Análises físico-químicas e biológicas de diferentes scaffolds à base de polihidroxibutirato e polihidroxibutirato-co-valerato

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Membranas de biocelulose como substrato para o crescimento de nanofios de ZnO: síntese e aplicação

Pós-graduação em Química - IQ

Gerenciamento de Big Data em plantas industriais

Nowadays the companies generate great amount of data from different sources, however some of them produce more data than they can analyze. Big Data is a set of data that grows very fast, collected several times during a short period of time. This work focus on the importance of the correct management of Big Data in an industrial plant. Through a case study based on a company that belongs to the pulp and paper area, the problems resolutions are going to be presented with the usage of appropriate data management. In the final chapters, the results achieved by the company are discussed, showing how the correct choice of data to be monitored and analyzed brought benefits to the company, also best practices will be recommended for the Big Data management

Diretrizes para o gerenciamento de resíduos provenientes de papel na UNESP, câmpus de Rio Claro

As atividades exercidas em uma Instituição acadêmica resultam na formação de diversos tipos de resíduos entre eles um volume considerável daqueles provenientes de celulose, principalmente variedades de papel e papelão, sendo o primeiro utilizado em larga escala para a confecção de objetos para os mais variados fins, de atividades didáticas, usos para fins de limpeza, até documentos. O presente trabalho foi realizado integrado às práticas do projeto PGR (Plano de Gerenciamento de Resíduos) desenvolvido no campus da Unesp de Rio Claro, tendo como objetivo o diagnóstico do gerenciamento dos resíduos de papel e papelão, tais como as práticas de descarte, reciclagem e/ou reutilização vigentes para posterior elaboração de um manual para o gerenciamento ambientalmente correto de tais tipos de resíduos. Para esse levantamento foi elaborado um questionário (Check-list) que foi aplicado nos diferentes setores da UNESP entre Novembro de 2014 e Abril de 2015. A partir desse levantamento preliminar e da quantificação aproximada do montante de resíduos e das porcentagens reutilizadas/recicladas e as descartadas, visou-se propor melhorias no processo de gerenciamento deste tipo de resíduo. O montante de resíduos provenientes de papel gerado nos 50 setores avaliados, sendo 27 do Instituto de Biociências, 21 do Instituto de Geociências e Ciências Exatas e dois de uso comum entre os dois institutos, foi de aproximadamente 190kg de material, embora observado que na maioria das vezes os papéis tenham sido eliminados junto a resíduos de outra natureza, até mesmo orgânicos. Também foram constatadas a proporção de setores que procuram reduzir e reutilizar seus resíduos, sendo que a reutilização de papéis diversos para rascunhos e a utilização de caixas de papelão para o armazenamento de variados objetos foram as práticas mais comumente observadas, sendo apresentadas em maior ou menor grau em 62% dos setores visitados

Obtenção e caracterização de nanocelulose a partir de fibras de Chorisia speciosa St. Hil

Natural fibers have been highlighted as a renewable material that can replace materials from oil and its derivatives. In this context, Brazil becomes the perfect setting because of the diversity of fibers found in its territory, such as sugarcane, sisal, rice, cotton, coconut, pineapple, among others. The paineiras (Chorisia speciosa St. Hil) are typically Brazilian trees, which produce paina as fruit. These fruits are still little studied as a source of lignocellulose by research groups. This project aimed obtaining and characterization of cellulose nanofibers from the fibers from the paina fibers. Obtaining nanocellulose is practically made through simplified chemical processes. First, was performed out pre-treatments to removal of waxes, lignin and hemicellulose. The first stage of pre-treatment was carried out by alkaline aqueous solution of sodium hydroxide (NaOH) at 5wt%, where the fibers were under constant agitation for 1h at 70°C. Through alkali treatment it was possible to remove most of the lignin, hemicellulose, waxes and extractives. After the alkaline treatment was done bleaching with an aqueous solution of sodium hydroxide (NaOH) to 4wt% and hydrogen peroxide (H2O2) to 24wt% 1:1 during 2h with constant stirring to 50 °C. Through bleaching was possibe to remove residual lignin, and got cellulose with 72% of crystallinity. Nanocellulose of paina fibers was extracted using different conditions of acid hydrolysis with sulfuric acid (H2SO4) to 50wt%. After acid hydrolysis, the suspensions were centrifuged during 30 min and dialyzed in water to remove excess acid until neutral pH (6-7). Then the suspensions were passed by ultrasonification in an ultrasound 20 kHz during 1h in an ice bath. Untreated, alkalinized and bleached fibers as well as cellulose nanoparticles were characterized by the techniques of thermogravimetry ... (Complete abastract click electronic access below)

Organic material decomposition and nutrient dynamics in a mulch system enriched with leguminous trees in the Amazon

As novas técnicas propostas para a agricultura na Amazônia incluem sistema de rotação de capoeira enriquecido com árvores leguminosas e transformando a queima da biomassa em cobertura morta sobre o solo. A decomposição e a liberação de nutrientes da cobertura morta foram estudadas usando sacos de liteira com malha fina que continham cinco tratamentos com diferentes espécies de leguminosas em comparação a um tratamento-controle com vegetação natural. As amostras para cada tratamento foram analisadas para conteúdos de C total, N, P, K, Ca, Mg, lignina, celulose e polifenóis solúveis em diferentes tempos de amostragem durante um ano. A razão constante de decomposição variou com a espécie e com o tempo. A perda de massa nos sacos de decomposição foi de 30,1 % para Acacia angustissima, de 32,7 % para Sclerolobium paniculatum, de 33,9 % para Inga edulis e para a vegetação secundária, de 45,2 % para Acacia mangium e de 63,6 % para Clitoria racemosa. Foi observada imobilização de N e P em todos os tratamentos, sendo a mineralização do N negativamente correlacionada com o fenol, razão C/N, razão (lignina + fenol)/N, razão fenol/P e o conteúdo de N nos sacos de liteira. Depois de 362 dias de incubação no campo, 3,3 % de K, 32,2 % de Ca e 22,4 % de Mg permaneceram no material em decomposição. Os resultados evidenciaram que a baixa qualidade mineral e a alta quantidade de carbono orgânico e aplicado como cobertura morta podem limitar a quantidade de energia disponível para os microrganismos resultando em uma competição por nutrientes com as plantas agrícolas.

Métodos de extração da lignina do bagaço da cana-de-açúcar do Noroeste do Estado de São Paulo

Pós-graduação em Química - IBILCE

Análises físico-químicas e biológicas de diferentes scaffolds à base de polihidroxibutirato e polihidroxibutirato-co-valerato

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Membranas de biocelulose como substrato para o crescimento de nanofios de ZnO: síntese e aplicação

Pós-graduação em Química - IQ

Gerenciamento de Big Data em plantas industriais

Nowadays the companies generate great amount of data from different sources, however some of them produce more data than they can analyze. Big Data is a set of data that grows very fast, collected several times during a short period of time. This work focus on the importance of the correct management of Big Data in an industrial plant. Through a case study based on a company that belongs to the pulp and paper area, the problems resolutions are going to be presented with the usage of appropriate data management. In the final chapters, the results achieved by the company are discussed, showing how the correct choice of data to be monitored and analyzed brought benefits to the company, also best practices will be recommended for the Big Data management

Diretrizes para o gerenciamento de resíduos provenientes de papel na UNESP, câmpus de Rio Claro

As atividades exercidas em uma Instituição acadêmica resultam na formação de diversos tipos de resíduos entre eles um volume considerável daqueles provenientes de celulose, principalmente variedades de papel e papelão, sendo o primeiro utilizado em larga escala para a confecção de objetos para os mais variados fins, de atividades didáticas, usos para fins de limpeza, até documentos. O presente trabalho foi realizado integrado às práticas do projeto PGR (Plano de Gerenciamento de Resíduos) desenvolvido no campus da Unesp de Rio Claro, tendo como objetivo o diagnóstico do gerenciamento dos resíduos de papel e papelão, tais como as práticas de descarte, reciclagem e/ou reutilização vigentes para posterior elaboração de um manual para o gerenciamento ambientalmente correto de tais tipos de resíduos. Para esse levantamento foi elaborado um questionário (Check-list) que foi aplicado nos diferentes setores da UNESP entre Novembro de 2014 e Abril de 2015. A partir desse levantamento preliminar e da quantificação aproximada do montante de resíduos e das porcentagens reutilizadas/recicladas e as descartadas, visou-se propor melhorias no processo de gerenciamento deste tipo de resíduo. O montante de resíduos provenientes de papel gerado nos 50 setores avaliados, sendo 27 do Instituto de Biociências, 21 do Instituto de Geociências e Ciências Exatas e dois de uso comum entre os dois institutos, foi de aproximadamente 190kg de material, embora observado que na maioria das vezes os papéis tenham sido eliminados junto a resíduos de outra natureza, até mesmo orgânicos. Também foram constatadas a proporção de setores que procuram reduzir e reutilizar seus resíduos, sendo que a reutilização de papéis diversos para rascunhos e a utilização de caixas de papelão para o armazenamento de variados objetos foram as práticas mais comumente observadas, sendo apresentadas em maior ou menor grau em 62% dos setores visitados

Obtenção e caracterização de nanocelulose a partir de fibras de Chorisia speciosa St. Hil

Natural fibers have been highlighted as a renewable material that can replace materials from oil and its derivatives. In this context, Brazil becomes the perfect setting because of the diversity of fibers found in its territory, such as sugarcane, sisal, rice, cotton, coconut, pineapple, among others. The paineiras (Chorisia speciosa St. Hil) are typically Brazilian trees, which produce paina as fruit. These fruits are still little studied as a source of lignocellulose by research groups. This project aimed obtaining and characterization of cellulose nanofibers from the fibers from the paina fibers. Obtaining nanocellulose is practically made through simplified chemical processes. First, was performed out pre-treatments to removal of waxes, lignin and hemicellulose. The first stage of pre-treatment was carried out by alkaline aqueous solution of sodium hydroxide (NaOH) at 5wt%, where the fibers were under constant agitation for 1h at 70°C. Through alkali treatment it was possible to remove most of the lignin, hemicellulose, waxes and extractives. After the alkaline treatment was done bleaching with an aqueous solution of sodium hydroxide (NaOH) to 4wt% and hydrogen peroxide (H2O2) to 24wt% 1:1 during 2h with constant stirring to 50 °C. Through bleaching was possibe to remove residual lignin, and got cellulose with 72% of crystallinity. Nanocellulose of paina fibers was extracted using different conditions of acid hydrolysis with sulfuric acid (H2SO4) to 50wt%. After acid hydrolysis, the suspensions were centrifuged during 30 min and dialyzed in water to remove excess acid until neutral pH (6-7). Then the suspensions were passed by ultrasonification in an ultrasound 20 kHz during 1h in an ice bath. Untreated, alkalinized and bleached fibers as well as cellulose nanoparticles were characterized by the techniques of thermogravimetry ... (Complete abastract click electronic access below)

Effects of irrigation on water use and water use efficiency in two fast growing Eucalyptus plantations

Eucalyptus plantations occupy almost 20 million ha worldwide and exceed 3.7 million ha in Brazil alone. Improved genetics and silviculture have led to as much as a three-fold increase in productivity in Eucalyptus plantations in Brazil and the large land area occupied by these highly productive ecosystems raises concern over their effect on local water supplies. As part of the Brazil Potential Productivity Project, we measured water use of Eucalyptus grandis x urophylla clones in rainfed and irrigated stands in two plantations differing in productivity. The Aracruz (lower productivity) site is located in the state of Espirito Santo and the Veracel (higher productivity) site in Bahia state. At each plantation, we measured stand water use using homemade sap flow sensors and a calibration curve using the clones and probes we utilized in the study. We also quantified changes in growth, leaf area and water use efficiency (the amount of wood produced per unit of water transpired). Measurements were conducted for 1 year during 2005 at Aracruz and from August through December 2005 at Veracel. Transpiration at both sites was high compared to other studies but annual estimates at Aracruz for the rainfed treatment compared well with a process model calibrated for the Aracruz site (within 10%). Annual water use at Aracruz was 1394 mm in rainfed treatments versus 1779 mm in irrigated treatments and accounted for approximately 67% and 58% of annual precipitation and irrigation inputs respectively. Increased water use in the irrigated stands at Aracruz was associated with higher sapwood area, leaf area index and transpiration per unit leaf area but there was no difference in the response of canopy conductance with air saturation deficit between treatments. Water use efficiency at the Aracruz site was also not influenced by irrigation and was similar to the rainfed treatment. During the period of overlapping measurements, the response to irrigation treatments at the more productive Veracel site was similar to Aracruz. Stand water use at the Veracel site totaled 975 mm and 1102 mm in rainfed and irrigated treatments during the 5-month measurement period respectively. Irrigated stands at Veracel also had higher leaf area with no difference in the response of canopy conductance with air saturation deficit between treatments. Water use efficiency was also unaffected by irrigation at Veracel. Results from this and other studies suggest that improved resource availability does not negatively impact water use efficiency but increased productivity of these plantations is associated with higher water use and should be given consideration during plantation management decision making processes aimed at increasing productivity. Published by Elsevier B.V.

Skeletal abnormalities in humpback whales Megaptera novaeangliae stranded in the Brazilian breeding ground

Skeletal tissues of 49 humpback whales Megaptera novaeangliae that stranded between 2002 and 2011 along the Abrolhos Bank seashore and its adjacent waters in Brazil were studied. Twelve (24.5%) animals presented pathological changes in one or more bones. Degenerative changes and developmental malformations were most frequent (10.2% each), followed by inflammatory/infectious and traumatic lesions (8.2% each). Infectious diseases led to severe lesions of the caudal vertebrae of 2 whales. In one of these individuals, the lesions involved 6 caudal vertebrae, leading to ankylosis of 3 vertebrae. Degenerative changes were observed in the vertebral columns of 3 animals, involving the joints of 13 ribs of 1 individual, and in the humerus of 1 whale. Traumatic lesions, such as osseous callus in the ribs, were observed in 4 animals. In 1 whale, the rib showed severe osteomyelitis, possibly resulting from the infection of multiple fractures. Developmental abnormalities such as spina bifida on 3 cervical vertebrae of 1 whale, fusion of spinal processes on thoracic vertebrae of 1 individual and fusion of the first 2 ribs unilaterally or bilaterally in 4 animals were found. Chronic infectious conditions found in the axial skeleton may have restrained spinal mobility and had detrimental effects on the general health of the animals, contributing to stranding and death. To our knowledge, this is the first systematic study on skeletal lesions in stranded humpback whales.

Terrestrial non-volant small mammals in agro-silvicultural landscapes of Southeastern Brazil

The area covered by Eucalyptus plantations is significantly increasing in Brazil for economic reasons. However, the impact of such land use change is still unknown. In this study we evaluated the spatial-temporal distribution and abundance of terrestrial non-volant small mammals on a recently converted landscape whose matrix is formed by Eucalyptus plantations up to 3 years of age. From August 2007 to July 2009 we carried out monthly sampling campaigns over a grid of 30 sampling units, formed by pitfall traps covering both the landscape matrix of Eucalyptus plantations (n = 18) and legal conservation areas of native vegetation (n = 7) and abandoned pastures (n = 5). A total of 1640 individuals from 14 species of the orders Didelphimorphia (4 spp.) and Rodentia (10 spp.) were captured. However, only three species of rodents (Olygorysomys flavescens, Oligoryzomys nigripes and Calomy tener) represented 81.8% of the total amount. Eucalyptus plantations had a lower species richness and abundance than the abandoned pasture and the remaining fragments of native vegetation. Although the present species are predominantly generalists, there is clear distinction among environments in terms of their species composition and relative abundance, which also present a pronounced time variation. The assemblage found in this study suggests that silvicultural landscapes still have some conservation value, with species that seem to be resident at the Eucalyptus plantations. Moreover, the presence of the native and abandoned pastures patches imbibed in the Eucalyptus plantation matrix may increase the carrying capacity of such a silvicultural system and these landscapes may play a role in maintaining local biodiversity. (C) 2012 Elsevier B.V. All rights reserved.