(Ce,Cu)∶LiNbO3晶体非挥发全息记录理论研究与优化

根据双中心带输运模型,对(Ce,Cu)∶LiNbO3晶体双中心非挥发全息记录进行了理论研究与优化。推导了(Ce,Cu)∶LiNbO3晶体的微观参量,采用数值方法通过严格求解模拟双中心带输运方程来模拟全息记录过程。分析了记录过程中,记录与敏化光强、Ce和Cu掺杂浓度以及晶体微观参量对(Ce,Cu)∶LiNbO3晶体双中心全息记录的影响。发现(Ce,Cu)∶LiNbO3晶体非挥发全息记录中实现高衍射效率与固定效率的主导因素是深中心Cu,在记录过程中,深中心Cu建立起了很强的空间电荷场。数值模拟的结果经过实验验

LiNbO_3∶Ce∶Cu晶体中绿光非挥发全息记录优化

为了对在LiNbO3∶Ce∶Cu晶体中绿光作为记录光的非挥发全息记录进行优化,联立求解了双中心物质方程和双光束耦合波方程,数值分析了平均空间电荷场(SCF)和衍射效率随晶体的氧化还原态、记录光与敏化光的光强比以及深浅中心的掺杂浓度的变化。结果表明,采用绿光作为记录光在LiNbO3∶Ce∶Cu晶体中进行非挥发全息记录,可以记录得到强光折变光栅,其空间电荷场高达107V/m;获得高达80%以上的固定衍射效率,各相关参量都有较大的优化空间。

Multibeam coupling in photorefractive SBN:Ce

Theoretical and experimental results are presented for simultaneous multibeam coupling in photorefractive SBN:Ce. Within a single crystal, multiple signals are amplified through a coupling process that employs a single pump. The coupling gain of each signal results from coupling both between the pump and the signal and between different signals. The amount of gain that each signal receives is dependent on the intensity of the incident signal; thus a competition for the gain exists among the various signals.

Nonvolatile photorefractive holograms in LiNbO3 : Cu : Ce crystals

We report experimental and theoretical studies of nonvolatile photorefractive holographic recording in LiNbO3:Cu:Ce crystals with two illumination schemes: (1) UV light for sensitization and a red interfering pattern for recording and (2) blue light for sensitization and a red pattern for recording. The results show that the oxidized LiNbO3:Cu:Ce crystals can provide high, persistent refractive-index modulation with weak lightinduced scattering. The optimal working conditions and the prescription for doping and oxidation-reduction processing that yields the maximum refractive-index modulation are discussed. (C) 2000 Optical Society of America OCIS codes: 050.7330, 190.5330, 090.2900.

LiNbO3：Cu：Ce非挥发全息记录掺杂组份比的优化

实验研究了掺杂组份比对LiNbO3：Cu：Ce晶体非挥发全息记录性能的影响。结果表明．在全息记录过程中，掺杂组份比通过改变晶体的紫外光吸收特性而引起全息记录性能的改变。增加LiNbO3：Cu：Ce晶体中Cu和Ce的掺杂组份比会导致晶体对紫外光吸收的增强，进而提高了全息记录灵敏度和固定衍射效率。在弱氧化处理的掺有CuO和Ce2O4的质量分数分别为0.085％和0．011％的LiNbO3：Ce：Cu晶体中．得到了最高的固定衍射效率ηf=32％和记录灵敏度S=0．022cm／J。

Improvement of sensitivity and refractive-index changes in LiNbO3 : Ce : Cu crystals with UV light

A nonvolatile recording scheme is proposed using LiNbO3:Ce:Cu crystals and modulated UV light to record gratings simultaneously in two centres and using red light to bleach the grating in the shallow centre to realize persistent photorefractive holographic storage. Compared with the normal UV-sensitized nonvolatile holographic system, the amplitude of refractive-index changes is greatly increased and the recording sensitivity is significantly enhanced by recording with UV light in the LiNbO3:Ce:Cu crystals. Based on jointly solving the two-centre material equations and the coupled-wave equations, temporal evolutions of the photorefractive grating and the diffraction effciency are effectively described and numerically analysed. Roles of doping levels and recording-beam intensity are discussed in detail. Theoretical results confirm and predict experimental results.

Sensitivity improvement by UV-light recording in LiNbO3 : Ce : Cu crystals

Modulated UV light is used to increase the sensitivity of the two-centre holographic recording. Inherent mechanisms of nonvolatile holographic recording in oxidized and reduced crystals are numerically analysed based on solving the two-centre material equations modilied for UV-Iight recording. Experiments verification is performed with an oxidized crystal and a reduced crystal, and the role of UV intensity on the sensitivity is presented.

Improvement in refractive-index change in LiNbO3 : Ce : Cu by applying an external electric field

By jointly solving two-centre material equations with a nonzero external electric field and coupled-wave equations, we have numerically studied the dependence of the non-volatile holographic recording in LiNbO3:Ce:Cu crystals on the external electric field. The dominative photovoltaic effect of the non-volatile holographic recording in doubly doped LiNbO3 crystals is directly verified. And an external electric field that is applied in the positive direction along the c-axis (or a large one in the negative direction of the c-axis) in the recording phase and another one that is applied in the negative direction of the c-axis in the fixing phase are both proved to benefit strong photorefractive performances. Experimental verifications are given with a small electric field applied externally.

Refractive-index change and sensitivity improvement in holographic recording in LiNbO3:Ce:Cu crystals with green light

Nonvolatile holographic recording is performed with green light in LiNbO3:Ce:Cu crystals. The refractive-index change and the recording sensitivity are times better than those obtained by recording with red light, and higher optical fixing efficiency is obtained. Correspondingly, theoretical investigations are given.

Study of oscillatory behavior of recording process arising from electron-hole competition in strongly oxidized LiNbO3 : Ce : Cu

We have investigated ultraviolet (UV) photorefractive effect of lithium niobate doubly doped with Ce and Cu. It is found the diffraction efficiency shows oscillating behavior Under UV-1ight-recording. A model in which electrons and holes can be excited from impurity centers in the UV region is proposed to study the oscillatory behavior of the diffraction efficiency. Oil the basis of the material equations and the coupled-wave equations, we found that the oscillatory behavior is due to the oscillation of the relative spatial phase shift Phi. And the electron-hole competition may cause the oscillation of the relative spatial phase shift. A switch point from electron grating to hole grating is chosen to realize nonvolatile readout by a red light with high sensitivity (0.4 cm/J). (c) 2005 Elsevier GmbH. All rights reserved.

Optimal recording wavelength for nonvolatile photorefractive holograms in Ce : Cu : LiNbO

Three wavelengths of red, green and blue of recording beams are systemically tested for the UV-assistant recording and optical fixing of holograms in a strongly oxidized Ce:Cu:LiNbO3 crystal. Three different photorefractive phenomena are observed. It is shown that the green beams will optimally generate a critical strong nonvolatile hologram with quick sensitivity and the optimal switching technique could be jointly used to obtain a nearly 100% high diffraction. Theoretical verification is given, and a prescription on the doping densities and on the oxidation/reduction states of the material to match a defined recording wavelength for high diffraction is suggested.

Levantamento e estudo das ocorrências de grafita do Distrito Grafitífero Aracoiába-Baturité, CE

O Distrito Grafitífero Aracoiába-Baturité apresenta depósitos do tipo gnaisse grafitoso (minério disseminado) e veio (minério maciço) com diferentes origens genéticas e com características físicas e ambientes geológicos de formação próprios. O minério tipo gnaisse grafitoso é de origem sedimentar, singenético, com teores de 1,5 a 8% de C, que se distribuem ao longo de duas extensas faixas paralelas, hospedadas na Subunidade Baturité, que constitui um importante metalotecto regional. A associação de grafita metamórfica disseminada em metassedimentos da Sequência Acarápe constitui um geoindicador de antiga bacia sedimentar neoproterozóica e, também, pode ser considerado como zona de geosutura resultante do subsequente fechamento de um oceano primitivo. As rochas desta subunidade correspondem na paleogeografia da Sequência Acarápe aos fácies de sopé de talude e de planície abissal. O minério tipo veio (fluido depositado) é epigenético e, com teores entre 20% e 70% de C, forma corpos tabulares e bolsões, controlados em escala local por estruturas de alívio (falhas, fraturas, zonas de contato, eixos de dobras etc.) que permitiram a percolação de soluções penumatolíticas relacionadas ao corpo plutônico de Pedra Aguda. As variações dos valores das relações entre isótopos estáveis de carbono (δ13C) na grafita do minério disseminado são de -26,72 a -23,52 e do minério maciço de -27,03 a -20,83, revelando sinal de atividades biológicas (bioassinaturas) e permitem afirmar que a grafita das amostras acima são derivadas de matéria orgânica. Foram apresentados os principais guias de prospecção para grafita e testados os seguintes métodos geofísicos: Eletro-Resistividade; GPR - Ground Penetrating Radar; Magnetometria; VLF (Very Low Frequency); e Polarização Induzida Espectral (IPS) / Resistividade (ER). A conjugação dos métodos de Polarização Induzida Espectral (IPS) e Eletro Resistividade (ER) foi o que demonstrou a melhor eficiência. Com relação à determinação do teor de carbono por termogravimetria (ATG), que é o método mais utilizado para este elemento. Verificou-se, que as faixas de queima atribuídas ao carbono no minério do Distrito de Aracoiába-Baturité (340 a 570C e de 570 a 1050C) eram diferentes das faixas do minério de Minas Gerais (350C a 650C e 650C a 1.050C). Esta constatação indica a necessidade de se determinar previamente as faixas de temperatura para cada região pesquisada.

Effects of annealing on the color, absorption spectra, and light yield of Ce : YAlO3 single crystal grown by the temperature gradient technique

YAlO3 single crystal doped with Ce3+ at concentration 1% was grown by the temperature gradient technique. The as-grown crystal was pink. After H-2 annealing or air annealing at 1400degreesC for 20 h, the crystal was turned into colorless. We concluded there were two kinds of color centers in the as-grown crystal. One is F+ center attributed to absorption band peaking at about 530 nm, the other is O- center attributed to absorption band peaking at about 390 nm. This color centers model can be applied in explaining the experiment phenomena including the color changes, the absorption spectra changes, and the light yield changes of Ce:YAP crystals before and after annealing. (C) 2004 American Institute of Physics.