Composite Resin to Yttria Stabilized Tetragonal Zirconia Polycrystal Bonding: Comparison of Repair Methods

Purpose: The purpose of the current study was to evaluate different approaches for bonding composite to the surface of yttria stabilized tetragonal zirconia polycrystal (Y-TZP) ceramics.Methods: One hundred Y-TZP blocks were embedded in acrylic resin, had the free surface polished, and were randomly divided into 10 groups (n=10). The tested repair approaches included four surface treatments: tribochemical silica coating (TBS), methacryloxydecyldihidrogenphosphate (MDP)-containing primer/silane, sandblasting, and metal/zirconia primer. Alcohol cleaning was used as a "no treatment" control. Surface treatment was followed by the application (or lack thereof) of an MDP-containing resin cement liner. Subsequently, a composite resin was applied to the ceramic surface using a cylindrical mold (4-mm diameter). After aging for 60 days in water storage, including 6000 thermal cycles, the specimens were submitted to a shear test. Analysis of variance and the Tukey test were used for statistical analyses (alpha=0.05).Results: Surface treatment was a statistically significant factor (F=85.42; p<0.0001). The application of the MDP-containing liner had no effect on bond strength (p=0.1017). TBS was the only treatment that had a significantly positive effect on bond strength after aging.Conclusion: Considering the evaluated approaches, TBS seems to be the best surface treatment for Y-TZP composite repairs. The use of an MDP-containing liner between the composite and Y-TZP surfaces is not effective.

Adhesive Quality of Self-adhesive and Conventional Adhesive Resin Cement to Y-TZP Ceramic Before and After Aging Conditions

Purpose: This study evaluated the adhesive quality of simplified self-adhesive and conventional resin cements to Y-TZP in dry and aged conditions. Methods: Y-TZP ceramic blocks (N=192) (5 x 5 x 2 mm) were embedded in acrylic resin and randomly divided into two groups, based on surface conditioning: 96% isopropanol or chairside tribochemical silica coating and silanization. Conditioned ceramics were divided into four groups to receive the resin cements (Panavia F 2.0, Variolink II, RelyX U100 and Maxcem). After 24 hours, half of the specimens (n=12) from each group were submitted to shear bond strength testing (0.5 nun/minute). The remaining specimens were tested after 90 days of water storage at 37 degrees C and thermocycling (12,000x, 5 degrees C-55 degrees C). Failure types were then assessed. The data were analyzed using three-way ANOVA and the Tukey's test (alpha=0.05). Results: Significant effects of ceramic conditioning, cement type and storage conditions were observed (p<0.0001). The groups cleaned using alcohol only showed low bond strength values in dry conditions and the bond strength was reduced dramatically after aging. Groups conditioned using silica coating and silanization showed higher bond strengths both in dry and aged conditions. A high number of specimens failed prematurely prior to testing when they were cleaned using 96% isopropanol. Conclusion: Overall, silica coating and silanization showed higher, stable bond strengths with and without aging. The durability of resin-ceramic adhesion varied, depending on the adhesive cement type.

The primary sources of carbon loss during the crop-establishment period in a subtropical Oxisol under contrasting tillage systems

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Flooding tolerance of Tabebuia cassinoides: Metabolic, morphological and growth responses

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

As variaveis relevo e 'solo' na distribuicao desigual da umidade do solo. Avaliacao preliminar.

In a general way the analysis of soil water content enabled one to define which of the colluvium units hold larger water retention capacity. They are: Bela Vista, Piracema I, Campo Alegre, Bom Retiro and Treviso II. These results suggest that the contact zones among alostratigraphic units with high and low water retention capacity are potential zones for the generation of subsurface flow (throughflow). -from English summary

Alterações de fluidos corpóreos na rã Leptodactylus fuscus durante a estivação (Anura, Leptodactylidae).

The frog, L. fuscus, becomes dormant during the dry season in southeastern Brazil. Plasma and urine were obtained and analyzed for K+, Na+, and osmotic concentrations in active and estivating frogs. Soil water potential from the estivation sites was compared with the osmotic concentrations of the frog. Plasma and urine osmotic concentrations (286.2 +/- 13.8 and 242.3 +/- 17.2 mOsm1(-1), respectively) were higher in the estivating than in active frogs (240.3 +/- 12.8 and 112.7 +/- 15.6 mOsm1(-1); plasma and urine), and the same holds true for plasma K+ content. The Na+ concentration was the same for active and estivating frogs. Soil water potential corresponded to osmotic pressure of 110 mOsm1(-1), showing that L. fuscus may uptake water from the soil during the estivation.

Resistência ao Cisalhamento de um Latossolo sob Diferentes uso e Manejo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Effects of dentin collagen removal on microleakage of bonded restorations

Purpose: To evaluate the effects of removing dentin collagen exposed by acid etching on the microleakage of bonded restorations with and without flowable composite application and submitted to thermocycling and long-term water storage. Materials and Methods: Standardized Class V cavities were prepared in 180 bovine incisors. They were randomly assigned to three groups according to the adhesive technique used. Conventional group (C): Single Bond was applied according to the manufacturer's instructions and Z250 composite was placed. Hypochlorite group (H): After acid etching a 10% NaOCl aqueous solution was applied for 1 min, then Single Bond and Z250 were applied. Hypochlorite and Flowable group (HF): Similar to group H, but following adhesive application, a thin layer of Natural Flow flowable composite was applied before the Z250. Each group was divided into three subgroups (0, 6, 12), which remained immersed in distilled water for 24 h or 6 or 12 months and underwent 500, 1500 or 2500 thermal cycles, respectively. At the end of each storage time, the specimes were stained with silver nitrate, decalcified, immersed in methyl salicylate for clearing and observed under a stereomicroscope to determine microleakage (scores 0 to 4). The data were analyzed using the Kruskal-Wallis and the Multiple Comparison Tests (α = 0.05). Results: After 12 months, every group showed significant increases in microleakage. There was no significant difference between Groups H and HF for the three different periods of time, but they showed statistically less microleakage than Group C. Conclusion: The removal of dentinal collagen reduced the marginal microleakage when compared to the conventional technique. The use of the flowable composite did not produce significant effects. No technique was completely effective in preventing microleakage.

Pollution by hexachlorobenzene and pentachlorophenol in the coastal plain of São Paulo state, Brazil

Organochlorine compounds were dumped by chemical industries during the 1970s in many areas of the coastal plain of São Paulo state in Brazil. These dumps, located on hillsides and in valleys, in both rural and urban environments, are responsible for soil and water pollution. The objective of this work was to determine how the pollutants have spread in an area occupied by a spodosol-type soil mantle. The study combines soil morphological observations with soil and water analysis of hexachlorobenzene (HCB) and pentachlorophenol (PCP) in soil toposequences. The results indicate that the highest pollutant concentrations are observed near the dump site and that the compounds contamination is increasing. A map integrating topography and chemical concentrations was created to visualize the spatial distribution of HCB levels in the landscape. Physical and chemical analyses were performed to measure HCB and PCP levels in the soil. Soil water appears to act as a vector of HCB, probably through complexation with and dispersal of dissolved organic matter. The persistence of HCB at the studied site is most likely due to the low pH values in combination with a high content of organic matter. HCB was consistently found in higher concentrations than PCP. It is plausible that the cause of this difference is that PCP is degraded more easily under sunlight than HCB and that degradation of PCP under acid conditions leads to the formation of HCB. © 2003 Published by Elsevier B.V.

Indicadores de floresta urbana a partir de imagens aéreas multiespectrais de alta resolução

The present work evaluated urban forest indicators, acquired through airborne high-resolution multiespectral images, on the quality of the urban design and its vegetative fraction, in special its trees, in nine neighborhoods of Piracicaba, SP. There were made supervised classifications for characterization of intra-urban elements and the proportions obtained, as exposed soil, tree cover, lawns, asphalt, concrete pavements and roofs. They were studied for the measurement of the urban forest in each place. These variables were related to each other, as well as with the independent variables: population density, people with more than fifteen years of study and family heads with income above twenty minimum wages, obtained through population census. Through the analysis of linear regression variables were identified for intra-urban areas evaluation. Correlations were made and linear regressions among the data obtained from the image and among the proposed indicators. Negative correlations were obtained among population density and arboreal covering and the evaluated indices, in accordance with the predicted in the literature. Composite indicators are proposed, as: the proportion between arboreous space on waterproof space (PAW) and the proportion between arboreous space on building space (PAB). It is concluded by the possibility of the use of those indicators for evaluation of the urban forest and definition of priorities in the execution of ordinances to the improvement of the urban forestry, being prioritized the application of resources in the most lacking neighborhoods.

Reflorestamento compensatório com vistas à retençãode água no solo da bacia hidrográfica do Córrego Palmital, Jaboticabal, SP

This work had as objective to quantify the reforestation for water retention in the Palmital Stream watershed, County of Jaboticabal, SP, by using the methodology of compensatory forestation for retention of water in watersheds. This methodology esteems the retention of water in watersheds considering the world medium value of destiny of the water in the hydrologic cycle, the use/occupation of the soil (forest, pasture and agriculture) and its permeability. The watershed in this study presents an area of 10,625.21 ha, being 237.75 ha at forest, 467.01 ha in pasture and 9,237.57 ha in agriculture. The medium values of the permeability identified in the soils were of 94.81 mm h -1 in forest, 8.99 mm t -1 in pasture and 36.01 mm h -1 in agriculture (sugar cane). Considering that should infiltrate in the soil 20.55% of the water that precipitates on the watershed, and, that the losses of water in forest areas is considered standard, the total estimated volume to compensate the excessive loss that occur in the areas of pasture and agriculture is 12.21 million of m 3ano. The compensatory forestation to retain that volume of loss should contemplate an area of 942.73 ha (8.87% of the area of the watershed). The reforestation can be priority in permanent conservation area or in areas of Legal Reserve.

Propriedades físicas e infiltração de água de um Latossolo Vermelho Amarelo (Oxisol) do noroeste do estado de São Paulo, Brasil, sob três condições de uso e manejo

This study presents the results obtained in a field experiment carried out at Glicério, Northwest of São Paulo state, Brazil, whose objective was to analyze changes of selected soil physical properties and water infiltration rates on a Yellow-Red Latosol, under three different management conditions. The experimental design was arranged as completely randomized split-block with twelve treatments, which corresponded to four depths (0-0.05 m; 0.05-0.10 m; 0.10-0.20 m and 0.20-0.40 m) and three conditions of soil use and management with four replications. The soil surface conditions were: conventional tillage (one disking with moulboard plus two levelling passes with harrow), nine months before starting filed experiences; recent conventional tillage (also one disking with moulboard plus two levelling passes with harrow) and native forest. The conventional tillage areas were cropped for about fifteen years with annual cultures. The considered soil general physical properties were: macroporosity, microporosity, total porosity, bulk density, soil moisture and penetration resistance and, in addition; soil water infiltration rates were also recorded. According to our results, differences on general soil physical properties and infiltration rates appeared when both tilled sub-treatments and native forest were compared. Both, plots recently prepared by conventional tillage and those prepared by tillage but left nine months in rest, presented a statistically significant decrease of constant (final) water infiltration rates of 92.72% and 91.91% when compared with native forest plots.

Orientação geográfica de estufas de polietileno e potenciais de água no solo no cultivo do melão rendilhado híbrido 'nero'

This study aimed to verify the effects of four different minimum soil watler potentials (-30, -40, -50 e -70 kPa) and two different plastic tunnel positions (North-South and East-West) on net melon yield. The results showed that in the East-West position the yield and fruit weight were higher than in the North-South position. The highest yields of melon crop were obtained from -30 kPa. to -40 kPa minimum soil water potential.

Fatigue resistance of the bond of a glass-infiltrated alumina ceramic to human dentin

Purpose: To evaluate the fatigue resistance of the bond between dentin and glass-infiltrated alumina ceramic, using different luting protocols. Materials and Methods: The null hypothesis is that the fatigue resistance varies with the luting strategy. Forty blocks of In-Ceram Alumina were prepared, and one surface of each block was abraded with 110-μm aluminum oxide particles. Then, the blocks were luted to flat dentin surfaces of 40 human third molars, using 4 different luting strategies (luting system [LS]/ceramic surface conditioning [CSC]) (n=10): (G1) [LS] RelyX-Unicem/[CSC] airborne abrasion with 110-μm Al2O3 particles; (G2) [LS] One-Step + Duo-Link (bis-GMA-based resin)/[CSC] etching with 4% hydrofluoric acid + silane agent; (G3) [LS] ED-Primer + Panavia F (MDP-based resin)/[CSC] Al2O 3; (G4) [LS] Scotchbond1+RelyX-ARC (bis-GMA-based resin)/[CSC] chairside tribochemical silica coating (air abrasion with 30-μm SiO x particles + silane). After 24 h of water storage at 37°C, the specimens were subjected to 106 fatigue cycles in shear with a sinusoidal load (0 to 21 N, 8 Hz frequency, 37°C water). A fatigue survivor score was given, considering the number of the fatigue cycles until fracture. The failure modes of failed specimens were observed in a SEM. Results: G3 (score = 5.9, 1 failure) and G4 (score = 6, no failures) were statistically similar (p = 0.33) and had significantly higher fatigue resistance than G1 (score = 3.9, 5 failures) and G2 (score = 3.7, 6 failures) (p < 0.03). SEM analysis of fractured specimens of G1 and G2 showed that almost all the failures were between ceramic and cement. Conclusion: The MDP-based resin cement + sandblasting with Al2O3 particles (G3) and bis-GMA-based resin cement + tribochemical silica coating (G4), both using the respective dentin bonding systems, were the best luting protocols for the alumina ceramic. The null hypothesis was confirmed.

Produção de variedades de alface sob diferentes potenciais de água no solo em ambiente protegido

The knowledge of meteorological elements in protected environment is very important for commercial plants, because of possibility to produce for all the year according to the study conduced in Botucatu - SP, in order to evaluate the effects of different irrigation treatments on three lettuce cultivars. (Lisa, Crespa and American). The study was developed in a polyethilene tunnel with orientation northeast/southwest (NE/SW) and the fertigation through drip irrigation. Leaf number, head diameter, fresh weigh, dry weigh, meteorological elements and evaporation from minievaporimeters were determined. Four treatments of minimum soil water potential were applied: 20, 28, 35 and 45 kPa and the results showed the treatment -35 kPa showed the highest lettuce production and maximurn water efficiency use. The highest productions occurred in May/June, July/September and September/November, while the worst one was in February/April. There was not significant difference of dry mass production among the treatments, independently of the year period with exception of the Crespa cultivar which was superior in September/November. The south face showed the highest evaporation.