Synthesis, luminescence, energy transfer and Langmuir-Blodgett films of amphiphilic complexes of rare earths with monooctadecyl phthalate

Three new amphiphilic rare earth complexes with only two organic long chains Ln (MOP)(2)Cl (MOP=monooctadecyl phthalate, Ln=Eu, Tb, Gd) were synthesized and characterized by elemental analysis. The complexes (Eu, Tb) showed good luminescence property with long fluorescence lifetime, whereas the intensity and lifetime of Tb complex are greater than those of Eu complex, By measuring the triplet energy levels of ligand based on energy transfer mechanism, above phenomena have been well explained. The Langmuir films of the complexes on the air/water interface were also studied and the results show that all of them have good film-forming property.

Study of molecular orientation in Langmuir-Blodgett films by FTIR

The structure information of orientation and packing of molecular chains can be obtained from infrared transmission and reflection-absorbance (RA) spectra. In the present paper, on the basis of Umemura et al., their FORTRAN program of minicomputer was developed and can be run on 486 personal computer. By comparison of infrared transmission and RA intensities, surface enhancement factors and molecular orientation angle were calculated using the above program, and the influence of complex refractive index, angle of incidence, and thickness of LB film were discussed. These results are consistent with that of Umemura et al.

Characterization of neodymium bisphthalocyanine Langmuir-Blodgett films for gas-sensibility

The deposition of Langmuir-Blodgett film of neodymium bisphthalocyanine derivatives is reported for the first time. Optical absorption data reveal that these films call be deposited in a reproducible manner; results are also presented showing the extreme sensitivity and selectivity of their electrical conductivity to NH3 in room temperature. The Nd bisphthalocyanine LB film is a sensitive, reproducible. rapid and stable gas sensor. Neodymium bisphthalocyanine derivatives will be candidates for thin film gas-sensitive materials. (C) 1998 Elsevier Science S.A. All rights reserved.

Photoluminescence study of Langmuir-Blodgett films of blend poly 3-(2-(5-chlorobenzotriazole)ethyl) thiophene

The multilayer Langmuir-Blodgett (LB) films of pr,ly 3-(2-(5-chlorobenzotriazole)ethyl) thiophene (PCBET) blended with amphibious arachidic acid (AA) were prepared and characterized. The photoluminescence intensity of the blend film was enhanced as the AA increased by a certain amount. The PCBET excimers were not formed in the blend LB films.

Luminescence properties of the Langmuir-Blodgett film of terbium(III) stearoylanthranilate

Terbium(III) stearoylanthranilate has been prepared as a high property Z-type Langmuir-Blodgett (LB) film on various substrates by a vertical transfer process. The UV-visible absorption spectra and the low angle X-ray diffraction peaks have been collected in order to investigate the molecular arrangement and aggregation in the LB films. The average molecular orientation in multilayer stacking was determined by Attenuated Total Reflection Spectroscopy. The influence of the chemical environment of terbium within the LB films on the luminescence properties has been discussed. (C) 1997 Elsevier Science S.A.

Direct deposition and characterization of Langmuir-Blodgett monolayers of soluble polyimides

Langmuir-Blodgett (LB) monolayers of three kinds of soluble polyimides were prepared with the direct deposition method, The monolayer structures were characterized with W-vis absorption spectroscopy, the wide angle X-ray scattering method and electrochemical techniques. The polyimide molecules in the LB monolayers lie orderly on the substrate surfaces with the orientation in which the dianhydride group is normal to the substrate surface and two carbonyl oxygen groups close to the surface. Therefore, the thickness of the three kinds of polyimide LB monolayers are the same because it depends on the distance between the two carbonyl oxygen groups in the same ring. The area of monomeric units are dependent on the length of the diamine group. The model of the molecular packing proposed from the quantomechanical calculation is in good agreement with the experimental results. (C) 1997 Elsevier Science S.A.

Lanthanide ion induced formation of stripes domain structure in phospholipid Langmuir-Blodgett monolayer film observed by atomic force microscopy

Long-range ordered stripes domain structures were observed in Dipalmitoylphosphatidylcholine (DPPC) Langmuir-Blodgett monolayer film which was spread on the subphase of lanthanide ion (Eu3+) solution and transferred to a freshly cleaved mica substrate by vertical deposition. This novel phenomenon was discussed in terms of the competitive interaction of dipole-dipole and electrostatic interactions of the DPPC molecules combined with lanthanide ions with those DPPC molecules free of lanthanide ions.

MECHANISM OF IRON INHIBITION BY STEARIC-ACID LANGMUIR-BLODGETT MONOLAYERS

Using the Langmuir-Blodgett (LB) technique, stearic acid (SA) monolayers were deposited onto the surface of an iron (Fe) electrode to study the inhibition effect and the mechanism of SA in a neutral medium. Molecular orientation and the number of deposited monolayers of SA were shown to have marked effects on inhibition of Fe corrosion. The inhibition mechanism depended mainly on blocking.

金属缓蚀剂Langmuir－Blodgett膜及缓蚀机理的研究

应用Ｌａｎｇｍｕｉｒ－Ｂｌｏｄｇｅｔｔ（ＬＢ）技术研究了硬脂酸和十六烷基三甲基溴化胶等金属缓蚀剂在碳钢电极上的取向。单分子膜覆盖层数及分子结构对其缓蚀作用的影响．在实验技术上实现了对缓蚀剂表面膜在分子规模上的控制，文中讨论了这两种缓蚀剂的缓蚀机理．

INHIBITION OF CORROSION BY HEXADECYL TRIMETHYL AMMONIUM BROMIDE LANGMUIR-BLODGETT MONOLAYERS ON CARBON-STEEL

Langmuir-Blodgett (LB) monolayers of hexadecyl trimethyl ammonium bromide (HTAB) were deposited onto a carbon steel surface to investigate the inhibition of corrosion by measurement of the polarization resistance and cyclic voltammetry. The corrosion proc

PREPARATION AND CHARACTERIZATION OF LANGMUIR-BLODGETT-FILMS OF PORPHYRINS WITHOUT LONG ALKYL CHAINS

A number of synthetic and natural source porphyrins without long alkyl chains have been examined in the form of monolayers and multilayers on solid substrates. These compounds formed stable solid condensed films with measured molecular areas compatible with a vertical or tilted orientation of these molecules on the substrate. Spectral study and fluorescence lifetime measurement, in particular, revealed the formation of aggregates as the main species in these films.

DETERMINATION OF THE MOLECULAR-ORIENTATION OF A PHTHALOCYANINE DERIVATIVE IN A LANGMUIR-BLODGETT-FILM BY POLARIZED UV VIS SPECTRA

Langmuir-Blodgett (LB) films of (p-carboxyphenoxy)-tri(2,4-di-tert-pentyl phenoxy)phthalocyanine copper(II) (asyCuPc) are prepared; the associated forms of the compound in chloroform solution and the particular orientation of asyCuPc molecular macrocycles in LB films is determined by polarized UV-VIS.

THE CHARACTERIZATION OF 2 COPPER PHTHALOCYANINE LANGMUIR-BLODGETT-FILMS AND THEIR GAS-SENSITIVE PROPERTIES

The monolayer and deposition behaviour of a symmetrically substituted copper tetra-4-(2, 4-di-t-amylphenoxy) phthalocyanine (tapCuPc) and an asymmetrically substituted copper [tri-4-(2, 4-di-t-amylphenoxy)-mono-4-(-2-methoxyethoxy)]phthalocyanine (AsyCuPc) were investigated. The results on monolayer behaviour and spectroscopic characterization of the LB films show that both CuPc molecules in a monolayer at the air-water interface and the LB films are stacked and inclined. The gas-sensitive properties show that the responding speed of AsyCuPc LB film is faster than that of tapCuPc LB film.

一种具有“浮萍”结构的单分子膜与Langmuir-Blodgett多层膜

本文以St-DVB微凝胶/甲基丙烯酸两性接枝共聚物制成了一种新型“浮萍”结构的单分子膜,并转移制备了LB多层膜,对其单分子膜的性质、LB多层膜的二维有序结构及膜的热稳定性进行了较深入的研究。