Overcoming performance and convergence issues of discrete transform based modeling of crosslinking classical and reversible deactivated radical polymerizations

Population balances of polymer species in terms 'of discrete transforms with respect to counts of groups lead to tractable first order partial differential equations when ali rate constants are independent of chain length and loop formation is negligible [l]. Average molecular weights in the absence ofgelation are long known to be readily found through integration of an initial value problem. The extension to size distribution prediction is also feasible, but its performance is often lower to the one provided by methods based upon real chain length domain [2]. Moreover, the absence ofagood starting procedure and a higher numerical sensitivity hás decisively impaired its application to non-linear reversibly deactivated polymerizations, namely NMRP [3].

Revue GRASPE/GRASPE Review. Groupe de Réflexion sur l’avenir du Service Public Européen. Reflection Group on the Future of the European Civil Service Cahier n° 23 Juin 2014 GRASPE Cahier No 23, June,2014

No abstract.

Future of the EU27: What to expect from this summer’s period of reflection. CEPS Commentary, 18 July 2016

As the UK’s brutal political fallout of Brexit continues to astound the world, leaders in the other member states are wrestling with the EU’s new reality. They deemed it too early to draw conclusions at the June European Council. Instead, the heads of state and government declared a period of political reflection on the future of an EU with 27 member states. They will meet again informally on September 16th in Bratislava. The question is: What impetus can they give to reforms to remain united and deal with the challenges of the 21st century?