Influence of Mg on the structural and optical properties of LiNbO3 thin films grown by polymeric precursor method

A polymeric precursor solution was used to deposit pure and Mg doped LiNbO3 thin films on sapphire substrates by spin-coating. The effects of magnesium addition on crystallinity, morphology and optical properties of the annealed films were investigated. X-ray diffraction patterns indicate the oriented growth of the films. Phi-scan diffraction evidenced the epitaxial growth with two in-plane variants. AFM studies show that the films are very homogeneous, dense and present smooth surfaces. The refractive index and optical losses obtained by the prism coupling method were influenced by the magnesium addition.

Oxygen Interstitial Dynamics in Bi(2)Sr(2)CaCu(2)O(8+delta) Oxides Measured by Mechanical Spectroscopy

Many researchers became interested in the discovery of Bi(2)Sr(2)CaCu(2)O(8+delta) oxides with critical temperature of around 80 K. It is known that the critical temperature is related to the CuO2 planes of the material. For this reason, the study of the interstitial oxygen in these oxides is of great relevance. The samples were prepared by means of conventional solid state reactions, through the stoichiometric mixture of precursory powders. After the sinterization, the samples were submitted to measurements of density, electrical resistivity, x-ray diffraction, scanning electron microscopy and energy dispersion spectroscopy, with the objective of performing their characterization. The measurements of mechanical spectroscopy were performed by a torsion pendulum. The results show three relaxation processes in the temperature range of 200 and 700 K, with activation energy of approximately 0.9 eV, which has been attributed to the dynamics of the interstitial oxygen present in the material.

Obtenção e caracterização óptica e elétrica de 'La''Ta'O IND.4' e LiTaO Ind.3 puros e dopados com Eu POT.3+

Eletronicalceramics are used in many applications such as: multilayer capacitor, transducer, pyroelectric sensors and electrooptic devices. In recent years there has been a growing demand for eletronicalceramics with better performance and functionality. This demand has accelerated the development of synthesis techniques to produce powders with well-defined particle size, shape and crystallinity. The eletronicalceramics in the form of bulk are determined by their performance characteristics of the powders used and the preparation process. So, physical and chemical properties of powders, such as chemical control of stoichiometry, purity, homogeneity, particle size and shape should be observed when choosing the methods of synthesis. Among the techniques used so far, the polymeric precursor method, also known as Pechini, has been considered ideal for the preparation of nanosized powders. Thus, this research project aims to use the polymeric precursor method to prepare powders of lithium tantalate and lanthanum tantalate, with good chemical stability. In this aspect is proposed to investigate the effects of variation of the concentration of europium about the properties of tantalate because doping with Eu3 + indicates that they may occupy different sites in the crystal structure, as in the case of LiTaO3. Effects of things like occupation sites, stability of phases and formation temperature have been previously investigated by the group, which motivated the formulation of this project. Our proposal aims to introduce the Eu3 + LaTaO4 and LiTaO3 and study the structural and optical properties of the powders obtained by Pechini method, as well as correlate these studies with the electrical properties of the material, mainly the Ironelectricty Hysteresis.

Estética em sistema metal free associado a núcleos metalocerâmicos personalisados

The evolution of ceramic systems currently allows the manufacture of prosthesis similar to the natural teeth, meeting the expectations of patients. However, when using vitreous ceramic the color of substrate is significant for the esthetic result, requiring planning aesthetic cores when involved reconstruction of endodontically treated teeth without coronal structure. Thus, the aim of this study to describe a case report of aesthetic rehabilitation in upper anterior teeths using vitreous ceramic system for the reconstruction of elements: 11, 12, 21 and 22 after endodontically treated. It was emphasized the removal of crowns and manufacture of custom cast post and core with ceramic in coronal portion, prioritizing the aesthetic result. Through the clinical results observed can be seen that the use of custom cast post and core with ceramic in association lithium disilicate glass ceramics provided a satisfactory aesthetic result.

Restaurações cerâmicas minimamente invasivas executadas por cirurgiões dentistas com diferentes níveis de experiência profissional: estudo clínico cego, longitudinal e prospectivo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo clínico retrospectivo de restaurações cerâmicas do tipo laminado sobre dentes com ou sem preparo dentário: 1 a 5 anos de acompanhamento

Pós-graduação em Odontologia - FOA

Avaliação energética do ciclo de refrigeração por absorção utilizando biogás de aterros sanitários e gás natural

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Comportamento biomecânico de estruturas multicamadas em restaurações protéticas

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Efeitos de lasers de alta potência na superfície de cerâmicas vítreas de dissilicato de lítio e sua resistência de união à dentina humana

Pós-graduação em Odontologia Restauradora - ICT

Estudo da viabilidade da implantação de frotas de veículos elétricos e híbridos elétricos no atual cenário econômico, político, energético e ambiental brasileiro

Currently there are two car models that use electricity in their propulsion systems, the electric vehicle and the hybrid electric vehicle. The electric vehicles are classified as vehicles that use electric motors in their propulsion system and batteries as a power source, on the other hand, the hybrid vehicles are classified as vehicles that use both electric motors and internal combustion engines in their propulsion system, using both batteries and líquid fuels as a power source. The main goal of this work is to analyze the characteristics of electric and hybrid electric vehicles and demonstrate the unfeasibility of the electric vehicle in the current economic, political, energetic and environmental brazilian scenario, for this purpose it was realized a study about the current brazilian situation regarding to electricity generation, current conservation status of road network, lack of electrical infrastructure for charging batteries, national lithium reserves, environmental characteristics, tax incentives, economic scenario, oil market and political positioning related to the implantation of electric or hybrid electric fleets in nacional territory. The operational characteristics analysis of electric and hybrid electric vehicles in this current scenario leads to the conclusion that currently a growth of electric vehicles fleets on a national scale is totally impractical in the Brazil, Thus, the introduction of green vehicles probably will occur primarily with hybrid electric models, motivated mainly due the bigger autonomy of this models compared to electric models, lower cost of hybrid electric models compared to electric models, factors related to the lack of recharging infrastructure and also factors related to political positioning

Desenvolvimento de conjunto membrana-eletrodos para célula a combustível de metanol direto passiva

Direct methanol fuel cells (DMFCs) without external pumps or other ancillary devices for fuel and oxidant supply are known as passive DMFCs and are potential candidates to replace lithium-ion batteries in powering portable electronic devices. This paper presents the results obtained from a membrane electrode assembly (MEA) specifically designed for passive DMFCs. Appropriated electrocatalysts were prepared and the effect of their loadings was investigated. Two types of gas diffusion layers (GDL) were also tested. The influence of the methanol concentration was analyzed in each case. The best MEA performance presented a maximum power density of 11.94 mW cm^-2.

Efeitos de lasers de alta potência na superfície de cerâmicas vítreas de dissilicato de lítio e sua resistência de união à dentina humana

Pós-graduação em Odontologia Restauradora - ICT

Estudo da viabilidade da implantação de frotas de veículos elétricos e híbridos elétricos no atual cenário econômico, político, energético e ambiental brasileiro

Currently there are two car models that use electricity in their propulsion systems, the electric vehicle and the hybrid electric vehicle. The electric vehicles are classified as vehicles that use electric motors in their propulsion system and batteries as a power source, on the other hand, the hybrid vehicles are classified as vehicles that use both electric motors and internal combustion engines in their propulsion system, using both batteries and líquid fuels as a power source. The main goal of this work is to analyze the characteristics of electric and hybrid electric vehicles and demonstrate the unfeasibility of the electric vehicle in the current economic, political, energetic and environmental brazilian scenario, for this purpose it was realized a study about the current brazilian situation regarding to electricity generation, current conservation status of road network, lack of electrical infrastructure for charging batteries, national lithium reserves, environmental characteristics, tax incentives, economic scenario, oil market and political positioning related to the implantation of electric or hybrid electric fleets in nacional territory. The operational characteristics analysis of electric and hybrid electric vehicles in this current scenario leads to the conclusion that currently a growth of electric vehicles fleets on a national scale is totally impractical in the Brazil, Thus, the introduction of green vehicles probably will occur primarily with hybrid electric models, motivated mainly due the bigger autonomy of this models compared to electric models, lower cost of hybrid electric models compared to electric models, factors related to the lack of recharging infrastructure and also factors related to political positioning

Local structure around Fe ions on multiferroic Pb(Fe1/2Nb1/2)O-3 ceramics probed by x-ray absorption spectroscopy

Local structure around Fe ions on Pb(Fe1/2Nb1/2)O-3 ceramics was probed by x-ray absorption spectroscopy in order to settle the controversies about its structure. It is observed that the shell structure around Fe atoms exhibits a monoclinic local symmetry at 130 and 230 K, tetragonal local symmetry at room temperature, and cubic local symmetry at 410 K. Independently of the coordination, temperature, or symmetry, Fe-O mean bond-length does not vary significantly. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4709490]

Relationship between elastic and mechanical properties of dental ceramics and their index of brittleness

The purpose of the study was to verify the effects of a number of materials' parameters (crystalline content; Young's modulus, E; biaxial flexure strength, sigma(i); Vickers hardness, VH; fracture toughness, K-Ic; fracture surface energy, gamma(f); and index of brittleness, B) on the brittleness of dental ceramics. Five commercial dental ceramics with different contents of glass phase and crystalline particles were studied: a vitreous porcelain (VM7/V), a porcelain with 16 vol% leucite particles (d.Sign/D), a glass-ceramic with 29 vol% leucite particles (Empress/E1), a glass-ceramic with 58 vol% lithium-disilicate needle-like particles (Empress 2/E2), and a glass-infiltrated alumina composite with 65 vol% crystals (In-Ceram Alumina/IC). Discs were constructed according to manufacturers' instructions, ground and polished to final dimensions (12 mm x 1.1 mm). Elastic constants were determined by ultrasonic pulse-echo method. sigma(i) was determined by piston-on-3-balls method in inert condition. VH was determined using 19.6 N load and K-Ic was determined by indentation strength method. gamma(f) was calculated from the Griffith-Irwin relation and B by the ratio of HV to K-Ic. IC and E2 showed higher values of sigma(i), E, K-Ic and gamma(f), and lower values of B compared to leucite-based glass-ceramic and porcelains. Positive correlations were observed for sigma(i) versus K-Ic, and K-Ic versus E-1/2, however, E did not show relationship with HV and B. The increase of crystalline phase content is beneficial to decrease the brittleness of dental ceramics by means of both an increase in fracture surface energy and a lowering in index of brittleness. (C) 2012 Elsevier Ltd and Techna Group Sri. All rights reserved.