Secondary electron time detector for mass measurements at CSRe

The Isochronous Mass Spectrometry is a high accurate mass spectrometer. A secondary electrons time detector has been developed and used for mass measurements. Secondary electrons from a thin carbon foil are accelerated by ail electric field and deflected 180 degrees by a magnetic field onto a micro-channel plate. The time detector has been tested with alpha particles and a time resolution of 197 ps (FWHM) was obtained in the laboratory. A mass resolution around 8 x 10(-6) For Delta m/m was achieved by using this time detector in a pilot mass measurement experiment.

Drift distance survey in direct plasma injection scheme for high current beam production

In a laser ion source, plasma drift distance is one of the most important design parameters. Ion current density and beam pulse width are defined by plasma drift distance between a laser target and beam extraction position. In direct plasma injection scheme, which uses a laser ion source and a radio frequency quadrupole linac, we can apply relatively higher electric field at beam extraction due to the unique shape of a positively biased electrode. However, when we aim at very high current acceleration such as several tens of milliamperes, we observed mismatched beam extraction conditions. We tested three different ion current at ion extraction region by changing plasma drift distance to study better extraction condition. In this experiment, C6+ beam was accelerated. We confirmed that matching condition can be improved by controlling plasma drift distance.

利用HIRFL评估半导体器件单粒子效应敏感度的研究

用55MeV/u的~(40)Ar，离子对国内第一台专用的单粒子效应加速器模拟实验装置的注时探测器、能量探测器以及均匀度探测器进行了刻度。利用高能~(136)Xe离子获得了静态存储器IDT71256的单粒子翻转饱和截面和单粒子闭锁截面，在国内首次得到了该器件完整的G一LET曲线。并用改进的FONT方法预示了该器件以及其它常用宇航器件的在轨翻转率；用FOM公式、Barak经验公式和Lar叮模型推算这些器件的质子饱爪佩截而，少一仁对二种方法推算的结果进行了比较；探讨了利用HIRFL提供的高能~(12)C离子来模拟质子引起的单粒子效应的可能性；利用翻转截面与离子入射角度的关系估算了IDT71256敏感区的厚度以及聚酞亚胺膜的厚度，获得了截面与离子沉积能量的关系，临界沉积能量与临界LET值吻合，聚酞亚胺膜的厚度与对同类器件测量的结果一致；研究了离子入射角度对多位翻转的影响，在高LET值轰击下以及高能离子掠射的情况下，IDT71256多位翻转的比例可以高达70％，对于MBU敏感区中沉积的总能量及其分布范围是两个重要的参数；IDT71256单粒子翻转截面的角度效应主要是多位翻转的贡献；对实验中各种误差来源进行了分析。部分研究结果己经应用于星载七卜算机系统的抗辐射加固设计，建立的实验方法和理论模型为利用HIRFL开展宇航器件单粒子效应敏感度的评估奠定了坚实的基础。

Direct synthesis of Al-SBA-15 mesoporous materials via hydrolysis-controlled approach

Aluminum-substituted mesoporous SBA-15 (Al-SBA-15) materials were directly synthesized by a hydrolysis-controlled approach in which the hydrolysis of the silicon precursor (tetraethyl orthosilicate, TEOS) is accelerated by fluoride or by using tetramethyl orthosilicate (TMOS) as silicon precursor rather than TEOS. These materials were characterized by powder X-ray diffraction (XRD), N-2 sorption isotherms, TEM, Al-27 MAS NMR, IR spectra of pyridine adsorption, and NH3-TPD. It is found that the matched hydrolysis and condensation rates of silicon and aluminum precursors are important factors to achieve highly ordered mesoporous materials. Al-27 MAS NMR spectra of Al-SBA-15 show that all aluminum species were incorporated into the silica framework for the samples prepared with the addition of fluoride. A two-step approach (sol-gel reaction at low pH followed by crystallization at high pH) was also employed for the synthesis of Al-SBA-15. Studies show that the two-step approach could efficiently avoid the leaching of aluminum from the framework of the material. The calcined Al-SBA-15 materials show highly ordered hexagonal mesostructure and have both Bronsted and Lewis acid sites with medium acidity.

DNA diagnosis by capillary electrophoresis and microfabricated electrophoretic devices

DNA diagnosis is experiencing an impressive progression towards the development of novel technology to identity various clinically relevant categories of genetic changes and to meet the exponential growth of genomics. The introduction of capillary electrophoresis has dramatically accelerated the completion of the first draft of the human DNA sequence in the Human Genome Project, and thus, has become the method of choice for analysis of various genetic variants. The recent development of microfabricated electrophoretic devices has led to the possibility of integrating multiple sample handling with the actual measurement steps required for automation of molecular diagnostics. This review highlights the most recent progress in capillary electrophoresis and electrophoretic microdevices for DNA-based diagnostics, including the important areas of genotyping for point mutation, single nucleotide polymorphisms, short tandem repeats and organism identification. The application of these techniques for infectious and genetic disease diagnosis, as well as forensic identification purpose, are covered. The promising development and the challenges for techinical problems are also discussed.

Molecularly imprinted monolithic stationary phases for liquid chromatographic separation of enantiomers and diastereomers

The method for preparation of molecularly imprinted monolithic stationary phase has been improved to achieve liquid chromatographic separation of enantiomers and diastereomers. By adopting low polar porogenic solvents of toluene and dodecanol and optimal polymerization conditions, the molecularly imprinted monolithic stationary phases with good flow-through properties and high resolution were prepared. Enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were completely resolved using the monolithic stationary phases. The influence of porogenic composition, monomer-template ratio and polymerization conditions on the chromatographic performance was investigated. Some chromatographic conditions such as the composition of the mobile phase and the temperature were characterized. Scanning electron microscopy showed that the molecularly imprinted monolithic stationary phase has a large through-pore structure to allow the mobile phase to flow through the column at very low backpressure. Accelerated separations of enantiomers and diastereomers were therefore achieved at elevated flow rates. Finally, the chiral recognition performance of the prepared stationary phase in aqueous media was investigated. Hydrophobic interaction, and ionic and/or hydrogen bonding interactions were proposed to be responsible for the recognition mechanism. (C) 2002 Elsevier Science B.V. All rights reserved.

Climate change, sea level rise and integrated coastal zone management: An IPCC approach

Expansion of economic activities, urbanisation, increased resource use and population growth are continuously increasing the vulnerability of the coastal zone. This vulnerability is now further raised by the threat of climate change and accelerated sea level rise. The potentially severe impacts force policy-makers to also consider long-term planning for climate change and sea level rise. For reasons of efficiency and effectiveness this long-term planning should be integrated with existing short-term plans, thus creating an Integrated Coastal Zone Management programme. As a starting point for coastal zone management, the assessment of a country's or region's vulnerability to accelerated sea level rise is of utmost importance. The Intergovernmental Panel on Climate Change has developed a common methodology for this purpose. Studies carried out according to this Common Methodology have been compared and combined, from which general conclusions on local, regional and global vulnerability have been drawn, the latter in the form of a Global Vulnerability Assessment. In order to address the challenge of coping with climate change and accelerated sea level rise, it is essential to foresee the possible impacts, and to take precautionary action. Because of the long lead times needed for creating the required technical and institutional infrastructures, such action should be taken in the short term. Furthermore, it should be part of a broader coastal zone management and planning context. This will require a holistic view, shared by the different institutional levels that exist, along which different needs and interests should be balanced.

天山北麓中段土壤侵蚀影响因素及特征分析

通过对天山北麓中段土地类型、河流径流和植被覆盖等土壤侵蚀影响因素的空间分布特征分析认为 :1天山北麓中段主要侵蚀类型为风蚀、水蚀、冻融侵蚀及人为加速侵蚀 ;2侵蚀产沙类型以及产沙强度在空间上具有明显的垂直变化规律 :沙漠以风力侵蚀、高山和亚高山以冻融侵蚀为强烈侵蚀类型 ,普遍存在微度水力侵蚀 ,局部表现为中度甚至强度 ;3水蚀类型有冰川融雪径流侵蚀和降雨径流侵蚀两种方式。天山北麓中段河流产沙时间上主要在每年的 5月初至 8月末 ,且冰川雪水径流产沙要比雨水径流产沙量大 ,空间上则主要位于海拔 80 0～ 1 50 0 m的由第三纪、第四纪地层和黄土堆积所组成的中、低山丘陵地

论自然保护与资源开发的策略

The conservation of species requires preservation of natural habitats,where the integrity of natural habitats has been severely disturbed and species goes extinct. All natural habitats are continuing to decline both inside and outside of reserves. Habitat change is partly a natural process (e.g., succession), but human activities have accelerated the process so that natural rate of renewal is insufficient to maintain natural habitats. This paper provided concept, methods of habitat renewal, habitat mitigation and their implication to protection and exploitation of natural resource. We argue that our only resourse, in light of these scenarios, is to adopt a new conservation strategy that considers the importance of habitat renewal and habitat mitigation in addition to habitat preservation. Accordingly, in our management decision, we must not only choose the size of area to preserve ,but also the size of area to balance habitat loss with habitat renewal or habitat mitigation. Finally, we explored the application of habitat renewal and habitat mitigation in regional sustainable development of Liaohe Delta wetland.

开发西部切入点的研究──以黄土高原生态环境建设切入点为例

本本文以黄土高原为例，讨论了生态环境建设作为开发西部切入点的科学和实际意 义。从黄土高原毁林毁草耕垦和人为加速侵蚀的发展，剖析了退耕还林还草作为生态环境建 设切入点的科学依据。在此基础上，又进一步剖析了退耕还林还草的切入点及其实施对策。

黄土丘陵林区开垦地人为加速侵蚀与土壤物理力学性质的时间变化

以子午岭土壤侵蚀与生态环境演变观测站长年观测的径流泥沙资料为基础 ,分析了林地及其开垦地不同侵蚀年限土壤的颗粒组成、>0 .2 5 mm水稳性团粒含量、抗剪强度和容重等土壤物理力学性质与土壤侵蚀强度的关系。研究结果表明 ,>0 .2 5 mm水稳性团粒含量对土壤侵蚀强度影响最大 ,其偏相关系数为 0 .972 8,其次为土壤的粗粉粒含量和抗剪强度。最后对 >0 .2 5 mm水稳性团粒含量和抗剪强度与土壤侵蚀强度的关系进行了分析 ,表明林地开垦后侵蚀第 1年和第 7年为土壤侵蚀强度加剧的转折点 ,说明了森林植被在防治黄土高原土壤侵蚀方面的作用。

子午岭地区林地破坏加速侵蚀对土壤养分流失和微生物的影响研究

以浅沟集水区为研究对象,分析了子午岭地区林地被开垦破坏15年后裸露地在不同侵蚀强度和侵蚀方式下的土壤养分流失和土壤微生物数量的变化。结果表明,林地开垦破坏后,土壤侵蚀加剧发展,侵蚀强度达159.7t/(hm2.a),是林地土壤侵蚀量的上千倍。开垦破坏15年后,裸露地浅沟集水区不同地形部位表层土壤全氮、有机碳、速效磷和土壤微生物总数显著减少,同林地相比,依次分别减少37.9%~82.6%、42.7%~86.4%、24.2%~80.3%和31.8%9~2.0%。在裸露地浅沟集水区梁坡随坡长的增加,表层土壤有机碳、全氮和速效磷含量及微生物总数呈显著的下降趋势,且沟槽的土壤各养分含量及微生物总数明显低于沟间。裸露地浅沟集水区土壤养分流失强度及微生物数量减少幅度在浅沟集水区的空间分布与土壤侵蚀方式和侵蚀强度相对应。林地开垦破坏15年后,土壤养分以有机碳流失最严重,其次分别为速效磷、全氮;微生物中的真菌减少幅度最大,细菌次之,放线菌减少幅度最小。

大气效果实时绘制加速算法的研究

以地球为中心的空间环境仿真系统中，大气效果的实时绘制对于系统的视觉效果以及仿真结果的真实性都起到重要作用。大气散射是引起各种大气效果的主要原因，对其模拟是大气效果绘制的关键。目前，研究人员主要基于Nishita[1]所提出的基于真实物理的大气散射模型进行模拟，但是这个模型需要大量的积分运算，这对于实时仿真系统是不可接受。虽然也有一些加速算法，但是对于复杂的仿真系统来说，仍然是非常大的负担，使之很难应用于大型的仿真系统中。在本文中，基于Nishita[1]真实物理模型，提出了一种新的大气效果实时绘制加速算法：在分析其实现瓶颈以及现有加速算法不足的基础上，采用双重查询表机制降低了大量的重复计算，为物理模型的实时渲染提供基础；同时为提高渲染的效率，提出了基于视点的自适应多分辨率控制技术，使在复杂系统中基于物理散射模型实时渲染成为可能。实验结果显示，所提加速算法在保证绘制效果的前提下，渲染速度可显著提高。

New Organic Sensitizer for Stable Dye-Sensitized Solar Cells with Solvent-Free Ionic Liquid Electrolytes

We report a high molar extinction coefficient metal-free sensitizer composed of a triarylamine donor in combination with the 2-(2,2'-bithiophen-5-yl)acrylonitrile conjugation unit and cyanoacrylic acid as an acceptor. In conjugation with a volatile acetonitrile-based electrolyte or a solvent-free ionic liquid electrolyte, we have fabricated efficient dye-sensitized solar cells showing a corresponding 7.5% or 6.1% efficiency measured under the air mass 1.5 global sunlight. The ionic liquid cell exhibits excellent stability during a 1000 h accelerated test under the light-soaking and thermal dual stress. Intensity-modulated photocurrent and photovolatge spectroscopies were employed along with the transient photoelectrical decay measurements to detail the electron transport in the mesoporous titania films filled with these two electrolytes.

Electrospun palladium nanoparticle-loaded carbon nanofibers and their electrocatalytic activities towards hydrogen peroxide and NADH

Palladium nanoparticle-loaded carbon nanofibers (Pd/CNFs) were synthesized by the combination of electrospinning and thermal treatment processes. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that spherical Pd nanoparticles (NPs) are well-dispersed on the surfaces of CNFs or embedded in CNFs. X-ray diffraction (XRD) pattern indicates that cubic phase of Pd was formed during the reduction and carbonization processes, and the presence of Pd NPs promoted the graphitization of CNFs. This nanocomposite material exhibited high electric conductivity and accelerated the electron transfer, as verified by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV).