Geochemistry, isotopic ratios and aldehyde concentrations of frost flowers, snow and ice near Barrow, Alaska

Frost flowers, intricate featherlike crystals that grow on refreezing sea ice leads, have been implicated in lower atmospheric chemical reactions. Few studies have presented chemical composition information for frost flowers over time and many of the chemical species commonly associated with Polar tropospheric reactions have never been reported for frost flowers. We undertook this study on the sea ice north of Barrow, Alaska to quantify the major ion, stable oxygen and hydrogen isotope, alkalinity, light absorbance by soluble species, organochlorine, and aldehyde composition of seawater, brine, and frost flowers. For many of these chemical species we present the first measurements from brine or frost flowers. Results show that major ion and alkalinity concentrations, stable isotope values, and major chromophore (NO3- and H2O2) concentrations are controlled by fractionation from seawater and brine. The presence of these chemical species in present and future sea ice scenarios is somewhat predictable. However, aldehydes, organochlorine compounds, light absorbing species, and mercury (part 2 of this research and Sherman et al. (2012, doi:10.1029/2011JD016186)) are deposited to frost flowers through less predictable processes that probably involve the atmosphere as a source. The present and future concentrations of these constituents in frost flowers may not be easily incorporated into future sea ice or lower atmospheric chemistry scenarios. Thinning of Arctic sea ice will likely present more open sea ice leads where young ice, brine, and frost flowers form. How these changing ice conditions will affect the interactions between ice, brine, frost flowers and the lower atmosphere is unknown.

Frozen flowers. March 1952 [Dr. Elzada Clover and botany students]

On negative sleeve: Dr. Elzada Clover, associate professor of botany, (second from right) distributes frozen water lily buds to botany students at the U of M. Students are (left and right) Mrs. Benson Murray, N.Y.; Oka Nichols, Crawfordsville, Ind.; and Nancy Pridmore, Oxford, Mich. Frozen flowers are kept in regular cardboard containers with transparent tops

Campus views (paths, trees, etc.)

Image includes old law building, old Mason Hall, South Hall

Trees and rocks September 25th.

[From Jasper Cropsey Sketch book, 1855-1856]

Sketch of pine trees.

[From Jasper Cropsey Sketch book, 1855-1856]

View of cabin, bridge and trees.

[From Jasper Cropsey Sketch book, 1855-1856]

Lake, ship and trees.

[From Jasper Cropsey Sketch book, 1855-1856]

The language of flowers with illustrative poetry : to which are now first added the calendar of flowers, and the dial of flowers.

Probably based on "Le langage des fleurs" by Mme. Louise Cortambert, who wrote under the pseudonym "Charlotte de Latour."

The fruit garden : a treatise intended to explain and illustrate the physiology of fruit trees ... illustrated with upwards of 150 figures /

Includes index.

The fruit garden : a treatise intended to explain and illustrate the physiology of fruit trees, the theory and practice of all operations connected with the propagation, transplanting, pruning and training of orchard and garden trees ... the laying out and arranging different kinds of orchards and gardens ... : illustrated with upwards of 150 figures ... /

Advertisments on last page.

Flowering trees.

Mode of access: Internet.

The gardeners labyrinth, or, A new art of gardening : wherein is laid down new and rare inventions and secrets of gardening not heretofore known : for sowing, planting, and setting all manner of roots, herbs, and flowers, both for the use of the kitchen garden, and a garden of pleasure ... /

"Reprinted for the first time since the edition dated 1652, from the copy now owned by Mrs. Rosetta E. Clarkson."--T.p. verso.