Foraminíferos em um transecto de manguezal da Ilha do Cardoso (SP): distribuição em função da frequência de inundação e modelos para reconstruções paleoambientais no setor de petróleo & gás

O estudo do conteúdo de foraminíferos de 8 amostras de sedimentos superficiais coletados em manguezal do norte da Ilha do Cardoso, sul do Estado de São Paulo, no verão (período chuvoso) de 2001, ao longo de um transecto no sentido da Baía de Trapandé para o interior, revelou dois segmentos distintos: a) uma planície inferior lamosa, com menor tempo de exposição sub-aérea e maior diversidade específica, dominada por Ammotiumcassis, A.salsum, Arenoparrella mexicana e Trochamminainflata, com abundância expressiva de Caroniaexilis na parte mais baixa e de Miliammina fusca na parte mais alta; b) uma planície superior arenosa, com maior tempo de exposição sub-aérea e menor diversidade, dominada por M. fusca e com abundância expressiva de T. inflatana parte mais baixa. Os sedimentos investigados são colonizados por foraminíferos exclusivamente aglutinantes, representados por 21 espécies de 16 gêneros. Dados de abundância relativa, riqueza, diversidade e equitatividade das espécies ao longo do transecto são apresentados, bem como os valores de salinidade, pH, oxigênio dissolvido e temperatura, medidos a partir da água intersticial dos sedimentos no momento da coleta das amostras. São feitas comparações com um estudo anterior, similar, que focalizou amostras coletadas, nos mesmos pontos, no inverno (período seco) de 2002. Os resultados obtidos interessam às análises de sistemas estuarinos modernos e antigos, bem como a projetos envolvidos com o diagnóstico do estado de conservação de áreas litorâneas, sendo úteis ao Setor de Petróleo e Gás

Pré-sal e o novo marco regulatório: um estudo sobre o fundo social

This work intends to discuss about the current happenings in oil sector, and how the recent discovery of huge oil reserves on the layer known as Pre-Sal can positively transform in the socioeconomic context, the country. The impact of this huge quantity of natural resources it depends on the legislative policies adopted for the exploration and production (E & P) in the Pre-Salt layer, and the way in which laws are imposed for distribution of such resources. Therefore, it is made a shortly background of the laws from oil exploration, production and distribution, since the monopoly of Petrobras, to nowadays. To this end, an analysis is performed about the Oil Law, and about the possible legislative changes with the new Regulatory Framework. This monograph attempts to prove, based on historical data, socioeconomic facts, and international experiences, using either comparative statistical, that with the discovery in the Pre-Salt area, the best way to optimize the use of these resources, mainly the reduction of social inequality and economic contrasts, a legacy from colonization, would directly those recipes to a National Development Fund, the Social Fund, established by law for the new Regulatory Framework

Análise microestrutural de tubos API P110, para prospecção de petróleo e gás, soldados pelo processo HF/ERW

On the grounds of the great advances achieved over recent years, the process HF/ERW (High-Frequency/Electric Resistance Welding)welded pipe have played an active role in the oil and gas industry for deep water applications, at high and extremely low temperatures, under high pressure and in highly corrosive environments, gradually replacing manufactured pipes by other processes. However, studies have shown that defects in the welded joints are a the leading causes of pipelines failures, which has required the determination of toughness values in this region, in compliance with the strict recommendations of the codes and standards with manufacturers and construction companies, on the oil and gas sector. As part of the validation process required toughness values, this research project focuses on a microstructural analysis in HF / ERW tubes microalloyed, steel grade API 5CT P110, designed to explore oil and gas in deep waters, the subject of strategic relevance to the country because of the recent discoveries in the Santos mega fields: Tupi and Libra (pre-salt). In this scientific work will be presented and discussed the results of mechanical tensile and Charpy, a few CTOD tests curves (showing the trend of toughness values to be obtained), and the microstructures of the base material obtained by optical microscopy, with special emphasis on the formation of nonmetallic inclusions in the welded joint

Biodegradação de óleos derivados do petróleo e de origem vegetal estimulada por biossurfactantes em meio aquoso e monitoramento de sua toxicidade

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Determinação de metais em água produzida de petróleo

In order to enable the reuse of the large surplus volume of petroleum produced water for irrigation of crops inedible, the quality evaluation of this water is very important. This work aimed to evaluate the effectiveness of the diffusive gradient in thin films technique (DGT) for the determination of labile Cu (II), Mn (II) and Zn (II) in petroleum produced water destined to reuse in agriculture. Samples were collected at the exit of the wastewater treatment plant (WWTP) (after separation oil/water and flotation) of a Petrobrás onshore production region. Basically, the laboratory experiments with DGT devices involved the evaluation of the behavior of the main variables of the technique for determination of analytes in the samples (diffusion coefficients, immersion time, fractionation of organic and inorganic species, and performance of diffusion gels with different porosities, among others). Also, experiments were conducted based on the solid phase extraction (SPE) protocol with Chelex- 100 resin using previously established protocols to support the study. During the project the possibility of in situ immersions in water treatment plants was evaluated. The DGT technique presented satisfactory results for determination of Mn in produced water, and can be used for in situ determinations. However, the results obtained for Cu and Zn show the need of additional studies

Seleção de bactérias fenololíticas para tratamento de efluentes de refinarias de petróleo

Os efluentes de indústrias, como refinarias e petroquímicas, frequentemente contém elevadas concentrações de substâncias tóxicas, dentre elas, os compostos fenólicos. Estas substâncias, mesmo em pequenas quantidades, afetam as propriedades organolépticas da água, além de que durante o processo de cloração da água potável, podem ser transformadas em clorofenóis e policlorofenóis, pela reação com o cloro, formando substâncias com características carcinogênicas. Neste sentido, o refino do petróleo produz grande variedade de poluentes cujas propriedades modificam-se em função dos processos utilizados. Os fenóis são compostos tóxicos, com características fungicida e desinfetante, sendo tóxico para a maioria dos microrganismos, além de apresentarem ação de carcinogenicidade, mutagenicidade e serem recalcitrantes, acumulam-se nos corpos receptores, gerando danos à saúde e à vida aquática. No entanto, embora o fenol possua ação bactericida, alguns microrganismos adquiriram a habilidade de se adaptar e utilizar este composto como fonte de carbono e energia. O presente trabalho pretendeu selecionar linhagens bacterianas, a partir do efluente de uma refinaria de petróleo, da região de Paulínia – SP, que sejam capazes de utilizar altos teores de fenóis como fonte de carbono e energia para seu crescimento e desenvolvimento, a fim de serem aplicadas nas estações de tratamento de efluentes industriais, com foco nas refinarias de petróleo. Foram isoladas 3 linhagens a partir das amostras enriquecidas do efluente da refinaria e, após os ensaios, constatou-se que 1 linhagem apresentou resistência à concentração de fenol de 1.000 mg.L-1. Os ensaios de biodegradação e crescimento em fenol como única fonte de carbono, demonstraram que estas linhagens são capazes de biodegradar aproximadamente 20% do fenol disponível no meio, no período de 24 horas. A quantificação do fenol residual foi realizada em...

Avaliação do efeito do tratamento com surfactante químico e Pseudomonas aeruginosa LBI na toxicidade de solo contaminado com óleo lubrificante usado

Petroleum and its subproducts are considered a treat for the environmental quality because of the many environmental accidents that may occur during exploitation, transport and storage. A common remediation technique used in the contaminated areas is based on the use of surfactants, mainly the chemical ones, because they have low production costs. In the other hand, some microorganisms have indicate capacities of producing surfactants that emulsify substances and as result, offer a bigger contact surface for the microbiota degradation. This biossurfactants stand out in comparison with the chemical surfactants because they present lower micelar concentration values, are more tolerant for temperature and pH variation, because they are biodegradable, have low toxicity, higher emulsification and hydrocarbon solubilization index. In this way, after the surfactant application, a toxicity evaluation have to be made to identify the treatment effects. In soil, the activity of some microbial enzymes can show the environmental behavior of the contaminant under different treatment conditions. Dehydrogenase is one example of those enzymes that can demonstrate indirectly the effect of the pollutant on the soil microorganisms. The aim of this paper was to evaluate the toxicity after the addition of a surfactant and/or Pseudomonas aeruginosa LBI in soil contaminated by a mineral automotive lubricant. The previous mentioned bacteria are a potential biossurfactant (rhamnolipid) producer. In order to evaluate the toxicity, the dehydrogenase test was run. In this test, trifeniltetrazolium compound (TTC) after utilized as an electron acceptor, turns into trifenil formazan (TPF), that can be indirectly quantified using the absorbance measured by the spectrophotometer UV-visible. In this way, it was possible to quantify the dehydrogenase activity from the contaminated soil samples... (Complete abstract click electronic access below)

Variação histórica dos preços e das reservas de petróleo brasileiras e internacionais no período 1992-2011

The oil market is not a common market, and its complexity increases dramatically when considering the strategic and geopolitical involved, thus resulting in large uncertainties and concerns. The attempt to control prices has always been a challenge for the major world powers, since the increase in oil prices benefits the exporting countries, but harms importers, especially those regarded as less developed. Understand and try to predict some strategies adopted up the oil crises is one of the main points of the research, in order to demonstrate how economics can be used as an instrument of power and domination between nations, and how plans and strategies and rearrangements of supply and demand favor the growth of this economy, especially in the current period, with the new Brazilian oil era, beginning with the discovery of pre-salt, amid a context of growing need for the use of oil and its derivatives

Implicações federativas da emenda Ibsen Pinheiro

Since it was proposed, the Ibsen Pinheiro amendment has given rise to a huge debate in Brazilian society. This amendment proposes to share the revenue generated by royalties and special participations from offshore oil drilling between all municipalities and states, using for this the states and municipalities participation funds. This new distribution is a great rupture with the current model, which mandates that these resources should only be distributed to producing municipalities and states. Since the new proposal affects all offshore operations, and not only those in the new pre-salt areas, the producing municipalities and states would face an immediate loss of revenue in the scale of billions of reais. This study's objective is to analyze the validity of the criteria of redistribution of the government participations proposed by the Ibsen amendment. In this sense, we present the current Brazilian government participation model, focusing on the overfinancing of subnational spheres generated by this model, and compare it to a distribution simulation using the Ibsen amendment criteria. This comparison shows that the current beneficiaries would face a significant loss of revenue, and a distribution that favors the poorest regions of the country, consequence of the states and municipalities participation funds use. The study's last part discusses the various arguments in favor and against the amendment, especially those of constitutional character, most of which are contrary to the Ibsen amendment

Avaliação da toxicidade sobre Ceriodaphnia dubia das águas dos rios Atibaia, Jaguari e efluente tratado de refinaria de petróleo

Ensuring availability of quality water for human consumption causes becomes an increasing number of studies for the analysis of effluent before and after treatment, so that its release into receiving bodies do not cause significant changes in the river water and on the biological communities related to them. The biomarkers of toxicity have long been used to verify the potential toxic effluent and its correlation with the treatment efficiency of them. In this context, the cladoceran Ceriodaphnia dubia stands out because it is a benthic aquatic organism highly sensitive to environmental changes. In this study, to evaluate the interference of the release of treated wastewater of oil refinery in Rio Atibaia, we sought to determine the toxicity on population dynamics of Ceriodaphnia dubia microcrustacean in water samples upstream and downstream from the launch site, compared with samples from Rio Jaguarí at the point of capture by the company itself and treated effluent. We have studied the number of offspring produced in 10 replicates, each starting with a test individual of up to 24 hours for each sample and correlated the results with physical-chemical and microbiological tests performed by a laboratory technician. For most tests, the results indicate that the treated effluent gives sub-lethal toxicity to the microcrustacean, as delay the onset of the reproductive cycle of the same

Projeto de exploração de mercado e desenvolvimento de novos conceitos para segmento cosmético brasileiro: aplicação e avaliação de métodos de pesquisa

The current growth of the cosmetic Brazilian market and the incessant search for innovations requires the company´s Research & Development departments to be efficient and assertive. Therefore this work aimed to approach the process of development of new concepts, since the market exploration using quantitative tools, Survey, until the concept creation by qualitative tools. As results of this project an analysis of the tools and guidelines used nowadays and the creation of new exploration methods were delivered

Estudo da tecnologia e processos de extração em poços de petróleo

The analysis of the extraction process in oil wells is presented exploring the challenges to the effectiveness of the procedure is shown step by step in the process. There is an analysis of the major tools and equipment needed in the drilling process, promoting the understanding of the challenges in the pre-salt layers, compared to conventional processes. The work is reinforced through studies of the influence of the corrosive compared not corrosive environment in drill strings

Eficiência das resinas XAD4 e C18 na extração de compostos mutagênicos presentes em efluente de refinaria de petróleo para a realização do Teste de Ames

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Toxicidade de petróleo bruto sobre microcrustáceo Daphnia similis em água de rio e água de produção de petróleo

Aquatic ecosystems are suffering many impacts caused by human activities resulting from the activities occurring around them. With technological progress observed in recent years, this environment has received large amounts of chemicals from industries, agriculture and urban area that affect the aquatic biota. Among these sources of contamination, the oil industry has contributed to the pollution of aquatic environments with both effluents as produced water well as oil spills and their derivatives having toxicity to various organisms. With all the environmental issues has increased concern about water quality and has been used ecotoxicological tests with aquatic organisms to ecosystems to assess the toxicity of chemicals present in the water. In this context the microcrustacea Daphnia similis stands out as a freshwater organism very representative of the aquatic fauna of rivers and high sensitivity to environmental impacts. Thus, the present study aimed to evaluate the lethal toxicity of crude oil and produced water on this microcrustacea. The results showed that the microcrustacea presented high sensitivity to contaminants primarily crude oil. There was also the influence of environmental variables pH and temperature on the survival of organisms

XSOFT: estudo de reconhecimento, exploração e prevenção de vulnerabilidades de software através de uma distribuição LINUX

This work aims to give greater visibility to the issue of software security, due to people talk a lot in security conferences, that much of both IT (Information Technology) staff and, more specifically, IS (Information Security) staff does not know this, and, thanks to the spread of the mobile computing and of the cloud computing, this lack of deeper knowledge on this subject is increasingly becoming worrisome. It aims too, make applications to be developed in a security manner, priorizing the security of the information processed. It attempts to demonstrate the secure coding techniques, the principles of software security, the means to identify software vulnerabilities, the cutting-edge software exploitation techniques and the mechanisms of mitigation. Nowadays, the security guys are in charge of the most of the security tests in applications, audits and pentests, and it is undeniable that the so-called security experts, most often come from computer network field, having few experience in software development and programming. Therefore, the development process does not consider the security issue, thanks to the lack of knowledge on the subject by the developer, and the security tests could be improved whether security experts had a greater know-how on application development. Given this problem, the goal here is to integrate information security with software development, spreading out the process of secure software development. To achieve this, a Linux distribution with proof of concept applicati... (Complete abstract click electronic access below)