Confecção e caracterização físico-química de filmes compósitos autossustentáveis NaAlg-TiO2-WO3

A new self-sustainable film was prepared through the sol-gel modified method, previously employed in our research group; sodium alginate was used as the polymer matrix, along with plasticizer glycerol, doped with titanium dioxide (TiO2) and tungsten trioxide (WO3). By varying WO3 concentration (0,8, 1,6, 2,4 and 3,2 μmol) and keeping TiO2 concentration constant (059 mmol), it was possible to study the contribution of these oxides on the obtained films morphological and electrical properties. Self-sustainable films have analyzed by Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XDR), Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectroscopy (EDS) and Electrochemical Impedance Spectroscopy (EIS). By the IR specters, it was possible identify the TiO2, and posteriorly WO3, addition has provided dislocation of alginate characteristics bands to smaller vibrations frequencies indicating an electrostatic interaction between the oxides and the polymer matrix. Diffractograms show predominance of the amorphous phase in the films. SEM, along with EDX, analysis revealed self-sustainable films showed surface with no cracks and relative dispersion of the oxides throughout the polymer matrix. From Impedance analysis, it was observe increasing WO3 concentration to 2,4 μmol provided a reduction of films resistive properties and consequent improvement of conductive properties

Síntese, caracterização de ferritas espinélio com propriedades magnéticas e absorvedoras de microondas

Were synthesized spinel-type ferrites with general formula Ni0,8Mg0.2-xMxFe2O4, where M represents the doping Mn, Co or Mn + Co simultaneously, x ranges for the values 0.02, 0.05 and 0.1. The value of x was divided by 2 in cases where M equals Mn and Co conjugates. We used the citrate precursor method and heat treatment to obtain the phases at 1100°C. The materials were characterized by XRD, TGA/ DTGA, SEM, MAV and reflectivity measurements by the method of waveguide. Powders to 350°C/3.5 h were crystalline and nanosized. According to the results this temperature all powders have a percentage of ferrite phase over 90%. The composition had the addition of Mn and Co simultaneously showed a higher percentage of secondary phase NiO, 5.8%. The TGA/DTGA curves indicate that this sample reached phase (s) crystalline (s) at lowest temperatures. The X-ray diffractograms of the samples calcined at 350°C and 1100°C were treated with the Rietveld refinament technique. The powders calcined at 1100 °C/3h in air show to be 100% except spinel phase composition with 0.02 doping. The micrographs show clusters of particles with sizes smaller than 1 μm in calcination temperature of 1100°C which agreed with the result of Rietveld refinement. In the compositions doped with Mn were higher values of magnetization (45.90 and 53.20 Am2/kg), which did not cause high microwave absorption. The theoretical calculation of magnetization (MT) was consistent with the results, considering that there was agreement between the increase of magnetization experimental and theoretical. It was observed that there was the interrelation of the final effect of absorption with the thickness of MARE, the composition of ferrimagnetic materials and in particular the specific values of frequency. The analysis shows that the reflectivity increases in the concentration of cobalt increased the frequency range and also for absorption 10.17 GHz and 84%, respectively. The best result of chemical homogeneity and the value of 2.96 x 10-2 tesla coercive field were crucial for high performance ferrite absorber with 0.1 cobalt. The Cobalt has high magnetocrystalline anisotropy, it is associated with an increased coercive field, Hc. Therefore, this property improves the results of reflectivity of spinel ferrites

Diagnosis of inflammatory lesions by high-wavenumber FT-Raman spectroscopy

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Trajectory of neutron-neutron-C-18 excited three-body state

The trajectory of the first excited Efimov state is investigated by using a renormalized zero-range three-body model for a system with two bound and one virtual two-body subsystems. The approach is applied to n-n-C-18, where the n-n virtual energy and the three-body ground state are kept fixed. It is shown that such three-body excited state goes from a bound to a virtual state when the n-C-18 binding energy is increased. Results obtained for the n-C-19 elastic cross-section at low energies also show dominance of an S-matrix pole corresponding to a bound or virtual Efimov state. It is also presented a brief discussion of these findings in the context of ultracold atom physics with tunable scattering lengths. (C) 2008 Elsevier B.V. All rights reserved.

Trajectory of virtual, bound and resonant Efimov states

The pole trajectory of Efimov states for a three-body alpha alpha beta system with alpha alpha unbound and alpha beta bound is calculated using a zero-range Dirac-delta potential. It is shown that a three-body bound state turns into a virtual one by increasing the alpha beta binding energy. This result is consistent with previous results for three equal mass particles. The present approach considers the n-n-(18)C halo nucleus. However, the results have good perspective to be tested and applied in ultracold atomic systems, where one can realize such three-body configuration with tunable two-body interaction.

LARGE ATOMIC and NUCLEAR THREE-BODY SYSTEMS: SCATTERING and BINDING

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Neutron-C-19 scattering near an Efimov state

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

On stick-slip homoclinic chaos and bifurcations in a mechanical system with dry friction

In this paper we consider a self-excited mechanical system by dry friction in order to study the bifurcational behavior of the arisen vibrations. The oscillating system consists of a mass block-belt-system which is self-excited by static and Coulomb friction. We analyze the system behavior numerically through bifurcation diagrams, phase portraits, frequency spectra and Poincare maps, which show the existence of nonhomoclinic and homoclinic chaos and a route to homoclinic chaos. The homoclinic chaos is also analyzed analytically via the Melnikov prediction method. The system dynamic is characterized by the existence of two potential wells in the phase plane which exhibit rich bifurcational and chaotic behavior.

Impact dampers for controlling chaos in systems with limited power supply

We investigate numerically the dynamical behavior of a non-ideal mechanical system consisting of a vibrating cart containing a particle which can oscillate back and forth colliding with walls carved in the cart. This system represents an impact damper for controlling high-amplitude vibrations and chaotic motion. The motion of the cart is induced by an in-board non-ideal motor driving an unbalanced rotor. We study the phase space of the cart and the bouncing particle, in particular the intertwined smooth and fractal basin boundary structure. The control of the chaotic motion of the cart due to the particle impacts is also investigated. Our numerical results suggests that impact dampers of small masses are effective to suppress chaos, but they also increase the final-state sensitivity of the system in its phase space. (C) 2004 Elsevier Ltd. All rights reserved.

On an Active Control for a Structurally Nonlinear Mechanical System, Taking Into Account an Energy Pumping

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Chaos control of a nonlinear oscillator with shape memory alloy using an optimal linear control: Part II: Nonideal energy source

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

On energy pumping, synchronization and beat phenomenon in a nonideal structure coupled to an essentially nonlinear oscillator

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

A note on the attenuation of the sommerfeld effect of a non-ideal system taking into account a MR damper and the complete model of a DC motor

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

On energy transfer phenomena, in a nonlinear ideal and nonideal essential vibrating systems, coupled to a (MR) magneto-rheological damper

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Principais normas e recomendações existentes para o controle de vibrações provocadas pelo uso de explosivos em áreas urbanas: parte II

As atividades que envolvem o uso de explosivos devem ser controladas, não só com relação ao desmonte de estruturas (rocha e outros materiais), mas também quanto a danos estruturais em edificações próximas (casas, edificações históricas, etc.) e outros impactos ambientais como vibração, propagação de ruídos, ultralançamentos e sobrepressão atmosférica. Tais atividades são regidas por normas técnicas que sugerem parâmetros de medição e limites definidos na avaliação de prováveis danos. No caso específico de minerações em áreas urbanas, a velocidade de vibração de partícula (Vp), normalmente expressa em mm/s, é o parâmetro que tem dado melhor correlação na avaliação de possíveis danos às estruturas civis, atribuídos às vibrações do terreno. As diferentes normas existentes apresentam valores de Vp que variam de 2mm/s para edifícios históricos até 150mm/s para construções em concreto armado. A maioria delas considera na avaliação de danos estruturais, além da velocidade, a freqüência da vibração. Algumas normas foram elaboradas com base em dados experimentais, analisando parâmetros como o tipo de construção e o material nela utilizados, outras se basearam apenas em valores empíricos, mas todas apresentam valores conservativos. A norma brasileira não avalia o parâmetro freqüência e não classifica os diferentes tipos de estruturas civis, restringindo-se ao valor resultante da velocidade de vibração como parâmetro medido, sendo, assim, limitada e deficiente em relação às normas internacionais. A coletânea aqui apresentada reuniu as normas nas Américas e em outros continentes, além de uma comparação com as normas européias mais importantes em âmbito mundial.