复边藓在中国的重新发现

Cinclidotus fontinaloides (Hedw ) P Beauv,which was previously collected and reported only once from Tibet in 1859 by Mitten,was rediscovered from Xinjiang (Mt Tianshan),China The description and illustrations of the species based on Chinese collection is presented in details for the first time in China

管理措施对人工林土壤质量的影响

可持续性生产力是人工林发展的一个关键问题。然而,人工林培育过程中常出现土壤质量退化和人工林生产力下降等问题。管理措施是人工林发展过程中土壤质量变化的一个重要因素,正确的管理措施能够维护和提高林地的土壤质量。管理措施主要包括整地、施肥、林地收获与凋落物管理和营造混交林等。不同的整地方式、整地强度、整地时间等能改变土壤物理、化学和生物学性状,进而对其土壤质量产生一定的影响;施肥措施能改善土壤质量、提高人工林生产力,而过量施肥能够导致林地养分的流失和地下水质的恶化;木材收获和林地凋落物焚烧导致人工林系统养分的大量流失,加强对人工林系统有机物质的保护有利于林地土壤质量的改善;营造混交林在一定程度上有利于土壤质量维护,由于物种间存在复杂的相互关系,其对混交树种、混交方式和立地条件的选择等管理措施均能影响土壤质量。最后,文章对今后人工林管理措施对土壤质量影响的重点研究方向作了展望。

Mass resolved MPI spectra of methyl iodide in the 430-490 nm region

The mass resolved multiphoton ionization (MPI) spectra of methyl iodide were obtained in the 430-490 nm region using a time-of-flight (TOF) mass spectrometer. They have the same vibrational structure, which testifies that the fragment species, in the wavelength region under study, are from the photodissociation of multiphoton ionized molecular parent ions. Some features in the spectra are identified as three-photon excitations to 6p and 7s Rydberg states of methyl iodide. Two new vibrational structures of some Rydberg states are observed. The mechanism of ionization and dissociation is also discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

科尔沁草甸草地放牧和割草条件下土壤种子库研究

研究了科尔沁沙地草甸草地在放牧、割草两种利用方式下的土壤种子库的大小、组成及其与地上植被的关系 .结果表明 ,在自由放牧下 ,土壤种子库密度为 6 15 8± 16 4 7粒·m-2 ,在割草利用下 ,土壤种子库密度为 8312± 2 5 4 0粒·m-2 .放牧干扰下 ,种子库组成以矮小、短命的一年生植物为主 ,其中一二年生植物占 81 6 6 % ,占比例最大的前 4种植物分别为虎尾草 (38 5 5 % )、灰绿藜 (15 4 2 % )、毛马唐 (14 95 % )和狗尾草 (9 83% ) ,多年生植物种子密度仅为 112 9± 30 2粒·m-2 ;割草干扰下 ,一二年生植物占6 8 0 8% ,其中狗尾草占 5 2 7% ;而割草地多年生植物种子密度为 2 6 5 3± 811粒·m-2 放牧地土壤种子库密度与地上植物相关不显著 ;割草地土壤种子库密度与地上植物多度显著相关 (r=0 76 ,P <0 0 1) .放牧地种子库的Shannon Wiener指数、丰富度指数分别为 2 96和 2 98,明显小于割草地的 3 10和 5 0 9,表明自由放牧更易使物种多样性下降 .

利用树木年轮宽度资料重建长白山地区240年来降水量的变化

根据长白山地区水曲柳年轮宽度资料,分析了树木年轮宽度与气候要素的关系,重建了1765年来该地区的降水变化。结果表明:长白山地区近240年降水波动明显,1850年以前降水波动幅度较大,1850—1900年波动比较平稳,并且降水量偏低,1900年以后降水的波动幅度明显增大,且湿润和干旱的持续时间增长,特别是1920年以后,降水波动剧烈;降水减少幅度最大的干旱期是1816—1820年,湿润期是1975—1979年;而1925—1936年和1947—1957年的2个干旱期在持续时间上最为显著。周期分析结果表明,长白山地区降水具有显著的2.64～3.03年、5.28～6.96年以及12.13～22.63年的周期。

外源添加物对秸秆还田土壤中无机氮转化影响

采用室内培养方法,研究秸秆不同还田方式土壤中加入无机氮肥和玉米秸秆对无机氮转化的影响。在田间秸秆不同还田处理的土壤中加入氮肥(硫酸铵)培养,初期土壤NH_4~+-N的含量较高,随着培养时间延长,NH_4~+-N的含量下降,培养15天后NH_4~+-N的含量趋于平衡;而土壤中NO_3~--N含量在培养期间逐渐增加,培养30天后NO_3~--N含量趋于平衡;秸秆不同还田处理土壤中添加秸秆培养,粉碎还田处理的土壤中NH_4~+-N的含量在整个培养过程中处于最低,培养后期覆盖还田和高茬还田的土壤NH_4~+-N的含量略有下降。

植被与大气之间物质和能量交换过程的反演理论研究进展

介绍了研究植被与大气之间物质和能量交换过程的一个崭新理论———反演理论,主要包括拉格朗日方法、欧拉方法和欧拉-拉格朗日耦合方法.详细阐述了各种方法的理论框架,并简要说明了其应用范围,最后概述了反演理论的局限性和未来的发展方向.

Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application

Gold nanoparticles stabilized by amino-terminated ionic liquid (Au-IL) have been in situ noncovalently deposited on poly(sodium 4-styrene-sulfonate) (PSS)-functionalized multiwalled carbon nanotubes (MWCNTs) to form a MWCNTs/PSS/Au-IL nanocomposite. PSS can interact with MWCNTs through hydrophobic interaction. Amino-terminated ionic liquid was applied to reduce aqueous HAuCl4, and the resulting gold nanoparticles were attached to the PSS-functionalized MWCNTs simultaneously. Most gold nanoparticles dispersed well on the functionalized MWCNTs. Transmission electron microscopy, Raman and X-ray photoelectron spectroscopy were used to confirm the composition and structure of the nanocomposites. The resulting MWCNTs/PSS/Au-IL composite exhibits good electrocatalysis toward oxygen and hydrogen peroxide reduction.

White electroluminescence from a single polymer system: Improved performance by means of enhanced efficiency and red-shifted luminescence of the blue-light-emitting species

High-efficiency white electrolurninescence from a single polymer is achieved by enhancing the electroluminescence efficiency and effecting a red-shift in the emission spectrum of the blue emissive species. A single-layer device of the resultant polymer exhibits a higher luminous efficiency than the nonmodified species (12.8 cd A(-1), see figure) and an external quantum efficiency of 5.4 % with CIE coordinates of (0.31,0.36), exemplifying the success of the reported methodology.

Brittle-ductile transition in high-density polyethylene/glass-bead blends: Effects of interparticle distance and temperature

The toughness of high-density polyethylene (HDPE)/glass-bead blends containing various glass-bead contents as a function of temperature was studied. The toughness of the blends was determined from the notch Izod impact test. A sharp brittle-ductile transition was observed in impact strength-interparticle distance (ID) curves at various temperatures. The brittle-ductile transition of HDPE/glass-bead blends occurred either with reduced ID or with increased temperature. The results indicated that the brittle-ductile-transition temperature dropped markedly with increasing glass-bead content. Moreover, the correlation between the critical interparticle distance (ID.) and temperature was obtained. Similar to the ID, of polymer blends with elastomers, the ID, nonlinearly increased with increasing temperature. However, this was the first observation of the variation of the ID, with temperature for polymer blends with rigid particles. (C) 2001 John Wiley & Sons, Inc. J Polym. Sci Part B: Polym. Phys 39: 1855-1859, 2001.

ELECTROCHEMICAL STUDY OF ISOPOLY-OXOMETALLATE AND HETEROPOLY-OXOMETALLATE FILM MODIFIED MICROELECTRODES .2. ELECTROCHEMICAL-BEHAVIOR OF ISOPOLYMOLYBDIC ACID MONOLAYER MODIFIED CARBON-FIBER MICROELECTRODES

In this paper the electrochemical properties of isopolymolybdic anion thin film modified carbon fibre (CF) microelectrode prepared by simple dip coating have been described. The modified electrode shows three couples of surface redox waves between + 0.70 and - 0.1 V vs. sce in 2 M H2SO4 solution with good stability and reversibility. The pH of solution has a marked effect on the electrochemical behaviour and stability of the film, the stronger the acidity of electrolyte solution is, the better the stability and reversibility of isopolymolybdic anion film CF microelectrode will be. The scanning potential range strongly influences on the electrochemical behaviour of the film. The isopolymolybdic anion film prepared by the dip coating resulting a monolayer with estimated surface concentration (F) 2.8 x 10(-11) mol cm-2. From the half-peak widths and peak areas of the surface redox waves of the film electrode, the first three surface waves are corresponding to two-electron processes. The electron energy spectra show the products by six electrons reduction are a mixture of Mo(VI) and Mo(V) species. The electrochemical reaction of the isopolymolybdic anion monolayer can be expressed as Mo8O264- + mH+ + 2ne half arrow right over half arrow left [HmMo8-2n(VI)Mo2n(V)O26](4,2n-m)-n = 1, 2, 3; m = 2, 5, 7.

Bromophenols coupled with methyl gamma-ureidobutyrate and bromophenol sulfates from the red alga Rhodomela confervoides

Four new bromophenols C-N coupled with methyl gamma-ureidobutyrate (1-4), a phenylethanol bromophenol (5), and three phenylethanol sulfate bromophenols (6-8) have been isolated from polar fractions of an ethanolic extract of the red alga Rhodomela confervoides. On the basis of spectroscopic evidence including HRMS and 2D NMR data, the structures of the new compounds were determined as methyl N'-(2,3-dibromo-4,5-dihydroxybenzyl)-gamma-ureidobutyrate (1), methyl N,N'-bis(2,3-dibromo-4,5-dihydroxybenzyl)-gamma-ureidobutyrate (2), methyl N'-[3-bromo-2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]-gamma-ureidobutyrate (3), methyl N'-(2,3-dibromo-4,5-dihydroxybenzyl)-A7-[3-bromo2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]-gamma-ureidobutyrate (4), 2,3-dibromo-4,5-dihydroxyphenylethanol (5), 2,3-dibromo-4,5-dihydroxyphenylethanol Sulfate (6), 3-bromo-4,5-dihydroxyphenylethanol sulfate (7), and 3-bromo2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxyphenylethanol sulfate (8). The cytotoxicity of all compounds was evaluated against several human cancer cell lines including human colon cancer (HCT-8), hepatoma (Bel7402), stomach cancer (BGC-823), lung adenocarcinoma (A549), and human ovarian cancer (A2780). Among them, the phenylethanol and the phenylethanol sulfate bromophenols (5-8) showed moderate cytotoxicity against all tested cell lines.

神经网络用于多模式分类

本文叙述一种改进型HAMMING网在印刷汉字文本识别实用系统中作为粗分类的应用.给出了以3755印刷汉字为多模式分类对象的神经网络分类器的结构及其相应的算法.该方法在微型机上用软件仿真得以实现.取得令人满意的结果.

智能机器人基于作业子空间划分的自学习自适应控制方法

现有的机器人自适应控制基本上都是在建立机器人线性化的动力学模型的基础上,采用某种显式或隐式参数辨识的方法,在线地修正控制作用.本文针对机器人运动和动力学参数变化的固有特点,提出一种完全不同的自学习自适应方法.这种方法基于智能机器人分级系统中的两级结构,并且在空间域里而不是在时间域里处理机器人参数的变化.把机器人的作业空间划分成子空间,其中包括重力载荷的作用,每个子空间对应一组控制器.规划的轨迹映射到作业空间形成子空间序列.用自学习方法选择与这个序列对应的最佳控制器序列.该方法算法简单,计算量小.避开了通常的自适应方法遇到的一系列困难问题.