508 resultados para 1531


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We study theoretically the low-temperature electronic transport property of a straight quantum wire under the irradiation of a finite-range transversely polarized external terahertz (THz) electromagnetic (EM) field. Using the free-electron model and the scattering matrix approach, we show an unusual behaviour of the electronic transmission of this system. A sharp step-structure appears in the electronic transmission probability as the EM field strength increases to a threshold value when a coherent EM field is applied. We demonstrate that this effect physically comes from the inelastic scattering of electrons with lateral photons through intersubband transitions.

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线程池被广泛地应用在中间件如Web应用服务器、事务监控器等的实现中。实现线程池的方法主要有半同步/半异步(Half-Sync/Half-Asyn)模式和领导者/跟随者(Leader/Follower)模式。实现了这两种线程池,从理论上分析了它们的性能,并进行了性能实验。实验数据表明Leader/Follower模式具有较高的性能优势。

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应用生态学是迅猛发展的现代生态学的主体 .寻求解决人口、资源、环境等问题是应用生态学发展的主要动力 .经过 4 0年的发展 ,应用生态学已发展成为一个庞大的学科门类 .应用生态学未来的发展应更多地关注受人类影响和管理的生态系统并将人视为生态系统的组成成分 .应用生态学在当前和今后应给予优先重视的研究领域 ,包括生态系统与生物圈的可持续利用、生态系统服务与生态设计、转基因生物的生态学评价、生物入侵生态学、流行病生态学、生态预报、生态过程及其调控等 .在今后若干年内 ,围绕这些领域 ,可能会出现广泛而活跃的研究热潮以及一些新的特点 .

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National Natural Science Foundation of China [30590381]; Knowledge Innovation Program of the Chinese Academy of Sciences [KZCX2YW-432]; International Partnership Project

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The reaction mechanism of Pd(O)-catalyzed allenes silastannation reaction is investigated by the density functional method B3LYP. The overall reaction mechanism is examined. For the allene insertion step, the Pd-Si bond is preferred over the Pd-Sn bond. The electronic mechanism of the allene insertion into Pd-Si bond to form sigma-vinylpalladium (terminal-insertion) and sigma-allylpalladium (internal-insertion) insertion products is discussed ill terms of the electron donation and back-donation. It is found that the electron back-donation is significant for both terminal- and internal-insertion. During allene insertion into Pd-Si bond, internal-insertion is preferred over terminal-insertion. By using methylallene, the regio-selectivity for the monosubstituted allene insertion into Pd-Si and Pd-Sn bond is analyzed.

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Enantiomerically pure dinuclear ruthenium complexes with 1,2-dicarbonylhydrazide as a bridging ligand are optically active in the visible and near infrared spectral regions depending on the oxidation states of the metal centers and are useful as an electrochemically driven near infrared chiroptical switch.