936 resultados para Nitroprussiato de cobre


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Pós-graduação em Agronomia (Proteção de Plantas) - FCA

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Pós-graduação em Agronomia (Proteção de Plantas) - FCA

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Pós-graduação em Agronomia (Proteção de Plantas) - FCA

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Pós-graduação em Agronomia (Proteção de Plantas) - FCA

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Pós-graduação em Agronomia (Proteção de Plantas) - FCA

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Nitrogen (N) is the most required nutrient for corn plants and, in order to supply this demand in highly productive crops, mineral fertilizers are used, especially urea. The disadvantage of urea is the loss of N-NH3 to atmosphere. To reverse this situation, some technologies have been developed, such as nitrification and urease inhibitors, which are used as additives to urea. This work aimed at evaluating the agronomic efficiency of urea stabilized with urease and nitrification inhibitors applied to cover the 2013/2014 corn crop. We evaluated 11 nitrogen fertilizer applied in coverage: urea + PA (41.6% N, 3% Cu); urea + PA (41.6% N, 1.5% Cu); urea + PA (41.6% N, 3% Zn); urea + PA (41.6% N, 1.5% Zn); urea + PA (41.6% N, 0.34% Cu, 0.94% B); urea + PA (41.6% N, 0.25% Cu, 0.68% B); urea + PA (41.6% N); urea (44.3% N, 0.15% Cu, 0.4% B); urea (43% N, 0.1% Cu, 0.3% B, 0.05% Mo); pearled urea (46% N); urea + 0,8% DMPP (45% N) and the control, which did not receive nitrogen topdressing. The evaluations were: Nitrogen losses through volatilization, content and accumulation of N, boron (B), copper (Cu) and zinc (Zn) to the dry matter of aerial parts, grains, and in straw and grain productivity. Fertilizers stabilized with urease and nitrification inhibitors did not reduce the volatilization of ammonia volatilization, when compared to pearled urea. Urea with 0.8% of DMPP nitrification inhibitor (3,4-dimethylpyrazole phosphate) provided higher loss by volatilization, lower productivity and agronomic efficiency compared to pearled urea. The coating of urea with Cu, B and Zn did not increase the accumulation of these nutrients in grains and MSPA plants. The use of fertilizers stabilized and coated with micronutrients did not increase the productivity and agronomic efficiency compared to conventional urea.

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The development of an electroanalytical method for simultaneous determination of copper and lead ions in sugar cane spirit (cachaça) using carbon paste electrode modified with ascorbic acid and carbon nanotubes (CPE-AaCNT) is described. Squarewave voltammetry (SWV) with anodic stripping was employed, and this technique was optimized with respect to the following parameters: frequency (50 Hz), amplitude (100 mV) and scan increment (9 mV). The analytical curves were linear in the range from 0.0900 to 7.00 mg L - 1 for lead and copper. The limits of detection were 48.5 and 23.9 µg L - 1 for lead and copper, respectively. The developed method was applied to the simultaneous determination of copper and lead in five commercial samples of sugar cane spirit. The results were in good agreement with those obtained by F AAS/GF AAS (flame atomic absorption spectrometry/graphite furnace atomic absorption spectrometry) and showed that CPE-AaCNT can be successfully employed in the simultaneous determination of these metals in real sugar cane spirit samples.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)