Site 546 may have been deposited in a very early central rift fed by marine waters from Tethys through the Gibraltar or South Atlas fracture zones.

Decreased light availability can amplify negative impacts of ocean acidification on calcifying coral reef organisms

Coral reef organisms are increasingly and simultaneously affected by global and local stressors such as ocean acidification (OA) and reduced light availability. However, knowledge of the interplay between OA and light availability is scarce. We exposed 2 calcifying coral reef species (the scleractinian coral Acropora millepora and the green alga Halimeda opuntia) to combinations of ambient and increased pCO2 (427 and 1073 µatm, respectively), and 2 light intensities (35 and 150 µmol photons/m**2/s) for 16 d. We evaluated the individual and combined effects of these 2 stressors on weight increase, calcification rates, O2 fluxes and chlorophyll a content for the species investigated. Weight increase of A. millepora was significantly reduced by OA (48%) and low light intensity (96%) compared to controls. While OA did not affect coral calcification in the light, it decreased calcification in the dark by 155%, leading to dissolution of the skeleton. H. opuntia weight increase was not affected by OA, but decreased (40%) at low light. OA did not affect algae calcification in the light, but decreased calcification in the dark by 164%, leading to dissolution. Low light significantly reduced gross photosynthesis (56 and 57%), net photosynthesis (62 and 60%) and respiration (43 and 48%) of A. millepora and H. opuntia, respectively. In contrast to A. millepora, H. opuntia significantly increased chlorophyll content by 15% over the course of the experiment. No interactive effects of OA and low light intensity were found on any response variable for either organism. However, A. millepora exhibited additive effects of OA and low light, while H. opuntia was only affected by low light. Thus, this study suggests that negative effects of low light and OA are additive on corals, which may have implications for management of river discharge into coastal coral reefs.

Radiocarbon age, and sedimentation and accumulation rate of core JM05-G001 obtained during Jan Mayen cruise JM050704 to the Barents Sea

Instrumental monitoring of the climate at high northern latitudes has documented the ongoing warming of the last few decades. Climate modelling has also demonstrated that the global warming signal will be amplified in the polar region. Such temperature increases would have important implications on the ecosystem and biota of the Barents Sea. This study therefore aims to reconstruct the climatic changes of the Barents Sea based on benthic foraminifera over approximately the last 1400 years at the decadal to sub-decadal scale. Oxygen and carbon isotope analysis and benthic foraminiferal species counts indicate an overall warming trend of approximately 2.6°C through the 1400-year record. In addition, the well-documented cooling period equating to the 'Little Ice Age' is evident between c. 1650 and 1850. Most notably, a series of highly fluctuating temperatures are observed over the last century. An increase of 1.5°C is shown across this period. Thus for the first time we are able to demonstrate that the recent Arctic warming is also reflected in the oceanic micro-fauna.

(Table 1) Percentage of non-opaque heavy minerals, heavy residue, magnetite, and opaque heavy minerals, DSDP Sites 58-445 and 58-446

Heavy-mineral analyses were made for 39 samples, 27 from DSDP Site 445 and 12 from Site 446. About one-fourth of the samples were so loose that they were easily disaggregated in water. The amount of heavy residue and the magnetite content of the heavy fraction were very high, 0.2 to 44 per cent and (on the average) more than 20 per cent, respectively. Among the non-opaque heavy minerals, common hornblende (0 to 80%) and augite (0 to 98%) are most abundant. Pale-green and bluish-green amphiboles (around 10%) and the epidote group (a few to 48%) are next in abundance. Euhedral apatite and biotite and irregularly shaped chromite are not abundant, but are present throughout the sequence. Hacksaw structure is developed in pale-green amphibole and augite. At Site 445, a fair amount of chlorite and a few glauconite(?) grains are present from Core 445-81 downward. The content of common hornblende and opaque minerals also changes from Core 445-81 downward. A geological boundary may exist between Cores 445-77 and 445-81. Source rocks of the sediments at both sites were basaltic volcanic rocks (possibly alkali suite), schists, and ultramafic rocks. The degree of lithification and amount of heavy residue, and the content of magnetite, non-opaque heavy minerals (excluding mafic minerals), and mafic minerals in the cores were compared with Eocene, Oligocene, and Miocene sandstones of southwest Japan. In many respects, the sediments at Sites 445 and 446 are quite different from those of southwest Japan. From the early Eocene to the early Miocene, the area of these sites belonged to a different geologic province than southwest Japan.

Low-temperature magnetic remanence and hysteresis measurements on sediment core GeoB4901-8 from the Niger deep-sea fan

Low-temperature (LT) magnetic remanence and hysteresis measurements, in the range 300-5 K, were combined with energy dispersive spectroscopy (EDS) in order to characterize the magnetic inventory of strongly diagenetically altered sediments originating from the Niger deep-sea fan. We demonstrate the possibility of distinguishing between different compositions of members of the magnetite-ulvöspinel and ilmenite-hematite solid solution series on a set of five representative samples, two from the upper suboxic and three from the lower sulfidic anoxic zone of gravity core GeoB 4901. Highly sensitive LT magnetic measurements were performed on magnetic extracts resulting in large differences in the magnetic behavior between samples from the different layers. This emphasizes that both Fe-Ti oxide phases occur in different proportions in the two geochemical environments. Most prominent are variations in the coercivity sensitive parameter coercive field (BC). At room-temperature (RT) hysteresis loops for all extracts are narrow and yield low coercivities (6-13 mT). With decreasing temperature the loops become more pronounced and wider. At 5 K an approximately 5-fold increase in BC for the suboxic samples contrasts a 20-25-fold increase for the samples from the anoxic zone. We demonstrate that this distinct increase in BC at LT corresponds to the increasing proportion of the Ti-rich hemoilmenite phase, while Fe-rich (titano-)magnetite dominates the magnetic signal at RT. This trend is also seen in the room-temperature saturation isothermal remanent magnetization (RT-SIRM) cycles: suboxic samples show remanence curves dominated by Fe-rich mineral phases while anoxic samples display curves clearly dominated by Ti-rich particles. We show that the EDS intensity ratios of the characteristic Fe Kalpha and Ti Kalpha lines of the Fe-Ti oxides may be used to differentiate between members of the magnetite-ulvöspinel and ilmenite-hematite solid solution series. Furthermore it is possible to calculate an approximate composition for each grain if the intensity ratios of natural particles are linked to well-known standards. Thus, element spectra with high Fe/Ti intensity ratios were found to be rather typical of titanomagnetite while low Fe/Ti ratios are indicative of hemoilmenite. The EDS analyses confirm the LT magnetic results, Fe-rich magnetic phases dominate in the upper suboxic environment whereas Ti-rich magnetic phases comprise the majority of particles in the lower anoxic domain: The mineral assemblage of the upper suboxic environments is composed of magnetite (~19%), titanomagnetite (~62%), hemoilmenite (~17%) and ~2% other particles. In the lower anoxic sediments, reductive diagenetic alteration has resulted in more extensive depletion of the (titano-)magnetite phase, resulting in a relative enrichment of the hemoilmenite phase (~66%). In these strongly anoxic sediments stoichiometric magnetite is barely preserved and only ~5% titanomagnetite was detected. The remaining ~28% comprises Ti-rich particles such as pseudobrookite or rutile.

Hydrochemistry in the Irminger and Iceland Seas

This paper describes the ways and means of assembling and quality controling the Irminger Sea and Iceland Sea time-series biogeochemical data which are included in the CARINA data set. The Irminger Sea and the Iceland Sea are hydrographically different regions where measurements of sea water carbon and nutrient chemistry were started in 1983. The sampling is seasonal, four times a year. The carbon chemistry is studied with measurements of the partial pressure of carbon dioxide in seawater, pCO2, and total dissolved inorganic carbon, TCO2. The carbon chemistry data are for surface waters only until 1991 when water column sampling was initiated. Other measured parameters are salinity, dissolved oxygen and the inorganic nutrients nitrate, phosphate and silicate. Because of the CARINA criteria for secondary quality control, depth >1500 m, the IRM-TS could not be included in the routine QC and the IS-TS only in a limited way. However, with the information provided here, the quality of the data can be assessed, e.g. on the basis of the results obtained with the use of reference materials.

Grain size composition and geochemistry of volcaniclastic sediments in the Lau Basin

Early Pliocene to Pleistocene volcaniclastic sediments recovered during Ocean Drilling Program Leg 135 from Sites 834 to 839 in the Lau Basin show a wide range of chemical and mineralogical compositions extending the spectrum previously known from the Lau Basin, Lau Ridge and Tofua Arc. The following major types of volcaniclastics have been distinguished: (1) primary fallout ashes originating from eruptions on land, (2) epiclastic deposits that resulted from subaerial and submarine eruptions, (3) subaqueous fallout and pyroclastic flow deposits resulting from explosive submarine eruptions, and (4) hyaloclastites resulting from mechanical fragmentation and spalling of chilled margins of submarine pillow tubes and sheet-lava flows. Vitric shards are mostly basaltic andesitic to rhyolitic and broadly follow two major trends in terms of K2O enrichment: a low-K series (LKS) with about 1 wt% K2O at 70 wt% SiO2, and a very low-K series (VLKS) with only about 0.5 wt% K2O at 70 wt% SiO2. Sites 834 and 835 on "old" backarc basin crust, >4.2 and 3.4 m.y. old, comprise LKS rhyolites >3.3 m.y. old. Calc-alkaline basaltic turbidites originating from the Lau Ridge flowed in at 3.3 Ma. In the period from 3.3 to 2.4 Ma basaltic andesitic to rhyolitic, fine-grained LKS and VLKS volcaniclastics were deposited by turbidity currents and subaerial fallout. Three thin, discrete fallout layers (2.4-3.2 m.y. old) with high-K calc-alkaline compositions probably erupted in New Zealand. Volcaniclastics from Site 836, all <0.6 m.y. old, make up 24% of the sediments and comprise local basaltic andesitic to andesitic hyaloclastites with low Ba/Zr ratios of 0.9 to 1.4 and polymict andesitic sediments with Ba/Zr ratios of up to 5.5, containing clasts altered to lower greenschist facies. In Sites 837-839, drilled on young crust (1.8-2.1 m.y. old), volcaniclastics make up 45%-64% of the total sediment. Glass compositions are often bimodal with a mafic and a rhyolitic population. Large-volume rhyolitic, silt- to lapilli-sized volcaniclastics are interpreted as pyroclastic flows from explosive eruptions on a seamount 25-50 km away from the sites. Ba/Zr ratios are 2 to 4, partially overlapping with some Lau Basin basement lavas that show an "arc" signature, and they can reach values >5 in thin volcaniclastic layers <0.6 m.y. old.

High resolution in situ microsensor measurements of oxygen and temperature at a vesicomyid clam colony in the Japan Deep Sea Trench

Oxygen penetration depth and temperature at the rim of the clam colony was measured with a small deep-sea microprofiler module (Treude et al., 2009), carrying 3 oxygen Clark-type microelectrodes (Revsbech et al., 1980) and one temperature sensor (Pt100, UST Umweltsensorentechnik GmbH, Germany). High-resolution microprofiles across the sediment-water interface were measured with a vertical resolution of 100 µm on a total length of 15 cm. Oxygen electrodes had a linear response to the oxygen concentration in seawater and were calibrated in situ using constant readings in the bottom water (oxygen concentration determined by Winkler titration) and the anoxic parts of the sediment.