Changes in Petrophysical Properties of the Stone Surface due to Past Conservation Treatments in Archaeological Sites of Merida (Spain)

Petrophysical properties, such as porosity, permeability, density or anisotropy de-termine the alterability of stone surfaces from archaeological sites, and therefore, the future preservation of the material. Others, like superficial roughness or color, may point out changes due to alteration processes, natural or man-induced, for ex-ample, by conservation treatments. The application of conservation treatments may vary some of these properties forcing the stone surface to a re-adaptation to the new conditions, which could generate new processes of deterioration. In this study changes resulting from the application of consolidating and hydrophobic treatments on stone materials from the Roman Theatre (marble and granite) and the Mitreo’s House (mural painting and mosaics), both archaeological sites from Merida (Spain), are analyzed. The use of portable field devices allows us to perform analyses both on site and in la-boratory, comparing treated and untreated samples. Treatments consisted of syn-thetic resins, consolidating (such as tetraethoxysilane TEOS) and hydrophobic products. Results confirm that undesirable changes may occur, with consequences ranging from purely aesthetic variations to physical, chemical and mechanical damages. This also permits us to check limitations in the use of these techniques for the evaluation of conservation treatments.

NDT for the detection and characterization of superficial treatments on stone material from archaeological sites of Merida (Spain)

Different treatments (consolidation and water-repellent) were applied on samples of marble and granite from the Front stage of the Roman Theatre of Merida (Spain). The main goal is to study the effects of these treatments on archaeological stone material, by analyzing the surface changes. X-Ray Fluorescence and Laser-Induced Breakdown Spectroscopy techniques, as well as Nuclear Magnetic Resonance have been used in order to study changes in the surface properties of the material, comparing treated and untreated specimens. The results confirm that silicon (Si) marker tracking allows the detection of applied treatments, increasing the peak signal in treated specimens. Furthermore, it is also possible to prove changes both within the pore system of the materialand in the distribution of surface water, resulting from the application of these products

Entre el Binomio Arte / Técnica. El cemento y el granito en el paisaje del Duero Internacional

Between Art and Tecnology. Concrete and granite in landscape of International Douro

Antonio Vallejo Álvarez: arquitectura de la sensatez

La presente tesis doctoral desarrolla la obra del arquitecto Antonio Vallejo Álvarez (n. 1903, t. 1928, f. 2002) cuya larga carrera profesional permite observar una evolución que tiene como fondo la de la arquitectura española desde los planteamientos academicistas de principios del siglo XX, pasando por el primer racionalismo, hasta la influencia del Movimiento Moderno. Antonio Vallejo nació en Almonacid de Zorita, un pueblo de la provincia de Guadalajara pequeño pero singular ya que entonces se construía el Salto de Bolarque, instalación energética crucial en la época que albergaba además elementos de arquitectura culta. La familia le envió a Madrid a estudiar en las Escuelas Pías de San Fernando y luego en la vieja escuela de arquitectura de la calle Escritorios perteneciente a la Real Academia de Bellas Artes de San Fernando. Terminada la carrera realizó unas primeras edificaciones de corte historicista con relativa abundancia de estilemas academicista que van desapareciendo paulatinamente a la vez que evolucionan hacia el “decó”. De esta depuración, que puede observarse muy bien en los números 69,73 y 62 de la calle Viriato de Madrid, resulta un primer racionalismo en el que las balconadas y cuerpos volados se apoyan sobre una trama racionalista ortogonal cada vez más rígida. Simultáneamente trabajó en esta época en la Oficina de Información sobre la Ciudad del Ayuntamiento de Madrid junto a Bernardo Giner de los Ríos y Fernando García Mercadal, entre otros. Más tarde se incorporó a las órdenes del primero a la Oficina de Construcciones escolares donde se mantuvo hasta el estallido de la guerra civil. Al amparo de la Ley Salmón fundó la empresa promotora de viviendas Ar-In donde realizó una arquitectura en la que la trama racionalista cobra una gran fuerza expresiva, matizada y potenciada por grandes balcones aterrazados de corte higienista. Sus exponentes máximos son el conjunto en la calle Narváez esquina a Alcalde Sáinz de Baranda, y la manzana de Guzmán el Bueno, 75 de Madrid. La guerra civil interrumpe el proceso y tras ella nuestro autor ensaya la supervivencia del racionalismo mediante la superposición de la trama en grandes cuerpos de alzado de ladrillo ocupando las plantas de pisos, sobre un basamento de granito en la planta baja y una especie de pórtico enmarcando los huecos del ático a modo de remate. En las ventanas se colocan embocaduras de caliza de diversas formas. Esta arquitectura, muy en la línea del gusto de la época, será sublimada mediante un magnífico ejemplo de manierismo en su gran obra de la Residencia de los Agustinos Recoletos y la Iglesia de Santa Rita de Madrid. Superados los al menos tres lustros de postguerra, Vallejo inicia un proceso que podríamos llamar estructuralista en la medida en que la asunción de la situación de la estructura en el edificio y el módulo por ella creada definen sus características formales. Aquí, tras trabajar el hormigón armado en algunos edificios como los del Residencial Bellas Vistas de Madrid, lo hace con mucho más convencimiento en edificios con estructuras de acero como el colegio del Sagrado Corazón de Guadalajara. Es también importante hablar de la provincia de Almería, a cuya capital llega nuestro arquitecto inmediatamente después de la guerra civil para alejarse de las indeseables consecuencias que hubiera podido tener su fidelidad al gobierno de la República con el que colaboró hasta el último momento. En la ciudad desarrolló una extensa labor como constructor a través de Duarín SA, que se había formado sobre los restos de su promotora. También como arquitecto, con una labor paralela a la madrileña pero con menor presión ambiental, lo que contribuyó a que en cierta medida el proceso de afloramiento de su arquitectura estructuralista, heredera lejana de su primer racionalismo, fuese más rápido, como prueban realizaciones como los edificios de la calle Juan Pérez, 18 y del Paseo de la Estación, 19. ABSTRACT This thesis deals with the works in architecture from Antonio Vallejo Álvarez (b. 1903, g. 1928, d. 2002) whose long career enables us to concentrate on the evolution of the Spanish Architecture from the Academicism taking place at the beginning of XXth century , until the influence of the Modern Movement, taking also into account Racionalism. Antonio Vallejo was born in Almonacid de Zorita, a village in the province of Guadalajara small but unique because then Salto de Bolarque the crucial energy facility at the time also housed elements of classical architecture is built. His family sent him to study to Madrid in Escuelas Pías de San Fernando first, and then he attended lessons in the old Architecture school from Escritorios street belonging this last one to la Real Academia de Bellas Artes de San Fernando. Once he finished his degree on Architecture, he worked on some historicist buildings with a great use of academicist stylemes which will be disappearing little by little, turning into “deco”. From this depurationn, whose traces can be found in 69, 73, 62 at Viriato street in Madrid, our architect ends up with a first racionalism in which balconies and flown bodies are suspended on a racionalist and orthogonal more and more rigid. At that time, he was also working in the Information Office in Madrid Town Hall together with Bernardo Giner de los Ríos y Fernando García Mercadal, among others. Later, he worked for Bernardo Giner de los Ríos in the School Building Offices until the breaking out of the Civil War. Under Salmón law, he founded a developer for buildings named Ar-In, where he developed a type of Architecture in which racionalism develops a magnificent expressive force, empowered by great terraced balconies with higienistain court. His great masterpieces at this time are the buildings from Narvaez opposite to Alcalde Sáinz de Baranda and the block in 75 Guzmán El Bueno, in Madrid. Civil war interrupts somehow his process and once the war is over, our architect works on the survival of racionalism by overlapping on large bodies of brick elevation occupying different floor plants, on a base of granite on the ground floor and a sort of portico framing the gaps in the attic by way of auction. On the Windows he se colocan embocaduras de caliza de diversas formas. This type of architecture, very much enjoyed at that time, will be sublimed as a great example of manierism in his great work such as the case of Agustinos Recoletos Residence and Santa Rita Church in Madrid. About fifteen years after the war, in the post-war era, Vallejo starts a process which we could call structuralist, as lons as the asumption from the situation of the structure in the building and the created module define his main features. Here, once our architect works with reinforce concrete in some of his buildings such as Residencial Bellas Vistas de Madrid, he improves his technique with steel strucutres such as the on in the school Sagrado Corazón in Guadalajara. It is also remarkable to speak about the province of Almería, where our architect arrives inmediately after the civil war, to get rid of the consequences of his loyalty to the Republic movement to which he collaborated until his death. He developed a great career as a builder there through Duarín SA, which was launched though his former enterprise. Similary as the way he worked in Madrid,he, also as an arquitect, did his work in Almería with less environmental pressure though, fact which contributed to the flourishing of the structuralist architecture, as an heir from his first racionalism, as it can be shown from buildings in streets such as 18 Juan Pérez, and 19 Paseo de la Estación.

Biochemical evolution II: Origin of life in tubular microstructures on weathered feldspar surfaces

Mineral surfaces were important during the emergence of life on Earth because the assembly of the necessary complex biomolecules by random collisions in dilute aqueous solutions is implausible. Most silicate mineral surfaces are hydrophilic and organophobic and unsuitable for catalytic reactions, but some silica-rich surfaces of partly dealuminated feldspars and zeolites are organophilic and potentially catalytic. Weathered alkali feldspar crystals from granitic rocks at Shap, north west England, contain abundant tubular etch pits, typically 0.4–0.6 μm wide, forming an orthogonal honeycomb network in a surface zone 50 μm thick, with 2–3 × 106 intersections per mm2 of crystal surface. Surviving metamorphic rocks demonstrate that granites and acidic surface water were present on the Earth’s surface by ∼3.8 Ga. By analogy with Shap granite, honeycombed feldspar has considerable potential as a natural catalytic surface for the start of biochemical evolution. Biomolecules should have become available by catalysis of amino acids, etc. The honeycomb would have provided access to various mineral inclusions in the feldspar, particularly apatite and oxides, which contain phosphorus and transition metals necessary for energetic life. The organized environment would have protected complex molecules from dispersion into dilute solutions, from hydrolysis, and from UV radiation. Sub-micrometer tubes in the honeycomb might have acted as rudimentary cell walls for proto-organisms, which ultimately evolved a lipid lid giving further shelter from the hostile outside environment. A lid would finally have become a complete cell wall permitting detachment and flotation in primordial “soup.” Etch features on weathered alkali feldspar from Shap match the shape of overlying soil bacteria.

Biochemical evolution III: Polymerization on organophilic silica-rich surfaces, crystal–chemical modeling, formation of first cells, and geological clues

Catalysis at organophilic silica-rich surfaces of zeolites and feldspars might generate replicating biopolymers from simple chemicals supplied by meteorites, volcanic gases, and other geological sources. Crystal–chemical modeling yielded packings for amino acids neatly encapsulated in 10-ring channels of the molecular sieve silicalite-ZSM-5-(mutinaite). Calculation of binding and activation energies for catalytic assembly into polymers is progressing for a chemical composition with one catalytic Al–OH site per 25 neutral Si tetrahedral sites. Internal channel intersections and external terminations provide special stereochemical features suitable for complex organic species. Polymer migration along nano/micrometer channels of ancient weathered feldspars, plus exploitation of phosphorus and various transition metals in entrapped apatite and other microminerals, might have generated complexes of replicating catalytic biomolecules, leading to primitive cellular organisms. The first cell wall might have been an internal mineral surface, from which the cell developed a protective biological cap emerging into a nutrient-rich “soup.” Ultimately, the biological cap might have expanded into a complete cell wall, allowing mobility and colonization of energy-rich challenging environments. Electron microscopy of honeycomb channels inside weathered feldspars of the Shap granite (northwest England) has revealed modern bacteria, perhaps indicative of Archean ones. All known early rocks were metamorphosed too highly during geologic time to permit simple survival of large-pore zeolites, honeycombed feldspar, and encapsulated species. Possible microscopic clues to the proposed mineral adsorbents/catalysts are discussed for planning of systematic study of black cherts from weakly metamorphosed Archaean sediments.

Geologia e petrologia da ilha de São Sebastião (Estado de São Paulo)

A ilha de São Sebastião consta principalmente de rochas alcalinas que formam um maciço de 300 km2 aproximadamente, constituindo o terceiro em área no Brasil. Apresenta-se em um "stock" alongado segundo NE-SW, encaixado em estruturas de gnais. As formações geológicas encontradas consistem em 1 - Granitos e Gnais (ARQUEANO), 2 - Eruptivas básicas (RÉTICO), 3 - Eruptivas alcalinas (JURÁSSICO) e 4 - Depósitos recentes (HOLOCENO). O método de estudo empregado foi o petrográfico e a coluna geológica estabelecida em base de dados petrográficos, tectônicos e fisiográficos. O arqueano é determinado por definição dos seus tipos petrográficos (1- gnais facoidal, 2- oligoclásio-gnais, 3- hornblenda-gnais, 4- biotita-gnais e 5- microlina-granito) idênticos aos concorrentes no considerado arqueano do Brasil meridional. O triássico (rético) é conferido às rochas básicas (diabásios e basaltos) pela sua semelhança tectônica e petrográfica com as congêneres que cortam de maneira semelhante o arqueano no continente. A "mise-en-place" das eruptivas alcalinas (1- Nordmarkito, 2- Biotita-pulaskito, 3- Pulaskito, 4- Nefelina-sienito, 5- Foiaito, 6- Essexito-foiaito, 7- Essexito e 8- Teralito) pode ser considerada jurássica devido suas relações com as eruptivas básicas referidas réticas, pois na praia do Bonete (foto 14) observa-se um dique de nordmarkito cortando outro de diabásio. As eruptivas quartzo-dioríticas (quartzo-microdiorito e quartzo-andesito) cortam as alcalinas no cume do Zabumba, indicando sua idade mais moderna que estas. Além deste fato, preenchem linhas de fraturas tectônicas recentes, como as falhas ao longo do canal de São Sebastião, indicando que a topografia deveria ser a mesma que a atual para permitir rios efusivos ao nível do canal ou que pelo menos toda a zona de extrusão estivesse, como hoje está, em superfície. Os depósitos aluviais marinhos e continentais são considerados recentes, (holocênicos) pelo favor da topografia onde se dispõe, ocupando o fundo os vales e os bordos do atual modelado costeiro, idade esta conferida em base fisiográfica. A tectônica que afetou a ilha de São Sebastião participa da que atuou em todo o litoral meridional brasileiro. Pode-se distinguir duas fases distintas: na primeira ocorreram as erupções básicas e as alcalinas subsidiárias e na segunda deram-se os falhamentos escalonados em blocos basculados para NW, com as fraturas de tensão preenchidas pelas eruptivas quartzo-dioríticas. Toda a atividade tectônica foi regulada pela direção NE-SW privilegiada da estrutura do arqueano, correspondente a antigos eixos dos dobramentos laurencianos e huronianos. A geomorfologia da ilha consta de uma antiga superfície de erosão rematada até a senilidade, - o peneplano cretáceo, hoje reduzida às cristas culminares do maciço alcalino e às satélites das estruturas gnáissicas, desnivelada pelo falhamento em blocos e ligeiramente adernada para NW devido ao basculamento. Ao lado desta topografia vestigial existe o modelado atual da ilha caracterizado por uma juventude do estágio evolutivo. Esta escultura foi inaugurada com os últimos levantamentos epirogênicos que ascenderam as eruptivas alcalinas plutônicas a mais de 1.300 m sobre o nível do mar. O modelado costeiro apresenta uma costa típica de submergência com esculturas em rias, no estágio da juventude. A presença de terraceamentos marinhos de abrasão, atualmente elevados cerca de 20 a 30 m, lembra as oscilações epirogênicas ou eustáticas do litoral.

Conversion of a digital camera into a non-contact colorimeter for use in stone cultural heritage: The application case to Spanish granites

In this study, a digital CMOS camera was calibrated for use as a non-contact colorimeter for measuring the color of granite artworks. The low chroma values of the granite, which yield similar stimulation of the three color channels of the camera, proved to be the most challenging aspect of the task. The appropriate parameters for converting the device-dependent RGB color space into a device-independent color space were established. For this purpose, the color of a large number of Munsell samples (corresponding to the previously defined color gamut of granite) was measured with a digital camera and with a spectrophotometer (reference instrument). The color data were then compared using the CIELAB color formulae. The best correlations between measurements were obtained when the camera works to 10-bits and the spectrophotometric measures in SCI mode. Finally, the calibrated instrument was used successfully to measure the color of six commercial varieties of Spanish granite.

Artefatos funerários como fontes para a história de ofícios urbanos artesanais

Este artigo descreve o uso de artefatos funerários na reconstituição histórica do processo de trabalho em marmorarias instaladas no município de São Carlos (São Paulo, Brasil), no período 1890-1950. Observação direta e registro fotográfico de artefatos funerários, exame de ferramentas de trabalho e utilização de fontes orais permitiram a reconstituição do processo de trabalho. A composição química de fragmentos de artefatos funerários foi determinada por Difração de Raios X e Microscopia Eletrônica de Varredura, evidenciando matérias-primas e sua combinação e uso no processo de trabalho. Considerando-se as etapas produtivas da indústria de rochas ornamentais (extração, serragem e beneficiamento final), os artefatos funerários indicam que as marmorarias inseriam-se na etapa de beneficiamento final. As marmorarias integravam os setores de base técnica artesanal da indústria brasileira, apresentando: baixo grau de concentração de capital e de operários; predomínio da habilidade do ofício especializado; separação pouco nítida entre trabalhadores e instrumentos de trabalho; identificação do trabalhador com o produto. Artefatos de mármore e granito eram destinados a brasileiros de segmentos sociais abastados, durante o início da imigração na cidade de São Carlos (final do século XIX). A partir de 1920, italianos incorporam-se a clientela dos marmoristas, indicando a mobilidade social do imigrante na cidade.

Experimental research on the residual mechanical properties of an ordinary concretes after fire

This paper summarizes the results of an experimental research to assess the residual mechanical properties of an ordinary concrete after fire. It was studied the influence of the cooling process, the maximum temperature that the concrete was subjected to and the loading level on the residual mechanical properties of calcareous and granite aggregate concretes. The properties studied were the residual compressive, tensile, splitting and flexural strengths and modulus of elasticity. Four levels of temperature; 20, 300, 500 and 700ºC; two loading levels (0.3f and 0.7fcd) and two cooling processes (cooling in the air and by water jet) were tested. The high temperatures attained and the sudden cooling down process on the concrete showed a negative effect on its residual mechanical properties. This effect was more notorious on the residual compression strength than in the other mechanical properties

Influência das elevadas temperaturas e as propriedades mecânicas residuais do concreto normal

O concreto, de um modo geral, apresenta um bom comportamento em situação de incêndio quando comparado com o aço, todavia em função da temperatura ocorrem algumas transformações químicas e físicas que podem comprometer esse desempenho. Apesar das alterações das propriedades mecânicas e térmicas do concreto quando sujeito a temperaturas elevadas e após situação de incêndio já terem sido avaliadas em vários estudos, ainda é um campo aberto onde é necessário muita investigação. O presente artigo apresenta os resultados de um estudo experimental sobre a avaliação das propriedades mecânicas residuais de concretos normais após incêndio. Para o efeito foram selecionados agregados graníticos e agregados calcários, dado serem os agregados mais utilizados na construção civil em Portugal e em muitos outros países. Os parâmetros testados foram: o nível de carregamento (0,3fcd e 0,7fcd); o processo de arrefecimento (arrefecimento ao ar e arrefecimento por jato de água) e o nível máximo de temperatura atingida (20, 300, 500 e 700ºC). As propriedades mecânicas estudadas foram a resistência à compressão residual, resistência à tração direta e resistência à tração por compressão diametral, resistência à flexão, módulo de elasticidade e coeficiente de Poisson. As temperaturas atingidas e o arrefecimento rápido do concreto apresentaram um efeito negativo sobre as propriedades mecânicas residuais. Este efeito foi mais notório na resistência à compressão residual do que nas restantes propriedades mecânicas estudadas.

Letters from Thomas Handasyd Perkins to William Tudor,

Five letters in which Perkins comments on the political landscape in the United States, the election of Andrew Jackson as president, Boston architectural and real estate developments, and the Granite Railway and granite quarries in Quincy.

Letters from William Tudor to Thomas Handasyd Perkins,

Four letters on topics including the Granite Railway project, Tudor’s thoughts on expanding trade in South America, domestic politics, and the process for appointing Americans to diplomatic posts.

Southeastern Australia, 1834 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Map of the discoveries in Australia : copied from the latest M.S. surveys in the Colonial Office, by permission dedicated to the Right Hon.ble Viscount Goderich, H.M. principal Secretary of State for the Colonies, and President of the Royal Geographical Society, by his Lordships obliged servant J. Arrowsmith. It was published by Pubd. by J. Arrowsmith, 35 Essex St., Strand in Feb. 15 1834. Scale [ca. 1:3,041,280]. Covers southeastern Australia with additions to the east of the Gulf of St. Vincent and Granite Island inserted in Encounter Bay.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Asia South Lambert Conformal Conic coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, cities and other human settlements, territorial boundaries, shoreline features, and more. Relief shown by hachures and spot heights. Major explorations shown. Includes also notes and insets: The Colony of Western Australia ... -- [Map of Australia in Asia].This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Age constraints on the tectonic evolution of the Itremo region in Central Madagascar

The Itremo region in Central Madagascar comprises a deformed metasedimentary sequence (Itremo Group) that has undergone greenschist to lower amphibolite facies metamorphism. During a first phase of deformation (D1) Itremo Group sediments were deformed into a fold-and-thrust belt and transported toward the E to NE on top of migmatitic gneisses rocks of Anatananarivo block. A second phase of deformation (D2) affected both the fold-and-thrust belt and structurally underlying units, and formed large-scale N-S trending folds with steeply dipping axial planes. A Late Neoproterozoic Th–U–Pb XRF monazite age (565±17 Ma) dates the emplacement of a granite that truncates first-phase structures in the Itremo Group, and indicates that the fold-and-thrust belt formed prior to ≈565 Ma. Th–U–Pb electron microprobe dating was applied to elongated monazites that lie within the first-phase foliation of Itremo Group metapelites. The detrital cores of zoned monazites reveal two distinct age populations at ∼2000 and 1700 Ma, the latter age giving a maximum depositional age for the Itremo Group. Statistical analysis of ages determined from the rims of zoned monazites and from unzoned monazites indicates three Late Proterozoic–Early Paleozoic monazite growth events at about 565–540, 500 and 430 Ma. The oldest age population is contemporaneous within error, with the intrusion of the dated granite. The two younger age populations are found both in the Th–U–Pb and Ar–Ar data; together with the perturbation of the Rb–Sr system we interpret both ages as due to alteration related to fluid circulation events, possibly connected to the emplacement of pegmatite fields in Central Madagascar. Syn-D1 tectonic growth of contact metamorphism minerals such as andalusite has been observed locally in metapelites along the margin of Middle Neoproterozoic (≈800 Ma) granites, suggesting that D1 in the Itremo Group is contemporaneous with the intrusion of granites at ≈800 Ma. The N-S trending D2 folds are associated with ≈E-W shortening during the final assembly of Gondwana in Late Neoproterozoic–Early Cambrian times.