Density and stable oxygen isotope profiles of four snow pits from Berkner Island, Filchner-Ronne Ice Shelf, Antarctica

The ice cap on Berkner Island is grounded on bedrock within the Filchner-Ronne Ice Shelf and is, therefore, expected to be a well-suited place to retrieve long-term ice-core records reflecting the environmental situation of the Weddell Sea region. Shallow firn cores were drilled to 11 m at the two main summits of Berkner Island and analysed in high depth resolution for electrical d.c. conductivity (ECM), stable isotopes, chloride, sulphate, nitrate and methane-sulphonate (MSA). From the annual layering of dD and non-sea-salt (nss) sulphate, a mean annual snow accumulation of 26.6 cm water at the north dome and 17.4 cm water at the south dome are obtained. As a result of ineffective wind scouring indicated by a relatively low near-surface snow density, regular annual cycles are found for all species at least in the upper 4-5 m. Post depositional changes are responsible for a substantial decrease of the seasonal dD and nitrate amplitude as well as for considerable migration of the MSA signal operating below a depth of 3-4 m. The mean chemical and isotopic firn properties at the south dome correspond to the situation on the Filchner-Ronne Ice shelf at a comparable distance to the coast, whereas the north dome is found to be more influenced by maritime air masses. Persistent high sea-salt levels in winter snow at Berkner Island heavily obscure the determination of nss sulphate probably due to sulphate fractionation in the Antartic sea-salt aerosols. Estimated time-scales predict ages at 400 m depth to be ca. 2000 years for the north and ca. 3000 years for the south dome. Pleistocene ice is expected in the bottom 200 and 300 m, respectively.

Properties of water masses, taxa abundance, and isotopic ratios of samples obtained around Svalbard archipelago

The feeding strategies of Calanus hyperboreus, C. glacialis, and C. finmarchicus were investigated in the high-Arctic Svalbard region (77-81 °N) in May, August, and December, including seasons with algal blooms, late- to post-bloom situations, and unproductive winter periods. Stable isotope and fatty acid trophic marker (FATM) techniques were employed together to assess trophic level (TL), carbon sources (phytoplankton vs. ice algae), and diet of the three Calanus species. In addition, population development, distribution, and nutritional state (i.e. storage lipids) were examined to estimate their population status at the time of sampling. In May and August, the vertical distribution of the three Calanus species usually coincided with the maximum algal biomass. Their stable isotope and fatty acid (FA) composition indicated that they all were essentially herbivores in May, when the algal biomass was highest. Their FA composition, however, revealed different food preferences. C. hyperboreus had high proportions of 18:4n3, suggesting that it fed mainly on Phaeocystis, whereas C. glacialis and C. finmarchicus had high proportions of 16:4n1, 16:1n7, and 20:5n3, suggesting diatoms as their major food source. Carbon sources (i.e. phytoplankton vs. ice algae) were not possible to determine solely from FATM techniques since ice-diatoms and pelagic-diatoms were characterised by the same FA. However, the enriched d13C values of C. glacialis and C. finmarchicus in May indicated that they fed both on pelagic- and ice-diatoms. Patterns in absolute FA and fatty alcohol composition revealed that diatoms were the most important food for C. hyperboreus and C. glacialis, followed by Phaeocystis, whereas diatoms, Phaeocystis and other small autotrophic flagellates were equally important food for C. finmarchicus. During periods of lower algal biomass, only C. glacialis exhibited evidence of significant dietary switch, with a TL indicative of omnivory (mean TL=2.4). Large spatial variability was observed in population development, distribution, and lipid store sizes in August. At the northernmost station at the southern margin of the Arctic Ocean, the three Calanus species had similarly low lipid stores as they had in May, suggesting that they ascended later in the year. In December, relatively lipid-rich specimens had TL similar to those during the peak productive season (TL~2.0), suggesting that they were hibernating and not feeding on the available refractory material available at that time of the year. In contrast, lipid-poor specimens in December had substantially high TL (TL=2.5), suggesting that they were active and possibly were feeding.

Age model, stable isotopes, major element proportions and endmember unmixing results from four western tropical Atlantic cores

We investigate changes in the delivery and oceanic transport of Amazon sediments related to terrestrial climate variations over the last 250 ka. We present high-resolution geochemical records from four marine sediment cores located between 5 and 12° N along the northern South American margin. The Amazon River is the sole source of terrigenous material for sites at 5 and 9° N, while the core at 12° N receives a mixture of Amazon and Orinoco detrital particles. Using an endmember unmixing model, we estimated the relative proportions of Amazon Andean material ("%-Andes", at 5 and 9° N) and of Amazon material ("%-Amazon", at 12° N) within the terrigenous fraction. The %-Andes and %-Amazon records exhibit significant precessional variations over the last 250 ka that are more pronounced during interglacials in comparison to glacial periods. High %-Andes values observed during periods of high austral summer insolation reflect the increased delivery of suspended sediments by Andean tributaries and enhanced Amazonian precipitation, in agreement with western Amazonian speleothem records. Increased Amazonian rainfall reflects the intensification of the South American monsoon in response to enhanced land-ocean thermal gradient and moisture convergence. However, low %-Amazon values obtained at 12° N during the same periods seem to contradict the increased delivery of Amazon sediments. We propose that reorganizations in surface ocean currents modulate the northwestward transport of Amazon material. In agreement with published records, the seasonal North Brazil Current retroflection is intensified (or prolonged in duration) during cold substages of the last 250 ka (which correspond to intervals of high DJF or low JJA insolation) and deflects eastward the Amazon sediment and freshwater plume.

Water chemistry, and isotopic ratios and fatty acids and alcohols in Calanus finmarchicus CV, norther Mid-Atlantic Ridge

Fatty acid and alcohol profiles and stable nitrogen and carbon isotope values, d15N and d13C, of Calanus finmarchicus CV were studied in June 2004 to estimate their trophic status along the northern Mid-Atlantic Ridge i.e. the Reykjanes Ridge (RR), extending from Iceland in the north to the productive region of the Sub-Polar Front (SPF) in the south. Two main groups of stations were defined in the study area based on fatty acid (FA) and fatty alcohol compositions, the stations in the RR area constituted one group and the stations in the frontal area constituted another. The sum of relative amounts of the dietary FAs was significantly higher in the RR area than in the frontal area. Conversely, the long-chained FAs, 20:1 and 22:1, were found in significantly lower relative amounts in the RR area than in the frontal area, thus indicating later ascent of the animals in the frontal area. Further support of this is provided by the fatty alcohols ratio 20:1/22:1 which differed significantly between the two areas. The d15N values were significantly higher in the frontal area compared to the RR area indicating higher trophic position and/or different pelagic-POM baseline in these areas.

Oxygen and carbon isotopic composition in Eocene and Oligocene planktonic and benthic foraminifera from DSDP sediments

Oxygen and carbon isotope ratios in Eocene and Oligocene planktonic and benthic foraminifera have been investigated from Atlantic, Indian, and Pacific Ocean locations. The major changes in Eocene-Oligocene benthic foraminiferal oxygen isotopes were enrichment of up to 1 per mil in 18O associated with the middle/late Eocene boundary and the Eocene/Oligocene boundary at locations which range from 1- to 4-km paleodepth. Although the synchronous Eocene-Oligocene 18O enrichment began in the latest Eocene, most of the change occurred in the earliest Oligocene. The earliest Oligocene enrichment in 18O is always larger in benthic foraminifera than in surface-dwelling planktonic foraminifera, a condition that indicates a combination of deep-water cooling and increased ice volume. Planktonic foraminiferal d18O does not increase across the middle/late Eocene boundary at our one site with the most complete record (Deep Sea Drilling Project Site 363, Walvis Ridge). This pattern suggests that benthic foraminiferal d18O increased 40 m.y. ago because of increased density of deep waters, probably as a result of cooling, although glaciation cannot be ruled out without more data. Stable isotope data are averaged for late Eocene and earliest Oligocene time intervals to evaluate paleoceanographic change. Average d18O of benthic foraminifera increased by 0.64 per mil from the late Eocene to the early Oligocene d18O maximum, whereas the average increase for planktonic foraminifera was 0.52 per mil. This similarity suggests that the Eocene/Oligocene boundary d18O increase was caused primarily by increased continental glaciation, coupled with deep sea cooling by as much as 2°C at some sites. Average d18O of surface-dwelling planktonic foraminifera from 14 upper Eocene and 17 lower Oligocene locations, when plotted versus paleo-latitude, reveals no change in the latitudinal d18O gradient. The Oligocene data are offset by ~0.45 per mil, also believed to reflect increased continental glaciation. At present, there are too few deep sea sequences from high latitude locations to resolve an increase in the oceanic temperature gradient from Eocene to Oligocene time using oxygen isotopes.

Stable carbon and oxygen isotope ratios of Late Miocene and Early Pliocene foraminifera from the Southwest Pacific

The Late Miocene-Early Pliocene paleoclimatic history has been evaluated for a deep drilled sediment sequence at Deep Sea Drilling Project Site 281 and a shallow water marine sediment sequence at Blind River, New Zealand, both of which lay within the Subantarctic water mass during the Late Miocene. A major, faunally determined, cooling event within the latest Miocene at Site 281 and Blind River coincides with oxygen isotopic changes in benthonic foraminiferal composition at DSDP Site 284 considered by Shackleton and Kennett (1975) to indicate a significant increase in Antarctic ice sheet volume. However, at Site 281 benthonic foraminiferal oxygen isotopic changes do not record such a large increase in Antarctic ice volume. It is possible that the critical interval is within an unsampled section (no recovery) in the latest Miocene. Two benthonic oxygen isotopic events in the Late Miocene (0.5 ? and 1 ? in the light direction) may be useful as time-stratigraphic markers. A permanent, negative, carbon isotopic shift at both Site 281 and Blind River allows precise correlations to be made between the two sections and to other sites in the Pacific region. Close interval sampling below the carbon shift at Site 281 revealed dramatic fluctuations in surface-water temperatures prior to a latest Miocene interval of refrigeration (Kapitean) and a strong pulse of dissolution between 6.6 and 6.2 +/- 0.1 m.y. which may be related to a fundamental geochemical change in the oceans at the time of the carbon shift (6.3-6.2 m.y.). No similar close interval sampling at Blind River was possible because of a lack of outcrop over the critical interval. Paleoclimatic histories from the two sections are very similar. Surface water temperatures and Antarctic ice-cap volume appear to have been relatively stable during the late Middle-early Late Miocene (early-late Tongaporutuan). By 6.4 m.y. cooler conditions prevailed at Site 281. Between 6.3 and 6.2 -+ 0.1 m.y. the carbon isotopic shift occurred followed, within 100,000 yr, by a distinct shallowing of water depths at Blind River. The earliest Pliocene (Opoitian) is marked by increasing surface-water temperatures.

Stable carbon and oxygen isotope record of planktonic and benthic foraminifera at ODP Site 111-677 in the Panama Basin

Oxygen and carbon isotope ratio measurements are presented for Globigerinoides ruber and for benthic species (mainly Uvigerina spp.) in the Pleistocene and uppermost Pliocene section of ODP Hole 677A in the Panama Basin. This provides the best available continuous Pleistocene stable isotope records from any location, fully justifying the recoring of DSDP Site 504. Oxygen isotope stage 22 (age about 0.85 Ma) was of similar magnitude to the most extensive glacials of the Brunhes and constitutes a logical base for the middle Pleistocene. Oxygen isotope stages as defined by Ruddiman et al. (1986, doi:10.1016/0012-821X(86)90024-5) and by Raymo et al. (1989, doi:10.1029/PA004i004p00413) back to stage 104 are recognized. Although the internationally agreed base of the Quaternary at or near stage 62 (about 1.6 Ma) is not marked by a major isotopic event, it does approximate the base of a regime characterized by highly regular 41,000-yr climate cycles. The records at Site 677 are ideal for time-series analyses and will permit a new attempt to develop a chronology for the early Pleistocene based on tuning to the orbital frequencies. The carbon isotope records also appear to contain considerable variance at orbital frequencies throughout the sequence analyzed.