Interaction of the Trinuclear Triangular Secondary Building Unit [Cu 3 (μ 3 -OH)(μ-pz) 3 ] 2+ with 4,4′-Bipyridine. Structural Characterizations of New Coordination Polymers and Hexanuclear Cu II Clusters. 2°

By reacting 4,4′-bipyridine (bpy) with selected trinuclear triangular CuII complexes, [Cu3(μ3-OH)(μ-pz)3(RCOO)2(LL′)] [pz = pyrazolate anion; R = CH3, CH3CH2, CH2═CH, CH2═C(CH3); L, L′ = Hpz, H2O, MeOH] in MeOH, the substitution of monotopic ligands by ditopic bpy was observed. Depending on the stoichiometric reaction ratios, different compounds were isolated and structurally characterized. One- and two-dimensional coordination polymers (CPs), as well as two hexanuclear CuII clusters were identified. One of the hexanuclear clusters self-assembles into a supramolecular three-dimensional structure, and its crystal packing shows the presence of two intersecting channels, one of which is almost completely occupied by guest bpy, while in the second one guest water molecules are present. This compound also shows a reversible, thermally induced, single-crystal-to-single-crystal transition.

Synthesis and Structural Characterizations of New Coordination Polymers Generated by the Interaction Between the Trinuclear Triangular SBU [Cu 3 (μ 3 -OH)(μ-pz) 3 ] 2+ and 4,4′-Bipyridine. 3°

The reactions of 4,4′-bipyridine with selected trinuclear triangular copper(II) complexes, [Cu3(μ3-OH)(μ-pz)3(RCOO)2Lx], [pz = pyrazolate anion, R = CH3(CH2)n (2 ≤ n ≤ 5); L = H2O, MeOH, EtOH] yielded a series of 1D coordination polymers (CPs) based on the repetition of [Cu3(μ3-OH)(μ-pz)3] secondary building units joined by bipyridine. The CPs were characterized by conventional analytical methods (elemental analyses, ESI-MS, IR spectra) and single crystal XRD determinations. An unprecedented 1D CP, generated through the bipyridine bridging hexanuclear copper clusters moieties, two 1D CPs presenting structural analogies, and two monodimensional tapes having almost exactly superimposable structures, were obtained. In one case, the crystal packing makes evident the presence of small, not-connected pores, accounting for ca. 6% of free cell volume.

Der Broyner bukh : ṿegn der unṭertsindung funem Raykhsṭag un ṿegn Hiṭlerishn ṭeror

Jidd., in hebr. Schr.

Laternenlied: Mit Feuer: 1. Sie ler-nen nichts, sie ler-nen nichts die Herrn Hochwohl-ge-bo-ren! Ver-geb-lich schmettert des Ge-richts Po-sau-ne ih-ren Oh-ren ...

Welsch (Projektbearbeiter): Abdruck eines Revolutionsliedes (nach dem Vorbild des französischen 'Ça ira' von 1789): "Weil denn die Herrn vom bes-sern Blut die neu-e Zeit nicht ler-nen: drum hängt die Herren kurz und gut ... hoch, hoch an die La-ter-nen!" Vgl. dazu Dunder, W. G.: Denkschrift über die Wiener October-Revolution; Wien 1849 S. 36: "Dieses Gedicht erschien abgedruckt im politischen Studenten-Courier vom 4. October [1848], Nr. 91, redigirt von Adolf Buchheim und Oscar Falke [recte Georg Peter] ..."

Jung Juda [Illustration] : (Titelblatt)

Scan von Monochrom-Mikroform

Jung-hebräische Lyrik

Samuel Meisels

Jung-hebräische Lyrik

Samuel Meisels

Jung-Juda : (Gedicht)

Hugo Zuckermann

Position Errors Caused by GPS HI Blunders

Height of instrument (HI) blunders in GPS measurements cause position errors. These errors can be pure vertical, pure horizontal, or a mixture of both. There are different error regimes depending on whether both the base and the rover both have HI blunders, if just the base has an HI blunder, or just the rover has an HI blunder. The resulting errors are on the order of 30 cm for receiver separations of 1000 km for an HI blunder of 2 m. Given the complicated nature of the errors, we believe it would be difficult, if not impossible, to detect such errors by visual inspection. This serves to underline the necessity to enter GPS HIs correctly.

Das jüdische "Jung-Ungarn"

l. l.