487 resultados para 1320


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A set of a-SiOx:H (0.52 < x < 1.58) films are fabricated by plasma-enhanced-chemical-vapor-deposition (PECVD) method at the substrate temperature of 250degreesC. The microstructure and local bonding configurations of the films are investigated in detail using micro-Raman scattering, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). It is found that the films are structural inhomogeneous, with five phases of Si, Si2O:H, SiO:H, Si2O3:H and SiO2 that coexist. The phase of Si is composed of nonhydrogenated amorphous silicon (a-Si) clusters that are spatially isolated. The average size of the clusters decreases with the increasing oxygen concentration x in the films. The results indicate that the structure of the present films can be described by a multi-shell model, which suggests that a-Si cluster is surrounded in turn by the subshells Of Si2O:H, SiO:H, Si2O3:H, and SiO2.

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以深圳大学用户对国外网络数据库的使用为例,总结各数据库使用统计数据的获取途径,统计各数据库的使用情况及成本效益,并与其他高校进行对比,最后从图书馆及数据库商两个角度提出建议

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从可证明安全的角度研究使用压缩函数的非平衡Feistel结构(UFN-C)的安全性,证明了k+1轮UFN-C是伪随机的,k+2轮UFN-C是超伪随机的;进一步地,探讨了UFN-C的有效构造,降低了Naor和Reingold在1999年文章中类似结构对伪随机函数个数的要求.最后,针对一类具体的UFN-C--SMs4,分析其广义形式SMS4-like结构的伪随机性和超伪随机性,为设计与使用该类结构的分组密码提供了可证明安全的理论依据.

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网络应用程序中为了保持程序的交互性,服务器端的控制程序如CGI(command gateway interface)程序需要在不同的脚本程序之问切换,这样不可避免的会造成控制信息的丢失.为了避免这些问题,介绍了将函数式程序设计语言的一些方法,如Continuation、CPS(eontinuationpassing style)等,并将它们应用到网络程序设计中,不仅简化了设计过程,也提高了程序的安全性,并可以在更一般的语言中实现.

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IEECAS SKLLQG

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通过野外实地调查与相对干扰度计算,采用物种多样性指数及方差分析、相关分析等方法,对长白山北坡原始林(阔叶红松林)与2种次生林(杂木林与桦木林)的植物物种多样性进行了比较研究,并对影响物种多样性的可能因素进行了系统分析。结果表明:原始林共记录植物物种91种,分别隶属于46科72属;杂木林共记录植物物种128种,分别隶属于53科92属;桦木林共记录植物物种108种,分别隶属于52科87属。仅从Shannon-w iener多样性指数看,桦木林的乔木层、草本层和总体多样性均最小,而灌木层多样性最大;原始林在乔木层多样性小于杂木林,但是在灌木层、草本层和总体多样性均大于杂木林。原始林与次生林草本层的多样性较高,均大于相应的乔木层和灌木层。以原始林为参照,较大的干扰强度使乔木层多样性降低,而较小的干扰强度不仅不会降低乔木层多样性,反而可以增加其多样性;灌木、草本层的多样性受干扰的变化与乔木层相反。

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BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated.

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The miscibility and the isothermal crystallization kinetics for PBT/Epoxy blends have been studied by using differential scanning calorimetry, and several kinetic analyses have been used to describe the crystallization process. The Avrami exponents n were obtained for PBT/Epoxy blends. An addition of small amount of epoxy resin (3%) leads to an increase in the number of effective nuclei, thus resulting in an increase in crystallization rate and a stronger trend of instantaneous three-dimensional growth. For isothermal crystallization, crystallization parameter analysis showed that epoxy particles could act as effective nucleating agents, accelerating the crystallization of PBT component in the PBT/Epoxy blends. The Lauritzen-Hoffman equation for DSC isothermal crystallization data revealed that PBT/Epoxy 97/3 had lower nucleation constant K, than 100/0, 93/7, and 90/10 PBT/Epoxy blends. Analysis of the crystallization data of PBT/Epoxy blends showed that crystallization occurs in regime II. The fold surface free energy, sigma(e) = 101.7-58.0 x 10(-3) J/m(2), and work of chain folding, q = 5.79-3.30 kcal/mol, were determined. The equilibrium melting point depressions of PBT/Epoxy blends were observed and the Flory-Huggins interaction parameters were obtained.

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The electrocatalytic oxidation of methanol at the Titanium oxide (TiOx, x<2) film modified with Pt microparticles has been studied. The results show that the modified electrodes exhibit a significant electrocatalytic activity and good stability for the oxidation of methanol. Under the optimal conditions, the peak current density at 0.58 V for the oxidation of methanol in the positive-going sweep is about 526 mA/cm(2) at the scan rate of 5 mV/s in 0.5 mol/L CH3OH and 0.5 mol/L H2SO4 solution and the over potential of the methanol oxidation at the modified electrode increases about 30 similar to 40 mV after 70 minutes at the current density of 100 mA/cm(2) and 50 mA/cm(2). The enhanced electrocatalytic activity and good stability are ascribed to the high dispersion of Pt microparticles in and on the TiOx film and the synergistic effect between Pt microparticles and TiOx.

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直接甲醇质子交换膜燃料电池(DMPEMFC)可用作未来电动车辆的动力电源[1],但要达到实际应用还有大量问题有待进一步解决.目前限制DMPEMFC实际应用的主要问题是甲醇阳极氧化催化剂低的活性、高的价格及催化剂的毒化.就目前对于甲醇氧化电催化剂研究的…

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详细研究了流动注射-鲁米诺-高碘酸钾-过氧化氢体系化学发光行为,给出了反应的最佳条件。拟定了一种化学发光测定过氧化氢的新方法。方法的检测限为3.0X10-8mol/LH2O2;线性范围为2.0×10-7~6.0×10-4mol/L。评价了该体系的应用前景。

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本文基于POM模式,对渤海的潮汐潮流进行了研究。给出了渤海正压三维全日分潮和半日分潮的潮汐潮流数值模拟结果,并与以前的结果和实测数据进行了对比,结果符合得很好。在潮汐潮流模拟基础上,又系统地计算了渤海欧拉余流、斯托克斯漂流和质点跟踪拉哥朗日余流。对欧拉余流、欧拉输运余流和质点跟踪拉哥朗日余流进行了对比。三者局部具有明显的差异,在渤海中部一致表现为顺时针环流。同时得到质点跟踪余流随深度的不同流速及流型均有差异,并且与释放时刻有关,给出了拉哥朗日余流椭轴。得到渤海潮余流的结果同以往冯士笮弱非线性理论计算所得到的渤海潮余流不同。