A new brominated phenylpropylaldehyde and its dimethyl acetal from red alga Rhodomela confervoides

A new brominated phenylpropylaldehyde and its dimethyl acetal together with a new natural brominated phenol were isolated from Rhodomela confervoides. Their structrues were elucidated as 2-methyl-3-(2,3-dibromo-4,5-dihydroxyphenyl)propylaldehyde, 2-methyl-3-(2,3-dibromo-4,5-dihydroxyphenyl) propylaldehyde dimethyl acetal and 3-bromo-4,5-dihydroxybenzoic acid methyl ester by spectroscopic techniques including IR, HRFABMS, ID and 2DNMR experiments.

Two new bromophenols from red alga Rhodomela confervoides

Two new bromophenols were isolated from Rhodomela confervoides. Their structures were elucidated as 2, 2', 3-tribromo-3', 4, 4', 5-tetrahydroxy-6'-hydroxymethyldiphenylmethane and 2, 2', 3-tribromo-3', 4, 4', 5-tetrahydroxy-6'-ethyloxymethyldiphenylmethane by spectroscopic methods including IR, HREIMS, 1D and 2D NMR techniques.

A new poly brominated dibenzylphenol from Rhodomela confervoides

A new poly brominated dibenzylphenol named as rhodomevoidin was isolated from Rhodomela confervoides. Its structrue was elucidated as 3-bromo-4, 5-bis (2, 3-dibromo-4, 5-dihydroxybenzyI)pyrocatechol by spectroscopic methods including IR, HRFABMS, 1D and 2D NMR techniques.

Two new norisoprenoid derivatives from the red alga Gymnogongrus flabelliformis

Two new norisoprenoid derivatives have been isolated from the red alga Gymnogongrus flabelliformis. Their structures were elucidated as (3R, 6R, 7E)-(+)-3-O-phenylacetyl-4,7-megastigmadiene-9-one and (3R,7E)-(-)-3-O-phenylacetyl-5,7-megastigmadiene-9-one, respectively, by spectroscopic methods including HRMS, 1D and 2D NMR techniques.

A new species of Bryodema (Orthoptera : Acridoidea) from China, with a key to the described species

A new species Bryodema nigrofrascia of the genus Bryodema Fieber, 1853 (Orthoptera, Acridoidea, Acrididae Oedipodinae) from China is described. A key to known species of the genus is given. The type specimens are deposited in the Northwest Plateau Institute of Biology, Chinese Academy of Sciences, Xining, Qinghai.

A new daphnane diterpene from Daphne tangutica

A new daphnane diterpene was isolated from the root barks of Daphne tangutica Maxim. Its structure was elucidated as 1, 2 alpha-dihydro-20-palimoyldaphnetoxin by the spectroscopic evidence including 2D-NMR.

Notes on grasses (Poaceae) for the Flora of China, VI. New combinations in Stipeae and Anthoxantham

When Oryzopsis is confined to the type species, Chinese species are placed in Achnatherum and Piptatherum. This necessitates the following new combinations: Piptatherum grandispiculum, Piptatherum aequiglume var. ligulatum, Piptatherum tibeticum var. psilolepis.. Piptatherum. munroi var. parviflorum, Achnatherum henryi. and Achnatherum henryi var. acutum. Achnatherum henryi is lectotypified. The new name Piptatherum kuoi replaces the illegitimate name Piptatherum obtusum, and this species is lectotypified. Hierochloe potaninii is transferred to Anthoxanthum as A. potaninii, as Hierochloe is regarded as a synonym of Anthoxanthum. All the grass taxa (Poaceae) listed are endemic to China.

Three new diterpenoids from Euphorbia wallichii

Three new abietane diterpene lactones, 3alpha-hydroxyjolkinolide A (1), ent-8alpha,14beta-dihydroxy-13(15)-ene-16(12alpha)-abietanolide (2) and ent-8alpha,14alpha-dihydroxy-13(15)-ene-16(12alpha)-abietanolide (3) as well as a known abietane diterpene jolkinolide A (4) were isolated from the roots of Euphorbia wallichii. Their structures were elucidated on the basis of spectroscopic analysis.

A new sesquiterpene lactone of Notoseris henryi

A new guaianolide, notoserolide E, along with nine known compounds was isolated from the Chinese endemic plant of Notoseris henryi ( Dunn) Shih and its structure was elucidated by means of spectroscopic evidence.

Two new xanthone glycosides from Swertia tetraptera

Two new xanthone glycosides, tetraswerosides A and B, were isolated from the whole plant of Swertia tertraptera. Their structures were determined as 3-O-beta -D-glucopyranosyl-1-hydroxy-4,7-dimethoxyxanthone and 3-O-[beta -D-xylopyranosyl-(1-->6)-beta -D-glucopyranosyl]-1- hydroxy-4,7-dimethoxyxanthone by spectroscopic methods.

Two new diterpenoids from Isodon rubescens

Two new diterpenoids taibairubescensin A (1) and B (2) have been isolated from Isodon rubescens. The structures of compound 1 and 2 were elucidated as 2 beta,3 beta-diacetoxy-11 beta,13 alpha-dihydroxy-ent-kaur- 16-en-15-one (1) and 3 beta,11 beta-diacetoxy-2 beta,6 alpha-dihydroxy-ent-kaur-16-en-15-one (2) on the basis of spectroscopic analysis.

石笋微层序列的断代和信号研究

Based on chronological and climatologic analysis of many young stalagmites in Shihua Cave at Beijing and Water Cave in Benxi, Liaoning Province, this dissertation aims to discuss some key points on quantitative reconstruction of high resolution climate change from micro bands time series in young stalagmites. On chronological aspect of micro bands time series in young stalagmite, the uppermost micro bands were testified formed in the sampling year or the year before sampling from long term and in situ experiment in Shihua Cave at Beijing. Have been observed detailed under microscope, the micro bands were counted and compared with high resolution TIMS-230Th or ICP-MS U series dating, the results show that the micro bands are annual bands. The microscopic characteristics of annual bands in North China is as follows after studying lots of young stalagmites: the interface appears to be carved, and there is a light line adjacent to it, which moves back and forth slightly when adjusting the microscope slide. The cross dating of annual bands from different stalagmites is experimented in this thesis. On climatologically aspect of micro bands times series in young stalagmites, one significant problem is that the deposition trend resulting from the variation of the stalagmite shape. Various deposition trends have been discussed and corrected before climatologically analysis of micro bands series. And the whole year in situ observation and analysis of dripping water in Shihua Cave provide us new evidence for climate information reserved in stalagmites micro bands. The stalagmites in the same cave may contain different climate information due to the micro hydrological condition. The annual bands of young stalagmites collected from North China can be used to reconstruct past climate changes quantitatively. The warm season temperature (May, June, July, August) is reconstructed using two annual bands time series from Shihua Cave, Beijing, which corresponds to the warm/cool periods very well in Chinese history documents. The precipitation record of past 500 years is reconstructed using two stalagmite annual bands series from Shihua Cave, which is consistent to the dryness/wetness records derived from historical documents too.

小学学习不良儿童对言语交际策略的理解与运用

[Abstract] Verbal communication strategy (VCS) refers to a programmed knowledge applied by individuals to understand and express intentions via language symbols in their realization of communicative objectives according to social conventions. As an important index of social development, verbal communication strategy has provided a new perspective for social skill studies. However, more work has to be done in the investigation of LD children’s VCS developmental pattern and affecting mechanism. Through contextual test, structured interview and role-play, the present study, by adopting integrated measurements of instrumental and interpersonal effectiveness, explored the developmental characteristics of Chinese learning-disabled primary school children across 3-6th grades at both comprehension and application levels. Then, their social perspective-taking performance and verbal retelling competence of each participant were examined, on the basis of which, path analysis was conducted, with social perspective-taking, verbal retelling and verbal communication strategy comprehension as independent variables, to reveal the inner mechanism affecting LD children’s application of verbal communication strategy. Finally, an intervention study was carried out through a combination of polite request strategy understanding lessons and social perspective-taking training dramas. The results indicate that:(1) No significant grade differences were found in LD group for polite request strategy, while significant differences were reported across different grades of non-LD children. For indirect reply strategy, significant grade and gender differences were found among LD children, but the developmental trajectory between the two groups was different. For both polite request and indirect reply strategies, the strategy comprehension level of LD children was significantly lower than those without learning disabilities. (2) No significant grade and gender differences were found in LD group in their application of polite request strategy, while for non-LD children, significant differences were reported across different grades. For indirect reply strategy, both LD and non-LD groups exhibited similar developmental characteristics. Significant group differences only exist in the over-all application level of polite request strategies, not in indirect reply strategies. However, the differences of the latter between the two groups were found at significant level only among the 11-12 year olds. (3) LD children’s perspective-taking and verbal retelling competence were significantly lower than those of non-LD group. For polite request strategy, the influence of social perspective-taking to strategy application was indirect and must be via strategy comprehension, while for indirect reply strategy, strategy comprehension was found to play as a partial mediator between social perspective-taking and strategy application. The influence of verbal retelling to strategy application was indirect on both types of strategies. (4) LD children’s strategy comprehension and social perspective-taking level can be improved, and the improvement of these two competences has significant positive impact on the increase of their strategy application level. Key Words: learning disabilities, verbal communication strategy, social perspective- taking