803 resultados para Gestão de resíduos sólidos


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Pós-graduação em Geociências e Meio Ambiente - IGCE

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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In this work, magnetic photocatalysts were synthesized containing differents levels of TiO2 (40, 60 e 80%) supported at the supporter of C/LV, forming the photocatalysts 40, 60, 80Ti/C/LV, using tar pitch as carbon (C) source and red mud (LV) as iron source. The prepared magnetic photocatalysts and TiO2 were used to degrade the Remazol Black textile dye (PR5) and the organic material present in samples of a textile dye effluent. The characterization of photocatalysts by Raman, X-Ray Diffraction, Transmission Electron Micoscope and Scanning, Energy Dispersive X-ray Spectrometry, Termogravimetry and Elemental Analysis, confirms the presence of carbon and magnetite in support C/LV and the presence of TiO2 in prepared photocatalysts. The photocatalytic reactions with TiO2 were analyzed by different experimental conditions, such as: mass of TiO2 (30-240 mg), solution pH (2-10), light intensity (0.871 and 1.20 mWcm-2), type of radiation (UV and sunlight-1.420 mWcm-2), radiation incidence area (44.2 to 143.1 cm2) and dissolved oxygen (OD, 1.9 and 7.6 mg L- 1). Results showed that reactions with the following conditions: 220 mg of TiO2, pH 10, solar radiation, 7.6 mg L-1 of OD and an incidence area of radiation of 143.1 cm2 showed the best results for degradation of PR5 dye. Photocatalytic reactions with magnetic photocatalysts for degrading PR5 shows that efficiency increases with TiO2 content in the C/LV support, where, above 60% of TiO2, there was not significant increase in reaction velocity. In addition, solar radiation has proved to be advantageous for photocatalytic reactions. In order to verify the presence of a non-magnetic fraction in the photocatalyst 60Ti/C/LV0, magnetic separation was proceeded. The characterizations of the magnetic (FM) and nonmagnetic (NMF) fraction confirmed that about 25% of TiO2 did not fixed in 60Ti/C/LV photocatalyst. Results of photocatalytic reactions with FM and FNM showed that both phases have photocatalytic activity for degradation of PR5. The reactions executed for the degradation of organic matter present in the actual sample of textile effluent showed that TiO2 and magnetic photocatalyst 60Ti/C/ LV have better results for color removal (85 to 35%), soluble solids ( 11 and 3%), DQO (90 and 86%) and turbidity (94 and 11%) than the treatment done by the textile industry. Sedimentation kinetics tests in presence of a magnet showed that photocatalysts are separated faster from aqueous environment than pure TiO2. Obtained results showed that magnetic photocatalysts have excellent photocatalytic activity and can be separated from the reaction environment on a simple and quick way when a magnetic field is applied.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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O presente consiste no estudo de caracterização e proposta de tratamento de lixiviados de resíduos de madeira produzidos em laboratório. Lixiviados de madeira ou chorumes de madeira são originados quando resíduos de madeira, decorrente do processo de transformação, são dispostos de forma inadequada, no ambiente, possibilitando a interação destes com água, geralmente de precipitações climáticas, o que resulta na geração de líquido de cor escura que pode conter uma série de substâncias com potencial impacto negativo sobre os ambientes aquáticos. O efluente estudado foi gerado em laboratório por meio de dois experimentos distintos. No Experimento A, em frascos de polietileno, foram misturadas água e pó-de-serra, na proporção 9:1, permanecendo em contato, em sistema aberto e temperatura ambiente, por 90 dias. Nos tempos de 0, 1, 5, 10, 20, 30, 45, 60, 75, 80 e 90 dias, a solução foi filtrada e levada ao laboratório para análise. No Experimento B, armazenou-se em um recipiente plástico aproximadamente 5 Kg de resíduos de madeira, onde na parte inferior foi adaptado um dreno para coleta de efluente. Este sistema ficou exposto ao sol e a precipitações climáticas, de tal forma a simular as condições reais de geração de lixiviados de uma pilha de resíduos de madeira em caso real. Em ambos experimentos (A e B) observou-se a geração de um líquido de cor âmbar claro a negro, com odor forte característico, levemente ácido @H 5,53 — 6,97), alta demanda de oxigênio (DBO 17 — 310 mg.L-1; DQO 857 — 3.161 mg.L-1 e OD 0,63 — 5,56 mg.L-1), altas cargas de matéria orgânica (CT 170,93 — 425,19 mg.L-1, COT 167,66 — 415,66 mg.L-1 e CIT 2,22 — 34,05 mg.L-1), grande concentração de sólidos (SS 10 — 23 mL.L-1; STS 463 — 1.330 mg.L-1; STD 31 — 640 mg.L-1) e turbidez (10,0 — 638,5 UT). Devido a estas características foi proposto um tratamento fisico-químico para o chorume produzido, por meio da combinação dos processos de coagulação/floculação e oxidação com permanganato de potássio, que resultou, respectivamente, na redução dos níveis de DQO 20,95% e 88,53%, cor 43,31% e 98,18%, turbidez 40,45% e 98,16%, STS 65,71% e 100%, por processo. A eficiência global do tratamento proposto foi de 90,93% nos valores de DQO, 98,97% nos valores de cor verdadeira, 98,90% nos valores de turbidez e 100,00% nos valores de STS.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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The leather footwear industry is an important sector in the Brazilian economy. The tannery industry accounted for $ 2.05 billion to exports in 2011, which represents a contribution of 6.86% to the Brazilian balance of trade. However, it is a highly polluting industry generating highly toxic and hazardous waste. Therefore, it is extremely important to search for environmental management actions that allow a cleaner production and waste recycling to prevent its discharge into the environment resulting in the deterioration of nature and quality of human life. Thus, based on a literature review and exploratory research, this study consisted of an analysis of some environmental management actions adopted by the leather industry in Franca - SP verifying if the industries have certifications or follow standards that characterize a responsible environmental management. This study is justified by the fact that tanneries and footwear industries produce highly hazardous waste, and therefore environmental actions are necessary to treat the waste effectively in order to minimize its environmental impacts. The literature review and empirical research conducted demonstrated the development of new techniques and technologies aiming at mitigating the impacts of leather waste in the environment. These actions are crucial for companies to remain competitive and focused on sustainability in this rapidly growing market.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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The expansion of urban in medium-sized citie, increase the importance of action planning and management of natural resources, among which water is the most important. Such action should include the integration of physical and man-made elements involved. In this context, it becomesimportant for watershed analysis and the use of geotecnologies. Thus, the objective was to demonstrate the contribution of the geo, as a tool for managing a river basin, allowing the integration of physical data and the analysis of anthropogenic environmental scenarios in urban areas. The area chosen, the basin of the Wenzel, is located in Rio Claro / SP, a city whose urbanization process has been intense and continuous. Thematic maps were generated from the physical environment: soil, slope and geological, as well as maps of land use. With regard to land use maps, these were drawn from the visual interpretation of material aerophotogrammetric, considering the years 1995 and 2010, performing an evolutionary analysis. It was observed that the area presents small variation in the physical and structural aspects, with lithological and geomorphological formation favoring the occurrence of floods, erosion and siltation. These processes are accelerated by the forms of land use, with intense urbanization during the period between 1995 and 2010, and poor preservation of permanent preservation areasand. In the floodplain areas there is a high waste disposal is the most notable environmental problem

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This project aimed to analyze the feasibility of the methane yield associated to the anaerobic digestion of brewery residues, checking whether the energetic balance of the system is favorable. The methane yield efficiency was calculated for the parameters of two papers that treated solids with a particle-size <1mm. Theses solids are not degraded in conventional treatment systems. Calculations were based in the reactions of anaerobic degradation of the macromolecules that compose brewery residues, considering the theoretical production and the effective production of methane. The results were 50.44% and 52.86%. Regarding to the energy balance of the anaerobic treatment, we noted the high influence of the selection and operating regime of electrical equipment over the potential energy. The best situation, in which the energetic self-sufficiency was reached, was observed when using the mixer under an intermittent regime (1min/h), without employing the heating recirculator, for the maximum organic loading of 4.0 gVS/L.day (days 248-258). In this case, the system would generate an amount of energy equal to 0.0356 kWh/day, able to overcome the energy required by the equipment in about 6.5 times. Moreover, we also noted the interference of the application of different solid loadings in the reactors, once the application of the higher organic load generated 5 times more energy than the application of the smaller one