(Table 2) Depth-age control points of ODP Site 177-1090

At Ocean Drilling Program (ODP) Site 1090 on the Agulhas Ridge (subantarctic South Atlantic) benthic foraminiferal stable isotope records span the late Oligocene through the early Miocene (25~16 Ma) at a temporal resolution of ?10 kyr. In the same time interval a magnetic polarity stratigraphy can be unequivocally correlated to the geomagnetic polarity timescale (GPTS), thereby providing secure correlation of the isotope record to the GPTS. On the basis of the isotope-magnetostratigraphic correlation we provide refined age calibration of established oxygen isotope events Mi1 through Mi2 as well as several other distinctive isotope events. Our data suggest that the d18O maximum commonly associated with the Oligocene/Miocene (O/M) boundary falls within C6Cn.2r (23.86 Ma). The d13C maximum coincides, within the temporal resolution of our record, with C6Cn.2n/r boundary and hence to the O/M boundary. Comparison of the stable isotope record from ODP Site 1090 to the orbitally tuned stable isotope record from ODP Site 929 across the O/M boundary shows that variability in the two records is very similar and can be correlated at and below the O/M boundary. Site 1090 stable isotope records also provide the first deep Southern Ocean end-member for reconstructions of circulation patterns and late Oligocene to early Miocene climate change. Comparison to previously published records suggests that basin to basin carbon isotope gradients were small or nonexistent and are inconclusive with respect to the direction of deep water flow. Oxygen isotope gradients between sites suggest that the deep Southern Ocean was cold in comparison to the North Atlantic, Indian, and the Pacific Oceans. Dominance of cold Southern Component Deep Water at Site 1090, at least until 17 Ma, suggests that relatively cold circumpolar climatic conditions prevailed during the late Oligocene and early Miocene. We believe that a relatively cold Southern Ocean reflects unrestricted circumpolar flow through the Drake Passage in agreement with bathymetric reconstructions.

Location, intervals and thickness of Cretaceous sections in Indian Ocean DSDP and ODP sites (Table 2)

The Indian Ocean covers approximately 73.5 * 10**6 km**3 from 25°N to 67°S and from 20° to 120°E. Several legs of the Deep Sea Drilling Project (DSDP) and the Ocean Drilling Program (ODP) have operated in its waters, many penetrating the Cretaceous. Most of the scientific drill sites are DSDP related and thus pre-dated modern biostratigraphic conventions. Foraminifers and calcareous nannoplankton were by far the dominant fossil groups studied in the earlier work, supplemented occasionally by studies of other fossil groups, The results of the Ocean Drilling Project phase are yet too young to be fully integrated but have been based on a broader range of techniques and fossil groups. During most of the Cretaceous, the proto-Indian Ocean basin lay in middle to high latitudes. Thus, it is unrealistic to expect successful routine application of low-latitude zonations. No planktonic foraminifer zonal scheme has been developed for the Indian Ocean basin for several reasons. There are no sections with complete or even significant partial sections to allow development of such a zonation. Carbonate compensation depth (CCD) effects have been marked in most sections, and significant intervals are devoid of planktonic foraminifers. The Indian Ocean now covers a great latitudinal range from tropics to polar regions and, at first glance, no scheme can be expected to be applicable over that entire range. In the Cretaceous the area was much smaller, though expanding progressively, and the paleolatitude range was quite small. Calcareous nannoplankton have proved valuable in dating Indian Ocean Cretaceous sediments and have, perhaps in contrast with the foraminifers, been consistently a more reliable means of applying zonal schemes developed elsewhere. For the Albian-Aptian, zonations based on well-known benthic foraminifer lineages (Scheibnerova, 1974) have been useful when nothing else was available or effective. Palynology has been used little, but where used, has proved excellent. It has the added value of providing valuable information on nearby terrestrial vegetation as the fossils were resistant to dissolution. Normally, when different fossil groups have been applied to a section, the results have been compatible or compatible to an acceptable degree. There are a few instances where incompatibility is noteworthy, and Site 263 is a classic example, as even two calcareous nannoplankton studies show irreconcilable differences here. All groups gave different results, but one benthic foraminifer analysis agreed with one calcareous nannoplankton study.

Geochemistry of Eocene/Oligocene sediments of ODP Site 177-1090

The Agulhas Ridge, off the tip of Africa between the Atlantic and Indian Oceans, is ideally located to capture the evolution of Paleogene-early Neogene circulation patterns associated with global cooling. Multiproxy records of productivity (biogenic barium (Baex), opal, CaCO3 mass accumulation rates (MARs)), nutrient and organic carbon burial (reactive phosphorus (Pr) MARs), and redox state of deep waters (U enrichment) from Ocean Drilling Program (ODP) Site 1090 reflect hydrographic shifts in this region between the middle Eocene and early Oligocene (~9-33 Ma). Several peaks in increased export productivity and burial of organic matter occurred within the late Eocene (~36.5, ~34, and ~33.7 Ma), which along with surface hydrologic conditions favoring opaline organisms over calcareous organisms could have aided in the draw down of pCO2 to a threshold level that facilitated large ice sheet development on Antarctica in the earliest Oligocene. Our multiproxy approach illustrates the importance of vertical as well as spatial hydrographic reorganization in amplifying or driving climatic cooling of the middle Eocene to early Oligocene by facilitating increases in the relative or absolute burial of organic carbon.

Mineralogy at DSDP Site 82-558 and Hole 82-563

Downhole bulk-sample and clay-mineral analytical results for Sites 558 and 563 are presented in this chapter. These results show a Tertiary climatic and hydrologic evolution similar to that at other DSDP drill sites in the northeastern Atlantic Ocean (Sites 398, 403-406, 548-550, 552-555). The sediments recovered at both sites are primarily calcareous and chalky oozes characterized by >90% carbonate and minor quartz and plagioclase feldspar. Clay minerals smectite, kaolinite, illite, and chlorite are present throughout the cores; upsection, illite increases at the expense of smectite. The clay mineralogy suggests climatic cooling and increased ocean circulation during the Miocene. Intervals rich in very fine grained (<2 µm) quartz suggest times of increased eolian input. This could have resulted from development, during Oligocene and late Miocene time, of an arid, desertlike sediment provenance that lasted until the present day.

Clay mineralogy of ODP Site 131-808 sediments

Drill core recovered at Ocean Drilling Program Site 808 (Leg 131) proves that the wedge of trench sediment within the central region of the Nankai Trough comprises approximately 600 m of hemipelagic mud, sandy turbidites, and silty turbidites. The stratigraphic succession thickens and coarsens upward, with hemipelagic muds and volcanic-ash layers of the Shikoku Basin overlain by silty and sandy trench-wedge deposits. Past investigations of clay mineralogy and sand petrography within this region have led to the hypothesis that most of the detritus in the Nankai Trough was derived from the Izu-Honshu collision zone and transported southwestward via axial turbidity currents. Shipboard analyses of paleocurrent indicators, on the other hand, show that most of the ripple cross-laminae within silty turbidites of the outer marginal trench-wedge facies are inclined to the north and northwest; thus, many of the turbidity currents reflected off the seaward slope of the trench rather than moving straight down the trench axis. Shore-based analyses of detrital clay minerals demonstrate that the hemipelagic muds and matrix materials within sandy and silty turbidites are all enriched in illite; chlorite is the second-most abundant clay mineral, followed by smectite. In general, the relative mineral percentages change relatively little as a function of depth, and the hemipelagic clay-mineral population is virtually identical to the turbidite-matrix population. Comparisons between different size fractions (<2 µm and 2-6 µm) show modest amounts of mineral partitioning, with chlorite content increasing in the coarser fraction and smectite increasing in the finer fraction. Values of illite crystallinity index are consistent with conditions of advanced anchimetamorphism and epimetamorphism within the source region. Of the three mica polytypes detected, the 2M1 variety dominates over the 1M and 1Md polytypes; these data are consistent with values of illite crystallinity. Measurements of mica bo lattice spacing show that the detrital illite particles were eroded from a zone of intermediate-pressure metamorphism. Collectively, these data provide an excellent match with the lithologic and metamorphic character of the Izu-Honshu collision zone. Data from Leg 131, therefore, confirm the earlier interpretations of detrital provenance. The regional pattern of sediment dispersal is dominated by a combination of southwest-directed axial turbidity currents, radial expansion of the axial flows, oblique movement of suspended clouds onto and beyond the seaward slope of the Nankai Trough, and flow reflection back toward the trench axis.

Stable carbon isotope record and geochemistry of late Miocene-early Pliocene sediments from DSDP Site 90-590 in the Tasman Sea

Biogenic components of sediment accumulated at high rates beneath frontal zones of the Indian and Pacific oceans during the late Miocene and early Pliocene. The delta13C of bulk and foraminiferal carbonate also decreased during this time interval. Although the two observations may be causally linked, and signify a major perturbation in global biogeochemical cycling, no site beneath a frontal zone has independent records of export production and delta13C on multiple carbonate phases across the critical interval of interest. Deep Sea Drilling Project (DSDP) site 590 lies beneath the Tasman Front (TF), an eddy-generating jetstream in the southwest Pacific Ocean. To complement previous delta13C records of planktic and benthic foraminifera at this location, late Neogene records of CaCO3 mass accumulation rate (MAR), Ca/Ti, Ba/Ti, Al/Ti, and of bulk carbonate and foraminiferal delta13C were constructed at site 590. The delta13C records include bulk sediment, bulk sediment fractions (<63 µm and 5-25 µm), and the planktic foraminifera Globigerina bulloides, Globigerinoides sacculifer (with and without sac), and Orbulina universa. Using current time scales, CaCO3 MARs, Ca/Ti, Al/Ti and Ba/Ti ratios are two to three times higher in upper Miocene and lower Pliocene sediment relative to overlying and underlying units. A significant decrease also occurs in all delta13C records. All evidence indicates that enhanced export production - the 'biogenic bloom' - extended to the southwest Pacific Ocean between ca. 9 and 3.8 Ma, and this phenomenon is coupled with changes in delta13C - the 'Chron C3AR carbon shift'. However, CaCO3 MARs peak ca. 5 Ma whereas elemental ratios are highest ca. 6.5 Ma; foraminiferal delta13C starts to decrease ca. 8 Ma whereas bulk carbonate delta13C begins to drop ca. 5.6 Ma. Temporal discrepancies between the records can be explained by changes in the upwelling regime at the TF, perhaps signifying a link between changes in ocean-atmosphere circulation change and widespread primary productivity.

(Table T2) Spectral reflectance record for ODP Site 188-1165

Two main alternating facies were observed at Ocean Drilling Program (ODP) Site 1165, drilled in 3357 m water depth into the Wild Drift (Cooperation Sea, Antarctica): a dark gray, laminated, terrigenous one (interpreted as muddy contourites) and a greenish, homogeneous, biogenic and coarse fraction-bearing one (interpreted as hemipelagic deposits with ice rafted debris [IRD]). These two cyclically alternating facies reflect orbitally driven changes (Milankovitch periodicities) recorded in spectral reflectance, bulk density, and magnetic susceptibility data and opal content changes. Superimposed on these short-term variations, significant uphole changes in average sedimentation rates, total clay content, IRD amount, and mineral composition were interpreted to represent the long-term lower to upper Miocene transition from a temperate climate to a cold-climate glaciation. The analysis of the short-term variations (interpreted to reflect ice sheet expansions controlled by 41-k.y. insolation changes) requires a quite closely spaced sampled record like that provided by the archive multisensor track. Among those, cycles are best described by spectral reflectance data and, in particular, by a parameter calculated as the ratio of the reflectivity in the green color band and the average reflectivity (gray). In this data report a numerical evaluation of spectral reflectance data was performed and substantiated by correlation with core photos to provide an objective description of the color variations within Site 1165 sediments. The resulting color description provides a reference to categorize the available samples in terms of facies and, hence, a framework for further analyses. Moreover, a link between visually described features and numerical series suitable for spectral analyses is provided.

(Table 2) Age model of ODP Site 184-1146

Orbital tuning of benthic d18O is a common approach for assigning ages to ocean sediment records. Similar environmental forcing of the northern South China Sea and the southeast Asian cave regions allows for transfer of the speleothem d18O radiometric chronology to the planktonic and benthic d18O records from Ocean Drilling Program Site 1146, yielding a new chronology with 41 radiometrically calibrated datums, spanning the past 350 kyr. This approach also provides for an independent assessment of the accuracy of the orbitally tuned benthic d18O chronology for the last 350 kyr. The largest differences relative to the latest chronology occur in marine isotope stages (MIS) 5.4, 5.5, 6, 7, and 9.3. Prominent suborbital-scale structure believed to be global in nature is identified within MIS 5.4 and MIS 7.2. On the basis of the radiometrically calibrated chronology, the time constant of the ice sheet is found to be 5.4 kyr at the precession band (light d18O lags precession minima by -55.4°) and 10.4 kyr at the obliquity band (light d18O lags obliquity maxima by 57.4°). These values are significantly shorter than the single 17 kyr time constant originally estimated by Imbrie et al. (1984), based primarily on the timing of terminations I and II and the 15 kyr time constant used by Lisiecki and Raymo (2005, doi:10.1029/2004PA001071).

(Table 1) Element concentrations in detrital sediments of ODP Site 184-1148

The chemical index of alteration (CIA) and elemental ratios that are sensitive to chemical weathering, such as Ca/Ti, Na/Ti, Al/Ti, Al/Na, Al/K, and La/Sm, were analyzed for detrital sediments at Ocean Drilling Program Site 1148 from the northern South China Sea to reveal information of chemical weathering in the source regions during the early Miocene. High CIA values of ~80, coupled with high Al/Ti and Al/Na and low Na/Ti and Ca/Ti, are observed for the sediments at ~23 Ma, indicating a high chemical weathering intensity in the north source region, i.e., south China. This was followed by gradual decreases in Al/Ti, Al/Na, La/Sm, and Al/K ratios, as well as the CIA values, and increases in Ca/Ti and Na/Ti ratios. These records together with other paleoclimate proxies, such as black carbon d13C and benthic foraminifer d18O, give reliable information on the climate changes in south China. Our results show that the climate in south China was warm and humid in the early Miocene (~23 Ma) according to the chemical weathering records. The humidity in south China decreased from the early Miocene to Present with several fluctuations centering at approximately 15.7 Ma, 8.4 Ma, and 2.5 Ma, coincident with the global cooling since the middle Miocene. These climate changes implied that the summer east Asian monsoon has dramatically affected south China in the early Miocene, whereas the influence of the summer monsoon on this region has decreased continuously since that time, probably because of the intensification of the winter monsoon. Such an evolution for the east Asian monsoon is different from that for the Indian monsoon.

Atlantic 231Pa/230Th and biogenic opal compilation of the Holocene and the LGM

The strength and geometry of the Atlantic meridional overturning circulation is tightly coupled to climate on glacial-interglacial and millennial timescales, but has proved difficult to reconstruct, particularly for the Last Glacial Maximum. Today, the return flow from the northern North Atlantic to lower latitudes associated with the Atlantic meridional overturning circulation reaches down to approximately 4,000 m. In contrast, during the Last Glacial Maximum this return flow is thought to have occurred primarily at shallower depths. Measurements of sedimentary 231Pa/230Th have been used to reconstruct the strength of circulation in the North Atlantic Ocean, but the effects of biogenic silica on 231Pa/230Th-based estimates remain controversial. Here we use measurements of 231Pa/230Th ratios and biogenic silica in Holocene-aged Atlantic sediments and simulations with a two-dimensional scavenging model to demonstrate that the geometry and strength of the Atlantic meridional overturning circulation are the primary controls of 231Pa/230Th ratios in modern Atlantic sediments. For the glacial maximum, a simulation of Atlantic overturning with a shallow, but vigorous circulation and bulk water transport at around 2,000 m depth best matched observed glacial Atlantic 231Pa/230Th values. We estimate that the transport of intermediate water during the Last Glacial Maximum was at least as strong as deep water transport today.

Lima Township (Mich.) residences

Left to right: Oak Lawn Farm Res. of Thos. S. Sears, Sec. 6, Lima Tp. Mich.; Res. of Elias Westfall, Sec. 9, Lima Tp. Mich.; Res. of Thomas Jewett, Sec 20, Lima Tp., Mich.; Res. of Richard Goodwin, sec. 9, Lima Tp. Mich.; Res. of Geo. H. Mitchell, Sec 28, Lima Tp., Mich.; Res. of Sampson Parker, Sec 24, Lima Tp. Mich. Publication information: Chicago, Ill. : Everts & Stewart, 1874.

On-site production of activated carbon from kraft black liquor /

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