Impact of Carbon Dioxide Pressurization on Liquid Phase Organic Reactions: A Case Study on Heck and Diels–Alder Reactions

Heck coupling reactions of methyl acrylate with various aryl bromides have been investigated using a Pd/TPP catalyst in toluene under pressurized CO2 conditions up to 13 MPa. Although CO2 is not a reactant, the pressurization of the reaction liquid phase with CO2 has positive and negative impacts on the rate of Heck coupling depending on the structures of the substrates examined. In the case of either 2-bromoacetophenone or 2-bromocinnamate, the conversion has a maximum at a CO2 pressure of about 3 MPa;

Pt/C催化剂对乙醇电氧化的粒径效应

利用有机溶胶方法,通过控制溶剂挥发温度制备了具有不同粒径大小的Pt/C催化剂.制得的Pt/C催化剂中,Pt粒子具有非常优异的均一性和良好的分散度.电化学研究表明,对于乙醇的电催化氧化,Pt/C催化剂存在着明显的粒径效应.当Pt粒子粒径为3.2nm时,Pt/C催化剂对乙醇的电催化氧化的质量比活性最佳.X射线光电子能谱(XPS)的研究显示,Pt/C催化剂对乙醇氧化的粒径效应与其零价Pt含量以及Pt粒子的比表面积密切相关.

Reduction of Eu3+ to Eu2+ in MAl2Si2O8 (M = Ca, Sr, Ba) in air condition

In general, the reduction of Eu3+ to Eu2+ in solids needs an annealing Process in a reducing atmosphere. in this paper, it is of great interest and importance to find that the reduction of Eu3+ to Eu2+ can be realized in a series of alkaline-earth metal aluminum silicates MAl2Si2O8 (M = Ca, Sr, Ba) just in air condition. The Eu2+-doped MAl2Si2O8 (M = Ca, Sr, Ba) powder samples were prepared in air atmosphere by Pechini-type sol-gel process. It was found that the strong hand emissions of 4f(6)5d(1)-4f(7) from Eu2+ were observed at 417, 404 and 373 nm in air-annealed CaAl2Si2O8, SrAl2Si2O8 and BaAl2Si2O8, respectively, under ultraviolet excitation although the Eu3+ precursors were employed. In addition, under low-voltage electron beam excitation, Eu2+-doped MAl2Si2O8 also shows strong blue or ultraviolet emission corresponding to 4f(6)5d(1)-4f(7) transition.

傅立叶变换拉曼光谱和红外光谱鉴别塑料

用傅立叶变换拉曼光谱、衰减全反射红外光谱和近红外光谱结合OPUS/Ident软件对添加不同填料、不同助剂的塑料进行鉴别分类。结果表明:分子光谱结合化学计量学鉴别塑料是一种快速可靠的方法。其中拉曼光谱和衰减全反射红外光谱能够直接区分样品,而近红外光谱非常类似,不能直接区分。但是用OPUS/Ident软件中的W ard算法处理这3种光谱后,得到的树形图能够将样品准确分类。

Studies on the solution structures of lanthanide(III) complexes of DTPA-BIN by NMR

The solution structures of diamagnetic lanthanide (III) complexes of DTPA-BIN (Ln = La, Y, Lu, Sc) have been investigated by H-1 NMR, C-13 NMR and 2D NMR. For each complex, two or more species of asymmetric conformations with little distinction were identified at room temperature. And their solution structures vary with the radius of the central metals. NMR spectra support the hypothesis that Sc3+ with smaller radius formed an eight-coordinated structure with DTPA-BIN, La3+ with larger radius formed nine- or ten-coordinated structures with DTPA-BIN, and Y (DTPA-BIN) and Lu (DTPA-BIN) had nine-coordinated solution structures. The solution structure of Gd (DTPA-BIN) was obtained from the similarity of radius between Gd3+ and Y3+, which is a nine-coordinated structure formed by three nitrogens, three acetate oxygens, two acetyl oxygens, one water molecule and a gadolinium(III) cation.

核磁共振法研究DTPA-BIN稀土配合物的溶液结构

用核磁共振方法研究了抗磁稀土配合物 Ln( DTPA-BIN) ( Ln=La,Y,Lu,Sc)的水溶液结构 . 1 H和1 3 C NMR谱的谱形特征表明 ,每一种配合物在水溶液中存在着两种以上不对称的异构体 ,异构体之间的差别较小 .并由 Y3+ 与 Gd3+ 离子半径的相似性推测出 Gd( DTPA-BIN)的溶液结构 ,即 DTPA-BIN分子提供 8个配位点 :3个骨架氮、 3个乙羧基氧及 2个酰胺氧 ,1个水分子占据另一个配位点 ,从而与 Gd3+ 形成了九配位结构 .溶液结构随中心金属离子半径不同而呈规律性变化

聚合物共混体系辐射交联反应中溶胶分数与辐照剂量间的关系

我们已建立了线性聚合物辐射交联反应中溶胶分数(S)与辐照剂量(R)间的关系式:R(S+S~(1/2))=1/q_0u_1+α_0R~β/q_0,(1)式中β是与高分子结构有关的参数β=2×10~(-3)T-g+0.206。(2)

一种新型导电聚合物离子选择电极

有机导电聚合物已成为新材料研究中的重要领域。本文首次用电化学法研制成功了一种检测掺杂阴离子的新型聚吡咯(PPY)导电聚合物离子选择电极。吡咯(PY)的电聚合实验参照文献[5]进行。用恒电流法和

Investigation of EscA as a chaperone for the Edwardsiella tarda type III secretion system putative translocon component EseC

Edwardsiella tarda is an important Gram-negative enteric pathogen affecting both animals and humans. It possesses a type III secretion system (T3SS) essential for pathogenesis. EseB, EseC and EseD have been shown to form a translocon complex after secretion, while EscC functions as a T3SS chaperone for EseB and EseD. In this paper we identify EscA, a protein required for accumulation and proper secretion of another translocon component, EseC. The escA gene is located upstream of eseC and the EscA protein has the characteristics of T3SS chaperones. Cell fractionation experiments indicated that EscA is located in the cytoplasm and on the cytoplasmic membrane. Mutation with in-frame deletion of escA greatly decreased the secretion of EseC, while complementation of escA restored the wild-type secretion phenotype. The stabilization and accumulation of EseC in the cytoplasm were also affected in the absence of EscA. Mutation of escA did not affect the transcription of eseC but reduced the accumulation level of EseC as measured by using an EseC-LacZ fusion protein in Ed. tarda. Co-purification and co-immunoprecipitation studies demonstrated a specific interaction between EscA and EseC. Further analysis showed that residues 31-137 of EseC are required for EseC-EscA interaction, Mutation of EseC residues 31-137 reduced the secretion and accumulation of EseC in Ed. tarda. Finally, infection experiments showed that mutations of EscA and residues 31-137 of EseC increased the LD50 by approximately 10-fold in blue gourami fish. These results indicated that EscA functions as a specific chaperone for EseC and contributes to the virulence of Ed. tarda.

越野移动机器人自动驾驶专家系统的研究

本文研究越野移动机器人驾驶专家系统等有关问题．首先介绍了系统的硬件支持环境，然后阐述了自动驾驶专家系统的总体结构，有关知识库的内容以及使用知识的各功能模块的作用与运行机理．该系统已部分得以应用，能够完全代替驾驶员完成各种驾驶操作，并能进行自主导航、运动规划、自动绕障、动态跟踪目标、原路返回以及示教再现等复杂任务。

龙游石窟洞室群稳定性分析及最佳旅游路线选择

The large ancient underground rock caverns in Longyou is an important component of grotto cultural. Current task facing the long-term preservation of these unmovable cultural relics is arduous and challenging. The deformation failure of the caverns' surrounding rock is deteriorating. The weathering velocity of these caverns is accelerating. With the strength of caverns' surrounding rock worsening, critical rocks were generated in local regions of the caverns' vault and posing a threat to the security of people passing by. Selection of a maximum-security route and construction a aisle in the caverns might be an efficient way to ensure the security of tourists and reach the target of long-term preservation. The deformation and destruction of the ancient underground caverns is primarily dominated by geological conditions and the special structure of caverns. Based on field investigation, several fundamental conditions for deformation and failure are recognized, and nine deformation and fracture patterns of the Longyou grotto are proposed. In order to judge the stability of caverns’ surrounding rock, the element safety coefficient method is presented. An explicit explanation for the meaning of the method is deduced using Mohr-Coulomb strength criterion. Numerical analyses are carried out in the dissertation through FLAC3D code. Through numerical analysis, the stress distribution regularities of the caverns’ roofs, piles and public side wall are analysed, and the stability properties of caverns’ surrounding rock are also assessed. At the same time, the element safety coefficient method is introduced to contrast the stability degree of different regions in caverns. The above analyses are bases for choosing the optimal tourism routes in the caverns of Longyou grotto. The impact of surface load on the stability of shallow buried cavities in Longyou grotto is evaluated, the results show that building load has significant influence on the stability of the No.1 cavern’s roof, pile and public side wall between the No.1 cavern and the No.2 cavern, pedestrian load has less impact on the stability of surrounding rock than building load. The principles for choosing the optimal tourism routes in the caverns are discussed. With these principles, the dissertation makes a systematic research on the geological analytic method, numerical analytic method and meeting tourism requirements method, which are used in selecting the optimal tourism routes in the caverns. In order to achieve the best effect in the process of tourism routes selection, the above three method are integrated through Theory of Engineering Geomechanics Meta-system(EGMS). According to field investigations, numerical analyses, tourism requirements and expert experiences, the optimal tourism routes through No.1 to No.5 cavern are determined preliminarily. The obtained results from the research work are useful for the security aisle's construction, they also have reference value to other projects in practice.

广西都安瑶族自治县农业可持续发展的生态安全评价

以广西都安瑶族自治县为例,建立都安农业可持续发展生态安全评价指标体系,对都安农业可持续发展进行生态安全评价,进而作出生态安全区划,并提出了不同生态安全区的土地利用与生态安全建设对策。

喀斯特低热河谷石漠化区环境梯度的小气候效应——以贵州花江峡谷区小流域为例

对典型喀斯特石漠化小流域区4 种石漠化等级(潜在(L) 、轻度(SL) 、中度(M) 、强度(ST) ) 样地的小气候特征进行了监测,对比分析了它们的气温、相对湿度、光强分布和土壤温度、湿度分布状况和日变化动态。结果表明,各等级石漠化样地内光照强度、气温及其变动幅度的大小顺序为ST > M >SL > L ;土温和土壤湿度及其变动幅度为M > ST > SL > L ;大气相对湿度及其变动幅度为ST > M > SL> L 。强度石漠化样地内日平均相对湿度雨季仅76 % ,旱季只有51 % ,分别与潜在石漠化相差13 %和35 %;光照强度为潜在的4 倍以上;雨季气温高3 ℃;表土(5 cm) 土温最高相差1615 ℃;日均表土含水率低4197 %。随着石漠化程度的加深,退化生态系统的环境调蓄能力逐渐减弱。

Rede de adaptação de cultivares de aipim e mandioca para o nordeste brasileiro.

Peso da parte aérea, Nossa Senhora das Dores; Peso de raízes, Nossa Senhora das Dores; Teor de matéria seca de raíz, Nossa Senhora das Dores; Teor de amido, Nossa Senhora das Dores; Peso da parte aérea, Lagarto; Peso de raízes, Lagarto; Teor de matéria seca de raíz, Lagarto; Teor de amido, lagarto; Altura da planta, Lagarto; Altura da 1º ramificação, Lagarto; peso da parte aérea, Umbaúba; Peso de raíz, Umbaúba; Teor de matéria seca de raíz, Umbaúba; Teor de amido, Umbaúba; Altura da planta, Umbaúba; Altura da 1º ramificação, Umbaúba; comprimento de raíz, Umbaúba; Ensaio de variedades e híbridos de mandioca; Avaliação de cultivares de mandioca no período 2004/2006; Peso da parte aérea, Nossa Senhora das Dores; peso de raízes, Nossa Senhora das Dores; Índice de colheita, Nossa Senhora das Dores; Teor de matéria seca de raíz, Nossa Senhora das Dores; Teor de amido, Nossa Senhora das Dores

Ocorrência de podridão em espigas de milho em Sergipe.

2009