Rare element concentrations measured on filtered seawater of water bottle samples during POLARSTRERN cruise ANT-XXIV/3 (GIPY5)

The concentrations of rare earth elements (REEs) in seawater display systematic variations related to weathering inputs, particle scavenging and water mass histories. Here we investigate the REE concentrations of water column profiles in the Atlantic sector of the Southern Ocean, a key region of the global circulation and primary production. The data reveal a pronounced contrast between the vertical profiles in the Antarctic Circumpolar Current (ACC) and those to the south of the ACC in the Weddell Gyre (WG). The ACC profiles exhibit the typical increase of REE concentrations with water depth and a change in the shape of the profiles from near linear for the light REEs to more convex for the heavy REEs. In contrast, the WG profiles exhibit high REE concentrations throughout the water column with only the near surface samples showing slightly reduced concentrations indicative of particle scavenging. Seawater normalised REE patterns reveal the strong remineralisation signal in the ACC with the light REEs preferentially removed in surface waters and the mirror image pattern of their preferential release in deep waters. In the WG the patterns are relatively homogenous reflecting the prevalence of well-mixed Lower Circumpolar Deep Water (LCDW) that follows shoaling isopycnals in the region. In the WG particle scavenging of REEs is comparatively small and limited to the summer months by light limitation and winter sea ice cover. Considering the surface water depletion compared to LCDW and that the surface waters of the WG are replaced every few years, the removal rate is estimated to be on the order of 1 nmol/m3/yr for La and Nd. The negative cerium anomalies observed in deep waters are some of the strongest found globally with only the deepest waters in parts of the Pacific having stronger anomalies. These deep waters have been isolated from fresh continental REE inputs during their long journey through the abyssal Indo-Pacific ocean and suggests that the high REE concentrations found in the ACC and WG reflect contributions from old deep waters.

Physical water column observations during summer breeze winds

During summer seasons (from 2012 to 2015) high resolution observation were performed in the Civitavecchia coastal area (Northern Tyrrhenian sea, west coast). All sampling was carried out from a small boat (5m rigid inflatable) starting in the early morning typically around 06:00 a.m. , and lasting from 2 to 8 h, depending on the weather conditions. The purposes of the experiment was to observe the variations of both the coastal circulation and the water column in response to rotation of 180 ° in the wind direction. During surveys both current measurements and yo-yo time series were performed. Current data were acquired using an ADCP SonTeck (500 Khz, sampling interval from 20sec to 60 sec, average interval 50% sampling, cell thickness 1 meter) and the yo-yo time series employing a small instrument package (CTD). The CTD contained an Idronaut 316 Plus and a SeaPoint fluorometer. The sampling rate for the CTD was 10Hz, profiling with the CTD was done by allowing the instrument package to free-fall, at an average descent rate of 1 m/s. During the summer 2012, the sampling plan consisted in four stations spaced a quarter of a mile (St. 1 - 10 m; St. 2 - 20 m; St. 3 - 30 m; and St. 4 - 40 m), in which yo-yo time series were performed with an interval of 20 min. In order to study fluorescence of Chlorophyll a pathes distribution in coastal zone. Breeze induced circulation was the goal of the following summers surveys, in these current measurements and yo-yo time series were performed moored at a depth of 40 m. Offshore station (St. 1 -40m) has been chosen to perform measurement, basis of previously observations (2012 sampling surveys). It was decided as wind driven circulation and mixing phenomena are less influenced by seabed than the other stations. Acquired data have been processed by NEMO SeaDataNet software.