Herbicidas mais empregados no cultivo de cana-de-açúcar no município de Araraquara (SP): desenvolvimento e validação de método de quantificação e avaliação do potencial de lixiviação em solos argiloso e arenoso (área de recarga do Sistema Aquífero Guarani)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Adsorção de íons metálicos em meio aquoso, etanólico e cetônico utilizando silsesquioxanos organofuncionalizados

Pós-graduação em Ciência dos Materiais - FEIS

Translocação dos herbicidas glyphosate e imazamox em plantas de aguapé

Eichhornia crassipes is one of the main weeds found in aquatic environments, being undesirable for many activities. The aim of this study was to evaluate the translocation of glyphosate and imazamox in E. crassipes. Eight intervals were studied for cutting leaves that received herbicides: 2, 4, 6, 8, 12 and 24 hours after application (HAA), and a treatment with no cutting (untreated). The glyphosate dose was 2,160 g a.e. ha-1 (commercial product - Rodeo) + 0.5% v v-1 Aterbane adhesive spreader and imazamox at 290.4 g i.a. ha-1 (commercial product - Clearcast). The treatments were installed in a completely randomized design with four replications. Glyphosate showed a bad control for all the periods of leaf cutting. The imazamox did not provide control within 12 HAA, while from 24 HAA onward the control was effective. There was not a great mobility of the glyphosate molecule in water hyacinth plants, a period above 24 hours being needed for a satisfactory translocation. For imazamox at least 24 hours were needed after herbicide application for the translocation to occur along with subsequent control.

Evolução de CO2 e atividades enzimáticas em amostras de solo tratado com herbicidas

Effects of bentazon, metolachlor, trifluralin, imazethapyr, imazethapyr+lactofen, haloxyfop-methyl, glyphosate and chlorimuron-ethyl at rates of 2 and 10 times the equivalent commercial dose on soil microbial activity was evaluated in soil samples extracted from a field never treated before. Global soil microbe respiration, estimated by CO2 production at 2, 4, 8, 12, 16, 20, 24 and 28 days of soil incubation and enzymatic activities (dehydrogenase and fluorescein diacetate hydrolysis) at 8 and 28 days were used as bioindicators. Bentazon and mixture imazethapyr+lactofen at the highest rate and haloxyfop-methyl at both rates, inhibited soil respiration although with differences in timing and duration. None of the herbicides affected FDA hydrolysis. Dehydrogenase activity was inhibited at 8 days of incubation with bentazon and imazethapyr at high rates but it was stimulated by metolachlor and imazethapyr at low rate and glyphosate at the highest rate. Herbicide effects on soil microbial activity was detected with higher sensitivity by global soil microbe respiration and dehydrogenase activity than by FDA hydrolysis. Only dehydrogenase activity and soil respiration estimations at 8 days of soil incubation had significant correlation. Results indicated the need of multiple estimations when evaluating herbicides effects on soil microbiota

Adubação nitrogenada e aplicação de herbicidas como reguladores de crescimento em grama esmeralda

Pós-graduação em Agronomia - FEIS

Imobilização de lipases por adsorção e ligação covalente em derivados de agarose e quitosana e sua aplicação em biocatálise

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Avaliação sobre o comportamento de antimicrobianos veterinários em solo e em cama de frango: estudos de adsorção e previsão do potencial de contaminação de águas superficiais e subterrâneas

Pós-graduação em Química - IQ

Hormesis de herbicidas em soja

Pós-graduação em Agronomia (Agricultura) - FCA

Teores foliares de macro e micronutrientes em milho tolerante ao glyphosate submetido à herbicidas

A serial of factors related to development of glyphosate-tolerant corn should be approached and best studied. This work was developed to evaluate foliar levels of N, P, K, Ca, Mg, S, B, Cu, Fe, Mn and Zn, besides the grain yield of glyphosate-tolerant corn (DKB390 RR hybrid). An experiment was carried out under field conditions, during the crop year of 2010/2011. A randomized complete block design with four repetitions was used to distribute the treatments in the field. Twelve herbicide treatments were studied: glyphosate (720, 1200 and sequential application of 960 plus 720 g ha(-1) of the acid glyphosate equivalent), atrazine (2500 g ha(-1)), nicosulfuron (60 g ha(-1)), mesotrione (192 g ha(-1)), tembotrione (100,8 g ha(-1)), atrazine plus glyphosate (1000 + 960 g ha(-1)), atrazine plus nicosulfuron (1000 + 20 g ha(-1)), atrazine plus mesotrione (1000 + 144 g ha(-1)) and atrazine plus tembotrione (1000 + 75,6 g ha(-1)) and one control treatment without herbicide. The glyphosate and mesotrione alone did not cause no visible injury to corn. The other herbicides caused intoxication symptoms classified as light (<5%). The treatments studied did not affect foliar levels of N, P, K, Ca, Mg, S, B, Mn and Zn in the corn plants. But, the plants treated with atrazine plus nicosulfuron had more leaf Fe content, and the plants sprayed with glyphosate (in the three doses) and atrazine, more accumulation of Cu in the leaf. The Grain yield of corn was reduced with application single of glyphosate (1200 g ha(-1)), nicosulfuron, tembotrione and with the mixture atrazine plus nicosulfuron.

Eficiência de herbicidas no controle de plantas daninhas latifoliadas em mamona

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Seletividade de herbicidas na cultura de crambe

The low productivity of crambe can be associated with many factors, among these, the competition with weeds, which reduces the yield, harvest affects and contributes to the increase in seed moisture. Therefore, this study aimed to evaluate the tolerance of crambe plants cv. FMS Brilhante to herbicides applied in preplant incorporated (PPI), preemergence (PRE), and postemergence (POST). The study was installed in a green-house and the treatments consisted of the herbicide application in: pre-plant incorporated ofdiclosulam, flumetsulam, metribuzin, and trifluralin; preemergence applicationof atrazine, diclosulam, diuron, flumetsulam, metribuzim, S-metolachlor, sulfentrazone, and trifluralin; and postemergence application ofbentazon, carfentrazone-ethyl, clefoxydim, cletodim + fenoxaprop-p-ethyl, ethoxysulfuron, fomesafen, fluazifop-p-butyl, flumioxazin, halosulfuron, imazamox, imazapic, lactofen, nicosulfuron, oxadiazon, quinclorac, and setoxydim. Visual evaluations of phytotoxicity on crambe plants were realized after applications, the seedlings were counted and the height and plant dry matter were determined in the end of the evaluation period. In conditions where the studies were conducted, we can conclude that only the trifluralin application in PRE and the application of clefoxidim+fenoxaprop-p-ethyl, fluazifop-p-butyl, quinclorac, setoxydim and clefoxydim in POST showed selectivity and potential use for FMS Brilhante crambe cultivar.

Adsorção do corante luganil azul por espuma de poliuretano

The industrial development has created many environmental problems that can be observed through the changes in air, soil and water. The pollution of water bodies with compounds present in textile effluents cause beyond the visual pollution, changes in biological cycles, mainly by changing the process of photosynthesis. Due to these environmental implications it is necessary a treatment of livestock manure. The process of adsorption of the dye is a technique that has been successfully employed for effective removal of the color of the effluent. The purpose of this study was to investigate the application of a polyurethane foam plant of castor oil as an alternative adsorbent for removal of dyes in textile effluents. The study was conducted with the dye “luganil azul”, as adsorbent and the foam in a flexible manner and sprayed. It also investigated the influence of pH on the adsorption dye. The kinetic data were obtained, noting that the pH influence on adsorption. Adsorption isotherms of the dye in aqueous solution using the foam in a flexible manner also were determined experimentally.

Estudo da adsorção e oxidação do monóxido de carbono sobre as fases intermetálicas ordenadas AuIn, AuSb2, AuSn, PdSb e PdSn

Aiming to reduce the cost of electrocatalysts and a greater resistance to CO poisoning this work was to study the adsorption and oxidation of carbon monoxide on ordered intermetallic phases AuIn, AuSb2, AuSn, PdSb and PdSn using voltammetric techniques in alkaline electrolyte solution. The results suggest that the AuSn and PdSn intermetallics has some form of resistance to CO poisoning. It is assumed that this behavior is a result of electronic effect and the effect of the third body has been achieved by adding a second metal to Au and Pd. However, further studies should be conducted to confirm this hypothesis as to test these materials as electrocatalysts in the reaction of oxidation of fuels

Seletividade de herbicidas em mudas pré-brotadas de cana-de-açúcar

Pós-graduação em Agronomia (Produção Vegetal) - FCAV

Preparo e caracterização de nanopartículas lipídicas sólidas como sistema carreador conjunto para os herbicidas atrazina e simazina visando futuras aplicações em agricultura

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)