Resonant States in Negative Ions

Resonant states are multiply excited states in atoms and ions that have enough energy to decay by emitting an electron. The ability to emit an electron and the strong electron correlation (which is extra strong in negative ions) makes these states both interesting and challenging from a theoretical point of view. The main contribution in this thesis is a method, which combines the use of B splines and complex rotation, to solve the three-electron Schrödinger equation treating all three electrons equally. It is used to calculate doubly excited and triply excited states of 4S symmetry with even parity in He-. For the doubly excited states there are experimental and theoretical data to compare with. For the triply excited states there is only theoretical data available and only for one of the resonances. The agreement is in general good. For the triply excited state there is a significant and interesting difference in the width between our calculation and another method. A cause for this deviation is suggested. The method is also used to find a resonant state of 4S symmetry with odd parity in H2-. This state, in this extremely negative system, has been predicted by two earlier calculations but is highly controversial. Several other studies presented here focus on two-electron systems. In one, the effect of the splitting of the degenerate H(n=2) thresholds in H-, on the resonant states converging to this threshold, is studied. If a completely degenerate threshold is assumed an infinite series of states is expected to converge to the threshold. Here states of 1P symmetry and odd parity are examined, and it is found that the relativistic and radiative splitting of the threshold causes the series to end after only three resonant states. Since the independent particle model completely fails for doubly excited states, several schemes of alternative quantum numbers have been suggested. We investigate the so called DESB (Doubly Excited Symmetry Basis) quantum numbers in several calculations. For the doubly excited states of He- mentioned above we investigate one resonance and find that it cannot be assigned DESB quantum numbers unambiguously. We also investigate these quantum numbers for states of 1S even parity in He. We find two types of mixing of DESB states in the doubly excited states calculated. We also show that the amount of mixing of DESB quantum numbers can be inferred from the value of the cosine of the inter-electronic angle. In a study on Li- the calculated cosine values are used to identify doubly excited states measured in a photodetachment experiment. In particular a resonant state that violates a propensity rule is found.

Proceedings of the Physical Society.

Issues for Nov.-Dec. 1961 issued in 2 pts. each.

Optimal measurements for relative quantum information

We provide optimal measurement schemes for estimating relative parameters of the quantum state of a pair of spin systems. We prove that the optimal measurements are joint measurements on the pair of systems, meaning that they cannot be achieved by local operations and classical communication. We also demonstrate that in the limit where one of the spins becomes macroscopic, our results reproduce those that are obtained by treating that spin as a classical reference direction.

Experimental characterization of continuous-variable entanglement

We present an experimental analysis of quadrature entanglement produced from a pair of amplitude squeezed beams. The correlation matrix of the state is characterized within a set of reasonable assumptions, and the strength of the entanglement is gauged using measures of the degree of inseparability and the degree of Einstein-Podolsky-Rosen (EPR) paradox. We introduce controlled decoherence in the form of optical loss to the entangled state, and demonstrate qualitative differences in the response of the degrees of inseparability and EPR paradox to this loss. The entanglement is represented on a photon number diagram that provides an intuitive and physically relevant description of the state. We calculate efficacy contours for several quantum information protocols on this diagram, and use them to predict the effectiveness of our entanglement in those protocols.

Fungible dynamics: There are only two types of entangling multiple-qubit interactions

What interactions are sufficient to simulate arbitrary quantum dynamics in a composite quantum system? It has been shown that all two-body Hamiltonian evolutions can be simulated using any fixed two-body entangling n-qubit Hamiltonian and fast local unitaries. By entangling we mean that every qubit is coupled to every other qubit, if not directly, then indirectly via intermediate qubits. We extend this study to the case where interactions may involve more than two qubits at a time. We find necessary and sufficient conditions for an arbitrary n-qubit Hamiltonian to be dynamically universal, that is, able to simulate any other Hamiltonian acting on n qubits, possibly in an inefficient manner. We prove that an entangling Hamiltonian is dynamically universal if and only if it contains at least one coupling term involving an even number of interacting qubits. For odd entangling Hamiltonians, i.e., Hamiltonians with couplings that involve only an odd number of qubits, we prove that dynamic universality is possible on an encoded set of n-1 logical qubits. We further prove that an odd entangling Hamiltonian can simulate any other odd Hamiltonian and classify the algebras that such Hamiltonians generate. Thus, our results show that up to local unitary operations, there are only two fundamentally different types of entangling Hamiltonian on n qubits. We also demonstrate that, provided the number of qubits directly coupled by the Hamiltonian is bounded above by a constant, our techniques can be made efficient.

Simulating quantum interference in a three-level system with perpendicular transition dipole moments

We consider a three-level V-type atomic system with the ground state coupled by a laser field to only one of the excited states, and with the two excited states coupled together by a dc field. Although the dipole moments of the two dipole-allowed transitions are assumed perpendicular, we demonstrate that this system emulates to a large degree a three-level system with parallel dipole moments-the latter being a system that exhibits quantum interference and displays a number of interesting features. As examples, we show that the system can produce extremely large values for the intensity-intensity correlation function, and that its resonance fluorescence spectrum can display ultranarrow lines. The dressed states for this system are identified, and the spectral features are interpreted in terms of transitions among these dressed states. We also show that this system is capable of exhibiting considerable squeezing.

Optimal cloning for finite distributions of coherent states

We derive optimal cloning limits for finite Gaussian distributions of coherent states and describe techniques for achieving them. We discuss the relation of these limits to state estimation and the no-cloning limit in teleportation. A qualitatively different cloning limit is derived for a single-quadrature Gaussian quantum cloner.

Scaling of multiple postselected quantum gates in optics

We show that interesting multigate circuits can be constructed using a postselected controlled-sign gate that works with a probability (1/3)(n), where n-1 is the number of controlled-sign gates in the circuit, rather than (1/9)(n-1), as would be expected from a sequence of such gates. We suggest some quantum information tasks which could be demonstrated using these circuits, such as parity checking and cluster-state computation.

Analysis of dynamical tunneling experiments with a Bose-Einstein condensate

Dynamical tunneling is a quantum phenomenon where a classically forbidden process occurs that is prohibited not by energy but by another constant of motion. The phenomenon of dynamical tunneling has been recently observed in a sodium Bose-Einstein condensate. We present a detailed analysis of these experiments using numerical solutions of the three-dimensional Gross-Pitaevskii equation and the corresponding Floquet theory. We explore the parameter dependency of the tunneling oscillations and we move the quantum system towards the classical limit in the experimentally accessible regime.

Transmission of optical coherent-state qubits

We discuss the long-distance transmission of qubits encoded in optical coherent states. Through absorption, these qubits suffer from two main types of errors, namely the reduction of the amplitude of the coherent states and accidental application of the Pauli Z operator. We show how these errors can be fixed using techniques of teleportation and error-correcting codes.

Fock-state dynamics in Raman photoassociation of Bose-Einstein condensates

By stochastic modeling of the process of Raman photoassociation of Bose-Einstein condensates, we show that, the farther the initial quantum state is from a coherent state, the farther the one-dimensional predictions are from those of the commonly used zero-dimensional approach. We compare the dynamics of condensates, initially in different quantum states, finding that, even when the quantum prediction for an initial coherent state is relatively close to the Gross-Pitaevskii prediction, an initial Fock state gives qualitatively different predictions. We also show that this difference is not present in a single-mode type of model, but that the quantum statistics assume a more important role as the dimensionality of the model is increased. This contrasting behavior in different dimensions, well known with critical phenomena in statistical mechanics, makes itself plainly visible here in a mesoscopic system and is a strong demonstration of the need to consider physically realistic models of interacting condensates.

Continuous-variable Einstein-Podolsky-Rosen paradox with traveling-wave second-harmonic generation

The Einstein-Podolsky-Rosen paradox and quantum entanglement are at the heart of quantum mechanics. Here we show that single-pass traveling-wave second-harmonic generation can be used to demonstrate both entanglement and the paradox with continuous variables that are analogous to the position and momentum of the original proposal.

Resources required for exact remote state preparation

It has been shown [M.-Y. Ye, Y.-S. Zhang, and G.-C. Guo, Phys. Rev. A. 69, 022310 (2004)] that it is possible to perform exactly faithful remote state preparation using finite classical communication and any entangled state with maximal Schmidt number. Here we give an explicit procedure for performing this remote state preparation. We show that the classical communication required for this scheme is close to optimal for remote state preparation schemes of this type. In addition we prove that it is necessary that the resource state have maximal Schmidt number.

Generation of macroscopic superposition states with small nonlinearity

We suggest a scheme to generate a macroscopic superposition state (Schrodinger cat state) of a free-propagating optical field using a beam splitter, homodyne measurement, and a very small Kerr nonlinear effect. Our scheme makes it possible to reduce considerably the required nonlinear effect to generate an optical cat state using simple and efficient optical elements.

Energy as an entanglement witness for quantum many-body systems

We investigate quantum many-body systems where all low-energy states are entangled. As a tool for quantifying such systems, we introduce the concept of the entanglement gap, which is the difference in energy between the ground-state energy and the minimum energy that a separable (unentangled) state may attain. If the energy of the system lies within the entanglement gap, the state of the system is guaranteed to be entangled. We find Hamiltonians that have the largest possible entanglement gap; for a system consisting of two interacting spin-1/2 subsystems, the Heisenberg antiferromagnet is one such example. We also introduce a related concept, the entanglement-gap temperature: the temperature below which the thermal state is certainly entangled, as witnessed by its energy. We give an example of a bipartite Hamiltonian with an arbitrarily high entanglement-gap temperature for fixed total energy range. For bipartite spin lattices we prove a theorem demonstrating that the entanglement gap necessarily decreases as the coordination number is increased. We investigate frustrated lattices and quantum phase transitions as physical phenomena that affect the entanglement gap.