Kinetics and Adsorption Isotherms of Bisphenol A, Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol in Tropical Sediment Samples

The sorption of four endocrine disruptors, bisphenol A (BPA), estrone (E1), 17 beta-estradiol (E2), and 17 alpha-ethinylestradiol (EE2) in tropical sediment samples was studied in batch mode under different conditions of pH, time, and sediment amount. Data obtained from sorption experiments using the endocrine disruptors (EDs) and sediments containing different amounts of organic matter showed that there was a greater interaction between the EDs and organic matter (OM) present in the sediment, particularly at lower pH values. The pseudosecond order kinetics model successfully explained the interaction between the EDs and the sediment samples. The theoretical and experimentally obtained q (e) values were similar, and k values were smaller for higher SOM contents. The k (F) values, obtained from the Freundlich isotherms, varied in the ranges 4.2-7.4 x 10(-2) (higher OM sediment sample, S(2)) and 1.7 x 10(-3)-3.1 x 10(-2) (lower OM sediment sample, S(1)), the latter case indicating an interaction with the sediment that increased in the order: EE2 > > E2 > E1 > BPA. These results demonstrate that the availability of endocrine disruptors may be directly related to the presence of organic material in sediment samples. Studies of this kind provide an important means of understanding the mobility, transport, and/or reactivity of this type of emergent contaminant in aquatic systems.

Ambient Air Quality Monitoring in Metropolitan City of Lagos, Nigeria

Twenty one sampling locations were assessed for carbon monoxide (CO), carbondioxide (CO2), oxygen (O2), sulphur dioxide (SO2), nitrogen dioxide (NO2), nitrogen oxide (NO), suspended particulate matter (SPM) and noise level using air pollutants measurement methods approved by ASTM for each specific parameter. All equipments and meters were all properly pre-calibrated before each usage for quality assurance. Findings of the study showed that measured levels of noise (61.4 - 101.4 dBA), NO (0.0 - 3.0 ppm), NO2 (0.0 - 3.0 ppm), CO (1.0 – 42.0 ppm) and SPM (0.14 – 4.82 ppm) in all sampling areas were quite high and above regulatory limits however there was no significant difference except in SPM (at all the sampling points), and noise, NO2 and NO (only in major traffic intersection). Air quality index (AQI) indicates that the ambient air can be described as poor for SPM, varied from good to very poor for CO, while NO and NO2 are very good except at major traffic intersection where they were both poor and very poor (D-E). The results suggest that strict and appropriate vehicle emission management, industrial air pollution control coupled with close burning management of wastes should be considered in the study area to reduce the risks associated with these pollutants.

Chemical changes and heavy metal partitioning in an oxisol cultivated with maize (Zea mays, L.) after 5 years disposal of a domestic and an industrial sewage sludge.

The need for solutions to minimize the negative environmental impacts of anthropogenic activities Fhas increased. Sewage sludge is composed of predominantly organic matter and can be used to improve soil characteristics, such as fertility. Therefore, its application in agriculture is an adequate alternative for its final disposal. However, there is a lack of information on its long-term effects on soil changes in tropical areas. Thus, the objectives of this study were to determine (i) the effect of sewage sludge application on heavy metal build-up in soil and maize grains and leaves, and (ii) the effects of soil amendment with sewage sludge on the chemical properties of a Brazilian oxisol. Besides the increasing levels of Zn, Cu, Ni, and Cr, amending soil with sewage sludge also alters the distribution of these metals by increasing the mobile Phases, which correlated significantly with the increase in metal extraction with two single extractants, Mehlich 1 and DTPA (Diethylene triamine pentaacetic acid). The levels of Fe, Mn, Zn, and Cu in maize grains and leaves increased with the type and rate of sewage sludge application. Nevertheless, metal build-up in soil and plants was within the allowed limits. Significant differences were also found in soil characteristics like humic fractionation with the applied sewage doses. The data obtained does not indicate any expressive drawbacks in the use of sewage sludge as a soil amendment, as the heavy metal concentrations observed are unlikely to cause any environmental or health problems, even overestimated loadings, and are in accordance with the Brazilian regulations on farming land biosolid disposal.

The Amplifier - v. 15, no. 9

In this issue...Theta Tau, Continental Oil Company, International Club, Independent Party, Coed Housing, Pollution Control, KXLF TV, Athletic Department, Physical Education

Incidencia del proyecto “ASEAN community” en el desarrollo humano de Tailandia (2004-2014)

Esta investigación se interesa en evaluar los logros y retos que ha presentado el proyecto ASEAN Community en cada una de sus tres áreas de acción (Comunidad económica, comunidad de política y seguridad, y comunidad socio-cultural) ante su aplicación en Tailandia. De esta manera, se busca analizar la incidencia que ha tenido el proyecto en el Desarrollo Humano de Tailandia durante el periodo 2004-2014. A través del análisis del estatus actual a la luz del concepto de libertades instrumentales se realiza la evaluación de los resultados de los proyectos y su conveniencia o no para el desarrollo humano de la sociedad tailandesa.

La influencia de los objetivos del milenio del PNUD en la implementación de políticas publicas ambientales en Tailandia para el periodo del 2000 al 2013

La presente investigación tiene como objetivo principal, explicar la influencia de los ODM del PNUD en la implementación de políticas públicas medioambientales de Tailandia en el periodo del 2000 al 2013, basado en la teoría de los complejos de socialización y la transferencia de normas que implican un buen comportamiento medioambiental. De esta manera, demostrar que los agentes socializadores han cumplido un papel fundamental para la implementación de políticas públicas en Tailandia en su interés por cumplir con sus compromisos internacionales. Esta monografía utilizara un método cualitativo, desde el análisis de las fuentes primarias y secundarias, realizando especial énfasis en la teoría de complejos de socialización que permita un análisis descriptivo y explicativo del fenómeno.

La influencia de los objetivos del milenio del PNUD en la implementación de políticas públicas ambientales en Tailandia para el periodo del 2000 al 2013

La presente investigación tiene como objetivo principal, explicar la influencia de los ODM del PNUD en la implementación de políticas públicas medioambientales de Tailandia en el periodo del 2000 al 2013, basado en la teoría de los complejos de socialización y la transferencia de normas que implican un buen comportamiento medioambiental. De esta manera, demostrar que los agentes socializadores han cumplido un papel fundamental para la implementación de políticas públicas en Tailandia en su interés por cumplir con sus compromisos internacionales. Esta monografía utilizara un método cualitativo, desde el análisis de las fuentes primarias y secundarias, realizando especial énfasis en la teoría de complejos de socialización que permita un análisis descriptivo y explicativo del fenómeno.

O papel da agricultura de conservação na luta contra a erosão do solo em particular em Angola

A agricultura de conservação, conseguindo reduzir as perdas de solo por erosão e aumentando o seu teor em matéria orgânica, permite aos agricultores produzirem mais alimentos com menos trabalho. Oferece-lhes uma possibilidade de melhorar a sua qualidade de vida. Várias abordagens sobre agricultura de conservação do solo, incluindo rotação e consorciação de culturas, são componentes deste sistema aplicável a diferentes níveis. A sementeira direta e o menor distúrbio de solo, são princípios primordiais da conservação do solo, fornecem benefícios direitos para a agricultura e o meio ambiente, questões da maior relevância para a agricultura Angolana, apesar da pouca importância que atualmente lhes é dedicada. Logo, é preciso uma conversão e transição de tecnologias e técnicas para implementar a agricultura de conservação e o controle da erosão dos solos no país. As técnicas de conservação utilizadas pelos pequenos e grandes produtores, embora sejam bem-intencionadas, não oferecem a proteção contra a erosão do solo e a conservação da água. Tanto as entidades políticas, como o Programa de Acão do Ministério da Agricultura e do Desenvolvimento Rural (MINADER) e os agricultores angolanos devem entender a importância da agricultura de conservação para a segurança alimentar e dar continuidade para as gerações futuras. Não basta a reformulação e consolidação dos objetivos traçados no período de 2009 a 2013, sem que haja a aplicação prática. Portanto, para sair do atual conceito oficial de agricultura tradicional/convencional e optar para agricultura capaz de responder às necessidades de Angola é necessário seguir modelos semelhantes aos desenvolvidos por países tropicais de condições naturais semelhantes às de Angola; The role of conservation agriculture in the fight against soil erosion particularly in Angola ABSTRACT: Conservation agriculture, managed to reduce soil losses by erosion and to increase its content of organic matter, allow farmers to produce more food with less work. It offers them a chance to improve their quality of life. Several approaches to soil conservation agriculture, including rotation and intercropping, are components of this system applicable to different levels. Direct sowing and less soil disturbance, are key principles of soil conservation providiy benefits for agriculture and the environment, issues of great importance for the Angolan agriculture, in spite of the little importance that is currently dedicated to them. Therefore, we need a conversion and transition technologies and techniques to implement conservation agriculture and soil erosion control in the country. Conservation techniques used by small and large producers, although well-intentioned, do not offer protection against soil erosion and water conservation. Both political entities, such as the Program of Action of the Ministry of Agriculture and Rural Development (MINADER) and Angolan farmers should understand the importance of conservation agriculture for food security and continuity for future generations. Not just the redesign and consolidation of the objectives outlined in the period 2009 to 2013, without practical application. Therefore, to exit the current official concept of traditional / conventional farming and opt for agriculture able to meet the needs of Angola is necessary to follow models similar to those developed by tropical countries of natural conditions similar to Angola.

Assessment of heavy metals in soils of a vineyard region with the use of principal component analysis.

Agricultural management with chemicals may contaminate the soil with heavy metals. The objective of this study was to apply Principal Component Analysis and geoprocessing techniques to identify the origin of the metals Cu, Fe, Mn, Zn, Ni, Pb, Cr and Cd as potential contaminants of agricultural soils. The study was developed in an area of vineyard cultivation in the State of São Paulo, Brazil. Soil samples were collected and GPS located under different uses and coverings. The metal concentrations in the soils were determined using the DTPA method. The Cu and Zn content was considered high in most of the samples, and was larger in the areas cultivated with vineyards that had been under the application of fungicides for several decades. The concentrations of Cu and Zn were correlated. The geoprocessing techniques and the Principal Component Analysis confirmed the enrichment of the soil with Cu and Zn because of the use and management of the vineyards with chemicals in the preceding decades.

Groundwater vulnerability and protection in County Tipperary (South Riding), Ireland

The aim of the project was to determine the extent and quality of the groundwater in Tipperary South Riding with a view to developing a groundwater protection plan which would allow the Local Authority to manage, protect and develop the groundwater as efficiently as possible. The geology of the area varies with topography. The low-lying areas of the county comprise mainly Carboniferous limestones while the elevated regions consist of sandstones and shales of Upper Carboniferous, Devonian and Silurian ages. Deformation of these rocks decreases in magnitude moving northwards over the area; the Southern Synclines having suffered the effects of the Hercynian orogeny and the northern region exhibiting Caledonian orogenic trends. Quaternary (subsoil) deposits are found throughout the area and are of variable thickness and permeability. Till is the most widespread deposit with discontinuous pockets of sand and gravel in various proportions, and some marl, alluvium and peat in places. The principal aquifers of the area are the Kiltorcan sandstone formation and various limestone units within the Carboniferous succession. 50 % of south Tipperary constitutes either regionally or locally important aquifers. Secondary permeabilities created by structural deformation, dolomitisation, karstification and weathering processes create high transmissivities and often have large well yields. Specific baseflow analysis highlighted the complexity of the aquifers and proved that the lower part of the Suir river system is a major groundwater resource region. The hydrochemistry and water quality of the local authority groundwater sources was examined briefly. The majority of south Tipperary is underlain by limestone or Quaternary deposits derived from limestone and, consequently, calcium/magnesium bicarbonate waters predominate. The quality of the groundwater in south Tipperary demonstrates that the main concern originates from the presence of E.coli, and Total coliforms. The primary sources of contamination are from farmyard wastes and septic tanks. The vulnerability of groundwater to diffuse and point sources of pollution has been found to be dependent on the overlying soil, subsoil and the thickness of the unsaturated zone. A conceptual rather than quantitative approach is used and it is found that approximately 60% of south Tipperary is designated as being extremely or highly vulnerable. The groundwater protection plan was devised subsequent to an understanding of the aquifer systems, an assessment of the vulnerability, and a review of the Irish planning system and environmental law. It is recommended that the plan be integrated into the county development plan for legislative purposes. A series of acceptability matrices were devised to restrict potentially polluting activities in vulnerable areas while maintaining a balance between protection of the groundwater resource and the need to site essential developments.

Levels of some heavy Metals in Cocoyam ( Colocasia esculentum ) grown on Soil receiving Effluent from a Paint Industry

The levels of some heavy metals in soil samples and tubers of cocoyam ( Colocasia esculentum ) grown on soil receiving paint wastes (PWS) has been investigated using Atomic Absorption spectrophotometer (Unicam 939/959 model). Similar analyses were carried out for the same plant from a control area. The studies revealed that although the P.W.S contained abnormally high levels of Pb (474.14mgkg-1) and Cu (137.85mgkg-1). The paint waste tuber (PWT) recorded low levels of these metals: Pb (2.13mgkg-1) and Cu (13.85mgkg-1) respectively. Correlation analysis tested at 0.05 level of significance show that no significant correlation existed between the metals levels in the soil and the level in the tuber. In all cases the levels of the metals in the tubers were well below the upper limit documented for unpolluted plant. The results however suggest the ineffectiveness of the use of Colocasia esculentum as a bioindicator for heavy metal pollution in soil.

Environmental pollution with soil-transmitted helminths in Sanliurfa, Turkey

Soil transmitted helminth (STH) infection are endemic in developing countries. A study was carried out of sewage farms, streams and vegetables to determine the sources and routes of STH infection in Sanliurfa, Turkey. Stool samples from farmhouse inhabitants as well as soil and vegetable samples from the gardens were collected and examined. In addition, water samples from streams and vegetable samples from the city market were collected and examined. One hundred and eighty-seven (59.5%) of a total of 314 samples, including 88.4% of the stool samples, 60.8% of the water samples, 84.4% of the soil samples and 14% of the vegetable samples, were found to be positive for STH eggs. These results indicate that the water, soil and vegetables are heavily contaminated, and suggest a vicious circle between humans and the environment. Improving environmental sanitation is imperative for the control of soil-transmitted helminthiasis in Sanliurfa.