(Table 2) Stable isotopes in foraminifers at DSDP Leg 78

Analyses of stable isotopes of monospecific planktonic foraminifers (G. quadrilobatus group) and monogeneric benthic foraminifers (Cibicidoides spp.) from late Neogene Atlantic Site 502 and Pacific Site 503 were conducted in order to determine the paleoceanographic changes resulting from the late Neogene uplift of the Panama Isthmus and from climatic cooling. In general, results at each site are similar to those from previous studies for the late Miocene and late Pliocene time interval, documenting the late Miocene (6 Ma) shift in carbon isotopes and the inferred growth of permanent Northern Hemisphere continental ice sheets beginning about 3.2 Ma. Comparison of Atlantic-Pacific planktonic-benthic isotope data for four stratigraphic intervals (~6-8, ~5-6, ~3-5, and ~2-3 Ma) suggests that increasing isolation of Atlantic and Pacific low-latitude waters may be related to the emergence of the Panama Isthmus. The contrast between Atlantic and Pacific benthic foraminiferal d13C increased in two steps from 0.60 per mil to 1 per mil (the modern contrast) at about 6 Ma and 3 Ma. The first increase (0.15 per mil) may represent the end of previously limited deep-water communication between the Atlantic and Pacific at the present location of Panama. The second increase (0.25 per mil) may be due to increased production of North Atlantic Deep Water. This probably reflects the development of modern deep-sea circulation. The d18O of planktonic foraminifers begins to increase in Atlantic Site 502 at 4.2 Ma and may reflect the increasing salinity of the North Atlantic Ocean arising from diminishing surface-water exchange across Panama. This increase is clearly shown by contrasting the d18O of Atlantic and Pacific planktonic foraminifers, as well as the d18O of planktonic and benthic foraminifers at Site 502. This inferred increase in surface-water salinity begins at the time of increasing provinciality of Atlantic and Pacific planktonic foraminifers.

Absolute abundances of benthic foraminifers and stable isotopes from the Alvin dives 3709-3712

The presence of gas hydrates on the Blake Ridge diapir, northeastern Atlantic Ocean, offers an opportunity to study the impact of methane seepage on the ecology and geochemistry of benthic foraminifera in the late Holocene. Three push cores, covering a time span of ~ 1000 yrs, were retrieved from three distinct microhabitats at the top of the diapir at a water depth of ~ 2150 m: (i) sediments away from seepage (control core), (ii) sediments overlain by clusters of methanotrophic and thiotrophic bivalves, and (iii) chemoautotrophic microbial mats. The foraminiferal assemblages at the two seep sites are marked by a reduction in benthic foraminiferal species diversity, coupled with a near-absence of agglutinated species. However, an opportunistic population rise in CH4- or H2S-tolerant calcareous species (e.g., Globocassidulina subglobosa and Cassidulina laevigata) that utilize the abundant trophic resources at the seeps has led to an increase in the overall assemblage density there. The delta18O and delta13C values of three species of benthic foraminifera - Gyroidinoides laevigatus, Globocassidulina subglobosa, and Uvigerina peregrina - and the planktonic species Globorotalia menardii were acquired from all three cores. The benthic species from methane seeps yield delta13C values of 0.1 to - 4.2 (per mil VPDB), that are distinctly more 13C-depleted relative to the delta13C of 0.4 to - 1.0 (per mil VPDB) at the control (off seep) site. The species from a mussel-bed site exhibit more negative delta13C values than those from microbial mats, possibly reflecting different food sources and higher rate of anaerobic oxidation of methane. The positive delta13C values in the paired planktonic species suggest that authigenic carbonate precipitation did not overprint the observed 13C depletions. Hence the probable cause of negative delta13C of benthic foraminifera is primary calcification from Dissolved Inorganic Carbon (DIC) containing mixed carbon fractions from (a) highly 13C-depleted, microbially-oxidized methane and (b) a seawater source.

Stable isotopes measured on Miocene benthic foraminifera from ODP sites 202-1237 and 184-1146

One of the most enigmatic features of Cenozoic long-term climate evolution is the long-lasting positive carbon-isotope excursion or "Monterey Excursion", which started during a period of global warmth after 16.9 Ma and ended at not, vert, similar 13.5 Ma, approximately 400 kyr after major expansion of the Antarctic ice-sheet. We present high-resolution (1-9 kyr) astronomically-tuned climate proxy records in two complete sedimentary successions from the northwestern and southeastern Pacific (ODP Sites 1146 and 1237), which shed new light on the middle Miocene carbon-isotope excursion and associated climatic transition over the interval 17.1-12.7 Ma. We recognize three distinct climate phases with different imprints of orbital variations into the climatic signals (1146 and 1237 d18O, d13C; 1237 XRF Fe, fraction > 63 µm): (1) climate optimum prior to 14.7 Ma characterized by minimum ice volume and prominent 100 and 400 kyr variability, (2) long-term cooling from 14.7 to 13.9 Ma, principally driven by obliquity and culminating with rapid cryosphere expansion and global cooling at the onset of the last and most pronounced d13C increase, (3) "Icehouse" mode after 13.9 Ma with distinct 100 kyr variability and improved ventilation of the deep Pacific. The "Monterey" carbon-isotope excursion (16.9-13.5 Ma) consists overall of nine 400 kyr cycles, which show high coherence with the long eccentricity period. Superposed on these low-frequency oscillations are high-frequency variations (100 kyr), which closely track the amplitude modulation of the short eccentricity period. In contrast to d13C, the d18O signal additionally shows significant power in the 41 kyr band, and the 1.2 Myr amplitude modulation of the obliquity cycle is clearly imprinted in the 1146 d18O signal. Our results suggest that eccentricity was a prime pacemaker of middle Miocene climate evolution through the modulation of long-term carbon budgets and that obliquity-paced changes in high-latitude seasonality favored the transition into the "Icehouse" climate.