典型陆地环境污染物浓度区域化变量的微分几何表达与分析

基于应用微分几何进行环境数据分析及建模的基本概念,提出了典型陆地环境污染物浓度区域化变量的微分几何表达与分析方法.基于陆地环境污染物浓度区域化变量的数据结构,将污染物浓度空间分布转换为三维形式,并采用二次曲面进行拟合,建立了区域化变量数据与其空间属性间的数学定量关系.通过对几种典型空间结构如凸状、凹状、脊状、鞍状及单坡等典型浓度曲面的分析与刻画,对该方法进行了举例说明.此方法适用于陆地环境污染物浓度区域化变量分析.

沈阳市苏家屯区耕层土壤养分空间变异性研究

利用地统计学和地理信息系统相结合的方法,研究了沈阳市苏家屯区耕地土壤(0～20 cm)有机质、速效氮、速效磷、速效钾含量的空间变异性特征.结果表明,各变量符合正态分布或经对数转换后符合正态分布,最佳的变异函数理论模型均为球状模型.有机质具有较强的空间相关性(C0与C0+C比值为24.11％),速效氮、速效磷、速效钾具有中度的空间相关性(C0与C0+C比值分别为29.53％、60.77％、58.82％).各变量的空间自相关距离分别为26.051、28.293、15.132和23.813 km.有机质和速效氮的空间变异主要受结构性因子(如成土因子)的影响,速效磷和速效钾主要受随机性因子(如施肥)的影响.Kriging插值绘制出的养分含量空问分布图显示了养分的空间分布格局,它将有助于进一步监测养分动态,为农业和环境管理提供数字地图支持.

基于随机背包的公钥密码

该文构造了一个背包型公钥密码算法。该背包公钥密码具有如下优点:加解密只需要加法和模减法运算,因此加解密速度快;该算法是基于随机背包问题而不是易解背包问题而构造的;证明了在攻击者不掌握私钥信息情况下该密码算法能抵抗直接求解背包问题的攻击,包括低密度攻击和联立丢番图逼近攻击等;证明了攻击者能够恢复私钥信息与攻击者能够分解一个大整数是等价的。分析表明,该算法是一个安全高效的公钥加密算法。

Synthesis and Characterization of Coil-Rod-Coil Triblock Copolymers Comprising Fluorene-Based Mesogenic Monodisperse Conjugated Rod and Poly(ethylene oxide) Coil

A series of coil-rod-coil triblock copolymers (i.e., F3T8EO8, F3T8EO17, F3T8EO45, and F3T8EO125) with a mesogenic monodisperse conjugated oligomer comprising 3 fluorene, 8 thiophene, and 2 phenyl units as the rod and poly(ethylene oxide) (PEO) as the coil were synthesized. A reference compound, that is F3T8ME2, with the identical rod but without PEO was also prepared for comparison. The volume fraction of PEO (f(PEO)) was 0, 0.16, 0.28, 0.50, and 0.73 for F3T8ME2, F3T8EO8, F3T8EO17, F3T8EO45, and F3T8EO125, respectively. It was found that the introduction of PEO into the triblock copolymers encouraged the formation of H-type aggregation and f(PEO)-dependent highly ordered mesophases while f(PEO) < 0.73. For F3T8ME2, only nematic mesophase was observed. In contrast, F3T8EO8 and F3T8EO17, with f(PEO) of 0.16 and 0.28, respectively, are smectic A (SA) mesomorphism.

Structural and Bluish-White Luminescent Properties of Li+-Doped BPO4 as a Potential Environmentally Friendly Phosphor Material

Many efforts have been devoted to exploring novel luminescent materials that not contain expensive or toxic elements, or do not need a mercury vapor plasma source. In this paper, BPO4 and Li+-doped BPO4 powder samples were prepared by the Pechini-type sol-gel (PSG) process. The structure and optical properties of the resulting samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM), photoluminescence (PL) excitation and emission spectra, kinetic decay, and X-ray photoelectron spectra (XPS), respectively. It was found that PSG -derived Li+-doped BPO4 annealed at 960 degrees C exhibited bright bluish-white emission centered at 416 nm. The luminescence decay curves analysis indicates that each sample has two kinds of lifetimes (5.9 ns and 0.529 ms) and two types of kinetic decay behaviors which can be fitted into a single-exponential function and a double-exponential function, respectively.

Facile synthesis of polyaniline nanofibers using pseudo-high dilution technique

A new approach for the synthesis of polyaniline nanofibers under pseudo-high dilute conditions in aqueous system has been developed. High yield nanoscale polyaniline fibers with 18-110 nm in diameter are readily prepared by a high aniline concentration 0.4 M oxidation polymerization using ammonium persulfate (APS) as an oxidant in the presence of hydrochloric acid (HCl), perchloric acid (HClO4), (1S)-(+)-10-camphorsulfonic acid (CSA), acidic phosphate PAEG120 (PA120) and sulfuric acid (H2SO4) as the dopants. The novel pathway always produces polyaniline nanofibers of tunable diameters, high conductivity (from 10(0) to 10(1) S/cm) and crystallinity.

On improving the phase stability and thermal expansion coefficients of lanthanum cerium oxide solid solutions

The phase stability of lanthanum cerium oxide (La2Ce2O7), which is stable up to 1400 degrees C, and the thermal expansion coefficient of La2Ce2O7 doped with Ta2O5 or WO3 were studied. The thermal expansion coefficient of La2Ce2O7 below 400 degrees C was increased by adding more CeO2 or doping with either Ta2O5 or WO3.

Synthesis and crystal structure of (1,3-(Bu2C5H3)-Bu-t)(2)Sm(mu-Cl)(2)Li(THF)(2)

Anhydrous SmCl3 reacts with two equal of Li(1-3-(Bu2C5H3)-Bu-t) to give a complex (1,3-(Bu2C5H3)-Bu-t)(2) Sm(mu -Cl)(2)Li(THF)(2) (C34H58Cl2LiO2Sm, M-r = 726.99), monoclinic, space group P2(1)/n, a = 10.615(2), b = 21.037(4), c = 17.166(3) Angstrom, beta = 93.60(3)degrees, V = 3825.7 (13) Angstrom (3), Z = 4, D-c = 1.262 Mg/m(3), mu = 1.699 mm(-1) and F(000) = 1508, final R = 0.0387 and wR = 0.0741 for 5320 observed[I greater than or equal to2 sigma (I)] reflections. The average Sm - C distance is 2.73 Angstrom. Sm - Cl1 and Sm - Cl2 distances are 2.719 (2) and 2. 697 (2) Angstrom, respectively. Two 1, 3-(Bu2C5H3)-Bu-t-ring centroids and two mu (2)-bridging chloride atoms around Sm atom form a distorted tetrahedron.