Selective excitation of concomitant electrochemiluminophores : tuning emission color by electrode potential

ECL in 3D: Selective electrogenerated chemiluminescence (ECL) of several ruthenium and iridium complexes simultaneously in solution can be controlled by electrode potential (see picture; λem=emission wavelength). These luminescent redox systems create a range of new possibilities for multi-analyte ECL detection, assessment of interdependent electrochemical/spectroscopic properties, and color tuning in light-emitting devices.

Impact of climate change on thermal comfort and energy performance in offices - a parametric study

This paper investigates the impact of climate change on comfort and energy performance in offices in relation to the influence of building design and occupants. It focuses on a typical cellular office room in the context of Athens, Greece, as input for a parametric study using the building simulation software EnergyPlus. Three different building design variations are combined with two different occupant scenarios and 4 different weather data sets for IPCC climate change scenario A2.

For naturally ventilated buildings adaptive thermal comfort is evaluated according to ASHRAE Standard 55 and EN 15251. For mixed mode context evaluation is focused on greenhouse gas emissions and peak heating / cooling loads. Results indicate significant impact of the climate change on thermal comfort, and deviations between both comfort models. Comparing climate change, building design and occupant scenarios indicates that building design is the predominant influence on thermal comfort, whereas occupants are the predominant influence on greenhouse gas emissions.

Current distribution and Lorentz field modelling using cathode designs : a parametric approach

A mathematical model of magnetohydrodynamic (MHD) effects in an aluminium cell using numerical approximation of a finite element method is presented. The model predicts the current distribution in the cell and calculates the Lorentz force from the external magnetic field in molten metal for cathode blocks with different surface inclinations.

The findings indicated that the cathode surface inclinations have significant influence on cathode current density and Lorentz field distribution in the molten metal. The results establish a trend for the current density and associated MHD force distributions with increase in cathode inclination angle, φ. It has been found that cathode with φ = 5^o inclination could decrease 16 to 20 % of Lorentz force in the molten metal.

A parametric approach to 3D massing and density modelling

This paper addresses the current void between social agendas, environmental criteria and design methodology in urban planning through the implementation of new computational systems. It considers the application of digital design tools such as GIS and parametric systems towards more efficient and effective design solutions. The digital design methods have been developed and tested within Grimshaw Architects Design Technology Group on both Australian and international urban development projects. A methodology for the use of parametric design for urban design development is suggested for defining, simplifying and categorising planning and design strategies. The following tools are a means of generating urban design concepts as digital forms in order to better inform the designer during the design process.

A potential-controlled switch on/off mechanism for selective excitation in mixed electrochemiluminescent systems

We demonstrate the complete, rapid, and reversible switching between the emissions from two electrogenerated chemiluminescence (ECL) systems contained within the same solution, controlled by simple modification of the applied potential. The fundamental bases of the approach are the ability to selectively 'switch on' luminophores at distinct oxidation potentials, and an intriguing observation that the emission from the well-known electrochemiluminescent complex, fac-Ir(ppy)3, (where ppy is 2-phenylpyridinato), can be selectively 'switched-off' at high overpotentials. The dependence of this phenomenon on high concentrations of the co-reactant implicates quenching of the excited [Ir(ppy)3]* state by electron transfer. Rapid spectral scanning during modulation of the applied potential reveals well resolved maxima for mixtures comprising either green and red or green and blue luminophores, illustrating the vast potential of this approach for multiplexed ECL detection.

Responsive façades : parametric control of moveable tilings

The challenge of developing adaptive, responsive low-energy architecture requires new knowledge about the complex and dynamic interaction between envelope architecture, optimization between competing environmental performance metrics (light, heat and wind indices) and local climate variables. Advances in modeling the geometry of building envelopes and control technologies for adaptive buildings now permit the sophisticated evaluation of alternative envelope configurations for a set of performance criteria. 

Enhancement of transient stability limit and voltage regulation with dynamic loads using robust excitation control

In stressed power systems with large induction machine component, there exist undamped electromechanical modes and unstable montonic voltage modes. This article proposes a sequential design of an excitation controller and a power system stabiliser (PSS) to stabilise the system. The operating region, with induction machines in stressed power systems, is often not captured using a linearisation around an operating point, and to alleviate this situation a robust controller is designed which guaruntees stable operation in a large region of operation. A minimax linear quadratic Gaussian design is used for the design of the supplementary control to automatic voltage regulators, and a classical PSS structure is used to damp electromechanical oscillations. The novelty of this work is in proposing a method to capture the unmodelled nonlinear dynamics as uncertainty in the design of the robust controller. Tight bounds on the uncertainty are obtained using this method which enables high-performance controllers. An IEEE benchmark test system has been used to demonstrate the performance of the designed controller

Control of excitation and quenching in multi-colour electrogenerated chemiluminescence systems through choice of co-reactant

We demonstrate a new approach to manipulate the selective emission in mixed electrogenerated chemiluminescence (ECL) systems, where subtle changes in co-reactant properties are exploited to control the relative electron-transfer processes of excitation and quenching. Two closely related tertiary-amine co-reactants, tri-n-propylamine and N,N-diisopropylethylamine, generate remarkably different emission profiles: one provides distinct green and red ECL from [Ir(ppy)3] (ppy=2-phenylpyridinato-C2,N) and a [Ru(bpy)3](2+) (bpy=2,2'-bipyridine) derivative at different applied potentials, whereas the other generates both emissions simultaneously across a wide potential range. These phenomena can be rationalized through the relative exergonicities of electron-transfer quenching of the excited states, in conjunction with the change in concentration of the quenchers over the applied potential range.

A parametric study of a monolithic microfluidic system for on-chip biomolecular separation

A microfabricated poly(dimethylsiloxane) (PDMS) chip containing channel filled with polymer monolith has been developed for on-chip biomolecule separation. Methacrylate monolithic polymers were prepared by photo-initiated polymerization within the channel to serve as a continuous stationary phase. The monolithic polymer was functionalized with a weak anion-exchange ligand, and key parameters affecting the binding characteristics of the system were investigated. The total binding capacity was unaffected by the flow rate of the mobile phase but varied significantly with changes in ionic strength and pH of the binding buffer. The binding capacity decreased with increasing buffer ionic strength, and this is due to the limited available binding sites for protein adsorption resulting from cationic shielding effect. Similarly, the binding capacity decreased with decreasing buffer pH towards the isoelectric point of the protein. A protein mixture, BSA and ovalbumin, was used to illustrate the capacity of the methacrylate-based microfluidic chip for rapid biomolecule separation.