Produção de hidrogênio por reforma a vapor de biogás

A new approach to generating clean energy has been studied by several researchers, among which one can highlight the steam reforming of biogas. The Biogas is result of decomposition of organic matter and it hasn’t been availed in the global level, instead, the biogas has been burned in flare or discarded into the atmosphere providing damage to the environment. The generation of vector biogas energy can be realized through its steam reforming and this work examines briefly the types of digesters used for biogas generation, studying the process of steam reforming to generate hydrogen as energy vector, analyzing each step in detail, seeking to adapt its main features an ethanol reformer for a biogas reformer. Besides this it is estimated the yield of the reform process and the boiler efficiency for efficiency of the process

Estabelecimento de rotinas de operação e orientações de manutenção para a planta termelétrica do DEN/FEG/UNESP

Steam generation plants have several industrial applications, being important for the national and global energetic matrix. Operational knowledge of steam plants is extremely important to forming a Mechanical Engineer. The facilities from Faculty of Engineering of Guaratingueta have a no operated steam pilot plant, named Thermal Machine Lab. Nowadays, the Energy Department from the faculty cannot explore this lab for its classes, even being essential to consolidate the theoretical concepts with tests simulating industrial applications. The goal of this project was to restore the operational condition of equipment of steam laboratory by fixing the equipment, and creating operational scripts for them. In a close future this lab could be used for classes, research and other applications

Aspectos técnicos e ambientais da incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e gaseificação do bagaço

The purpose of this work is to study the incorporation of hydrogen production (Case A) and the process of gasification of sugarcane bagasse associated with combined cycle gas turbine and steam turbine (Case B) for Distillery Pioneers process. These technologies can be used to improve the energy supply in the sugarcane mill. Initially the processes for obtaining sugar and ethanol from sugarcane is discussed, with a theoretical introduction to hydrogen, the process of steam reforming and gasification of biomass (bagasse) by inserting a turbine associated with the recovery boiler gas. Subsequently makes up the energy and exergy analysis of the incorporation of the above technologies. In end stage makes it an ecological analysis considering or not the carbon cycle (photosynthesis), to determine the levels of emissions of pollutants, carbon dioxide equivalent, indicators of pollution and ecological efficiencies associated with technological developments proposed. It is concluded that hydrogen production by steam reforming of ethanol and gasification of bagasse are viable alternatives from the point of view of technical and environmental applications in the biofuels industry, contributing to the development of the sector in the country

Aplicação do ciclo rankine orgânico alimentado termicamente pela queima da casca do arroz e resíduos de madeira

With the growing world energy demand mainly from developing countries like Brazil, Russia, India and China, the search for efficient sources of energy becomes a challenge for the coming years. Among the most widely used alternative sources, biomass is the one that grows in a more pronounced way. This study will assess the real possibility of having it as a heat source in an Organic Rankine Cycle, which employ heat transfer fluids as working fluids instead of water. From a regional data collection in agricultural production and their potential rice production and the resulting husk was defined as more appropriate. The availability of husks together with an amount of eucalyptus wood, provided by a company in the region on a monthly basis, were analyzed, and the low participation of the wood was discarded by the thermal contribution of little significance. Based on this, it was established the calorific value of fuel for thermodynamic calculations and the cycle to be used. It was then carried out the choice of working fluid from the literature and their availability in the library of software used for the simulations, the Engineering Equation Solver - ESS. The fluid most appropriate for the burning of biomass, Octamethyltrisiloxane (OMTS), was not included in the software and so the R227ea and R134a were selected. After the initial parameters modeling definition, as condensing temperature, efficiency and live steam conditions, the simulations were performed, and only the R227ea remained within the feasible thermodynamic and technological ranges. With this fluid the turbine power output was 265.7 [kW] for a scenario of 24 hours/day burning, 800.3 [kW] to biomass burning for 8 hours/day and 2134 [kW] for burning only 3 hours/day. The thermal efficiency of the cycle remained in the range of 6%, and for plants operating with the most... (Complete Abstract click eletronic access below)

Estudo de falhas por fadiga em caldeiras

In recent years, increasing demand for energy has led to studies to increase the amount of electricity produced. Due to this fact, more and more boilers are becoming important sources of electricity generation. To raise the efficiency of energy generated in the boilers is necessary to raise the steam pressure and temperature to values previously unimaginable. The use of more resistant materials and maintenance practices and most appropriate operation made it possible. The objective of this study is to test the main types of failure in a chemical recovery boiler, in particular due to fatigue in the superheater, because it is a component subjected to high temperatures and thus more subject to different failures. In this manner this study aims to reduce the incidence of unscheduled maintenance shutdowns, increasing the operation time under appropriate conditions. Modeling performed in this study, the failure did not occur, because we considered only the mechanical stress. Under normal conditions, mechanical stress in combination with thermal stresses can cause cracks in the tubes due to cyclical stresses, leading to fatigue failure

Estudo do potencial enzimático hidrolítico e oxidativo do microorganismo Myceliophthora thermophila M.7.7

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo sobre uma turbina a gás instalada em uma refinaria de petróleo

The gas turbine (GT) is known to have: low cost of capital over the amount of energy, high flexibility, high reliability, short delivery time, commissioning and commercial operation at the beginning and quick departure. The gas turbine is also recognized for its superior environmental performance, manifested in air pollution containment and reducing greenhouse gases (Mahi, 1994). Gas turbines in simple cycle mode (SC) have long been used by utilities to limited power generation peak. In addition, manufacturing facilities use gas turbines for power generation units on site, often in combination with the process of heat production, such as hot water and steam process. In recent years, the performance of industrial gas turbines has been improved due to significant investments in research and development, in terms of fuel to electricity conversion efficiency, plant capacity, availability and reliability. The greater availability of energy resources such as natural gas (NG), the significant reduction of capital costs and the introduction of advanced cycles, have also been a success factor for the increased use of gas turbines to load applications base (Poulikas, 2004). Open Cycle Gas Turbine with a greater degree of heat to the atmosphere may alternatively be used to produce additional electricity using a steam cycle, or to compose a cogeneration process. The combined cycle (CC) uses the heat from the gas turbine exhaust gas to increase the power output and increase the overall efficiency of more than 50% second (Najjar, 2001). The initial discovery of these cycles in the commercial power generation market was possible due to the development of the gas turbine. Only from the 1970s that gas turbine inlet temperature and therefore the exhaust gas temperature was sufficiently high to allow a better efficiency in the combined cycle ... (Complete Abstract click electronic access below)

Incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e aumento da oferta de eletricidade

This work studies the incorporation of new technologies in the sugarcane sector. Are considered the ethanol steam reforming and the gasification of sugarcane bagasse(by-product) processes associated with combined cycle systems (Gas Turbine + Steam Turbine), aggregating hydrogen production and increased electricity supply in the sector, respectively. To verify the technical feasibility of the incorporation processes was performed a thermodynamic analysis, considering data from a typical Brazilian Sugar Cane Industry. In another step the economic viability study of the hydrogen production process was made, with consideration on hydrated and anhydrous ethanol steam reform, comparing the cost of hydrogen production. Also considered studies of economic engineering of the gasification process and the generation of electricity associated. As conclusions, it follows that the ethanol steam reforming is a great alternative for hydrogen production, presenting production cost relatively low, especially when is considered the steam reforming of hydrated ethanol. For the gasification process associated with combined cycle, can be observed an increase of 8.56 times of the electricity production in the sugar cane industry, indicating a positive annual saving when the sales price of the supply electricity is greater than 0.070 US$/kWh. Finally it can be concluded that the incorporation of these new processes allow greater profitability and operational flexibility of Brazilian sugarcane mills

Comparação de junta soldada aço carbono/ aço inox utilizando como metal de adição aço carbono e aço inox

In contemporary industrial, welding processes are widely used, this is the most important process of joining metals used industrially. The welding can be used to build simple structures, like doors and gates for instance, in the same way can be used in situations of high responsibility, such as the nuclear industry and oil industry. Dissimilar welding is a case of welded joints, is characterized by the junction between different materials, for this case, stainless steel and carbon steel that are widely used in steam lines, power plants, nuclear reactors, petrochemical plants. Because their different mechanical and corrosive properties, the join, stainless steel with carbon steel, not only meets environmental requirements and also reduces cost. By using penetrating liquid tests, macrograph, hardness and tensile test was compared the possibility of replacing the current use of 309 rods as filler metal in dissimilar welding between carbon steel and stainless steel by add-on material carbon steel essentially, in this case E7018 coated electrode was used, but without the coating. After analysis of the results and for comparison, was proposed with some certainty that it is possible to replace the addition of materials, thus leading economy in this process widely used in the modern industry

Criopreservação de oócitos de Prochilodus lineatus (Valenciennes, 1836) (Teleostei, Prochilodontidae)

Pós-graduação em Ciência e Tecnologia Animal - FEIS

Aceitabilidade e qualidade nutricional de beterrabas in natura e pré-processadas submetidas a diferentes métodos de cocção

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

O centenário da ferrovia brasileira (1954): ensaio sobre a elabo-ração da memória ferroviária no Brasil

In 1954, it was celebrated the centenary of railways in Brazil. The date refers to the first section of 14.5 km of railway in Brazil (30/04/1854), in Rio de Janeiro, between Mauá and Fragoso, of the Petropolis Railway Company (Estrada de Ferro Petrópolis). Some of the texts and commemorative events indicated the symbolic values that the railroad took in the Brazilian history. Firstly, on 30.04.1954, the railway section Mauá-Fragoso and steam locomotive “Baroness” (the first used on the track) were declared national monuments(Decree No. 35,447-A, April 30, 1954). Secondly, some entities (Clube de Engenharia, Conselho Nacional de Geografia, Ministério da Viação e Obras Públicas) highlighted the importance of celebrating the Brazilian railway history and its historical significance, economic and geographical. For this, some events was occurred (the commemoration of one hundred years in Rio de Janeiro and Recife on 30.04.1954). Among the texts wrought produced, we highlight the text I Centenary of Brazilian Railroad (1954), released by the Brazilian Institute of Geography and Statistics (Instituto Brasileiro de Geografia e Estatística), and the National Council of Geography (Conselho Nacional de Geografia). The emphasis given to the railway refersto the geographical perspective (territorial expansion), but also makes mention of the Barãode Mauá, the founder of Petropolis Railway Company. We aim to understand the celebration from evocations about the Brazilian railroad history and some ideas that is assigned to the railway (and the Barãode Mauá), and railway heritage (the track and the locomotive “Baroneza”). On basis of this review will seek to understand how it was reconceived the railroad memory in view of these values and material elements.

Influência de diferentes métodos de esterilização de esmalte dental sobre a sua morfologia, composição química, estrutura e formação de biofilmes in vitro

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influência da fase I de compostagem e da esterilização do composto no cultivo de duas linhagens do Pleurotus ostreatus var. Florida

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Uso da avaliação do ciclo de vida para a determinação na redução de emissões de gases do efeito estufa e do consumo de energia associados a reciclagem de EPS

Pós-graduação em Engenharia Mecânica - FEG