Caracterização de solos e substâncias húmicas extraídas de amostras coletadas na região do Rio Aracá-AM: estudos de interações metal-matéria orgânica

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Utilização da ultrafiltração em fluxo tangencial como nova metodologia para determinação da capacidade de complexação e constantes de equilíbrio de íons 'Cu'(II) complexados por matéria orgânica natural

Pós-graduação em Química - IQ

Matéria orgânica do solo em rotações de culturas sob sistema semeadura direta

Pós-graduação em Agronomia (Agricultura) - FCA

Inter-relações da produtividade de cana soca com a resistência à penetração, umidade e matéria orgânica do solo

The sugarcane crop plays an important role on Brazilian economy,, especially in the aspect related to alternative energy sources. Yield of ratoon cane (2nd cycle) was evaluated in relation to resistance to penetration, gravimetric moisture and organic matter in a Typic Tropustalf, in the municipality of Suzanápolis (SP), 20º28'10'' S and 50º49'20'' W, in the Brazilian cerrado, in 2009. The main purpose was to select, among the attributes surveyed, the one with the highest linear and spatial correlations that explains the variability of sugar cane yield. A geostatistical grid was installed in order to collect data from the soil as well from the plant, with 120 sampling points in an area of 14.53 ha. Organic matter correlated linearly and negatively with penetration resistance, indicating that the soil management practices that aim its increase in the soil profile can improve soil physical conditions, and consequently, the development and yield of sugarcane. Both gravimetric moisture (UG) and content of soil organic matter (OM) correlated directly, linearly (UG2 and MO1) and spatially (UG1 and MO1) with sugarcane yield, proving to be the best attributes, among the evaluated ones, to estimate and increase the sugarcane yield.

Interações entre espécies de arsênio e matéria orgânica natural: Lílian Karla de Oliveira. -

Pós-graduação em Química - IQ

Teores e estoque de carbono em frações lábeis e recalcitrantes da matéria orgânica do solo sob integração lavoura-pecuária no bioma Cerrado

The study of organic matter and its compartments and their relationship with management, aims to develop strategies for increasing their levels in soils and better understanding of its dynamics. This work aimed to evaluate the fractions of soil organic matter and their carbon stocks in different soil cover system in crop-livestock integration and native Cerrado vegetation. The study was conducted at the farm Cabeceira, Maracaju-MS, sample area have the following history: soybean/corn + brachiaria/cotton/oat + pasture/soybean/formation of pasture/grazing, sampling was carried out in two seasons, dry (May/2009) and rainy (March 2010), in the dry season, crops present were: pasture, corn and cotton + brachiaria and in the rainy season were corn, cotton and soybeans, so the areas in the two evaluation periods were: pasture / maize + brachiaria / cotton, cotton / soybean area and a native of Savanna. Was performed to determine the exchangeable cations, particle size analysis, bulk density, organic carbon, particle size fractionation of organic matter of the soil with the quantification of particulate organic carbon (POC) and organic carbon associated with minerals (OCam). Was also quantified the carbon stock and size fractions. The area of pasture / maize showed higher carbon stock in the particulate fraction in the topsoil. The area of cotton / soy due to its lower clay, showed the greatest loss of carbon. Because of the areas have the same history, the stock of more recalcitrant fraction was not sensitive to variations in coverage. The POC fraction appears more sensitive to different soil covers and seasonality.

Atributos químicos e matéria orgânica em complexos florestais periodicamente inundados na restinga da marambaia - RJ

This study aimed to evaluate and characterize the chemical properties of soil organic matter under two periodically flooded forest formations on the island of Marambaia, Rio de Janeiro. These formations differ on the degree of soil water saturation, caused by the influence of water table, and in the (F1) formation presents the water table nearer the surface compared to the (F2) formation. Samples were collected in layers from 0.00 to 0.05, 0.05-0.10 and 0.10-0.20 m. The soil properties evaluated were: pH, H+ + Al+ 3, Ca+2, Mg+2, Na+, K+, P, N, total organic carbon (TOC) and base saturation (V%), humin carbon fraction (C-HUM), carbon of humic acid fraction (HAF-C) and fulvic acid fraction carbon (FAF-C). Statistically higher pH values were observed for F1. In F2 there are higher values of Mg+2, P, N and V% value. Correlation was found between the concentrations of Mg+2, N, humic acid and fulvic acid with water table in F1, and water table in F2 with Na+ and K+. Fraction C-HUM was more representative of the total organic carbon, followed by C-HAF and C-FAF. The TOC levels were higher in F1. The C /N ratio was lower in F2, with values ranging between 9 and 12, and F1 were found higher values of this relationship, ranging from 9 to 15. Among the pathways of formation of organic soils in both areas it appears that the major route for organic matter accumulation is the inheritance route.

Teores de nitrogênio no solo e nas frações da matéria orgânica sob diferentes sistemas de produção de milho

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Dependência espacial da estabilidade de agregados e matéria orgânica do solo em cambissolo sob cultivo de cana de açucar

The soil management system can modify the natural distribution of the soil attributes and, consequently, the variability of the soil aggregation and organic matter content. Thus, the aim of this work was to evaluate the aggregate stability and organic matter content spatial distribution on a Haplic Cambisol under sugar cane cultivation in the Southern Amazonas State, Brazil. A 70 x 70 m square mesh, with regular 10 meters intervals, was designed over the cultivation area, resulting in 64 sample points. Soil blocks with preserved structure were collected at 0.0-0.2 m depth in order to analyze the aggregate stability and organic matter content. The data were submitted to the descriptive and geostatistical analysis. The soil attributes presented a spatial dependence structure and the greater range was observed for the mean weighted diameter and aggregate class <1.00 mm. Also, there is a spatial relation among the mean geometric diameter, mean weighted diameter and aggregate classes (>2.00 and 2.00-1.00 mm).

Remoção de matéria orgânica e nitrogênio de efluentes provenientes de abatedouros de bovinos por meio de reator aeróbio operando em bateladas sequenciais com adição de coagulante químico

The volume of liquid effluent generated in cattle slaughterhouses is quite high and cannot be released untreated in water bodies due to its high pollution load of predominantly organic origin. To minimize the environmental impacts of its industrial wastewater and meet the local environmental legislation, abattoirs shall make the treatment of these effluents. The present work aims to develop the study of a reactor by sequential batch pilot scale, in order to optimize their performance in treating wastewater from a cattle slaughterhouse. The treatment system used was developed and installed in the Laboratory of Wastewater Treatment, in Faculty of Science and Technology UNESP, Presidente Prudente campus. The procedure used followed the operation of sequential batch reactors, in which all processes and treatment operations occurring sequentially in a single unit, by establishing specific operating cycles, which comprise the following separated phases: aerobic reaction, anoxic reaction, sedimentation and emptying. Aiming to improve the quality of treatment was planned the addition of coagulant Poly Aluminum Chloride (PAC) in the reactor, by determining their optimal dosage by Jar-test trials. Were prepared four steps with specific operating cycles: step one or acclimatization (10 hour of aeration, one hour and 30 minutes of sedimentation and 30 minutes for exchanging the effluent); step 2 (6 hours of aeration or aerobic phase, 4 hours and 45 minutes of stirring or anoxic phase and 1 hour and 15 minutes for sedimentation and exchange effluent); step 3 (2 hours and 30 minutes of aeration, 8 hours and 15 minutes of stirring and 1 hour and 15 minutes for sedimentation and exchange) and step 4 (2 hours of aeration, 8 hours and 45 minutes of stirring and 1 hour and 15 minutes for sedimentation and exchange)... (Complete abstract click electronic access below)

Comparação da eficiência de reatores aeróbios com paralisações escalonadas de aeração em diferentes concentrações de matéria orgânica no tratamento de águas residuárias do processamento de farinha de mandioca

Cassava wastewater, generated during cassava processing, is a highly polluting and toxic waste. This study aimed to assess the relationship of cassava treatment efficiency in two aerobic sequencing batch reactors, cylindrical plastics (31cm height x 9cm diameter), with 2.0 liters capacity and 1.5 liters of work volume, a ratio of diameter and height of the liquid 1:2.5, with a running time of 24 hours and stoppage aeration for 16 hours with average feed of 2,500 and 6,000 mg COD. L -1. COD, pH, SVI and F/M were analyzed. The results obtained in the two reactors showed an average reduction of 94.1% and 76.8% organic content, respectively; pH values showed a rising in the output pH values compared to entry ones; SVI values obtained: 54.1 mL/g, 99.3 mL/g, respectively in a F/M ratio values worked out of 0.4 d-1 and 1,1 d-1 , respectively. The results demonstrated that the process has generated considerable saving in energy consumption compared to traditional continuous systems, was efficient and did not affect the efficiency overly of the reactor.

Avaliação de compostos modelos visando propor um método de diferenciação de matéria orgânica lábil e recalcitrante em ambientes aquáticos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Transformações da matéria orgânica em latossolo vermelho tratado com esterco bovino

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Avaliação da redução de matéria orgânica do tratamento do efluente líquido deextração de fécula de mandioca por processo de biodigestão anaeróbia.

The aim of this paper was to evaluate the efficiency of the treatment of cassava wastewater, separately from the root washing water, by means of ascending flux anaerobic digesters, with separation of the phases, without temperature control or addition of chemical products and to evaluate its suitability by means of its physical and chemical characteristics for throwing in receiving body, public sewage system or application in fertilization and irrigation. After reactors had been stabilized, essays were conducted varying feeding flow with 8.0, 12.0 and 16.0 Ld-1 corresponding to a hydraulic retention time of 8.17, 5.44 and 4.08 days, respectively. The best reduction for organic load reduction were obtained with hydraulic retention times (HRT) of 8.17 and 5.44 days with mean efficiencies of 89.8 and 90.9%, respectively.

Método Mehlich 3 como substituinte ao HCl para extração de Cobre e Zinco em solos com alto teor de matéria orgânica do sul do Brasil

No presente trabalho, foram comparados dois métodos de extração de cobre (Cu) e zinco (Zn) em solos com teor de matéria orgânica (MO) maior que 50g kg-1. Os métodos de extração comparados foram: Extração com HCl 0,1mol L-1 (método padrão para os estados do Rio Grande do Sul e Santa Catarina) e Mehlich 3. Este trabalho foi realizado no Laboratório de Química e Fertilidade do Solo da Universidade do Estado de Santa Catarina (UDESC), no ano de 2009. As duas metodologias de extração foram aplicadas em 286 amostras de solo provenientes do Laboratório de Análise do Solo da UDESC, todas com mais de 50g kg-1 de MO. Os teores de cobre e zinco nos extratos foram determinados por espectrometria de absorção atômica com chama. Os resultados mostraram que houve correlação significativa entre os métodos, Cu (r=0,80) e Zn (r=0,93). A solução de Mehlich 3 extraiu mais cobre e menos zinco, quando comparada à solução de HCl 0,1mol L-1. O Mehlich 3 demonstrou ser eficiente na extração de cobre e zinco em solos com alto teor de MO, podendo substituir o método atual.