A 2-kW COIL with a square pipe-array JSOG and nitrogen buffer gas

A 2-kW-class chemical oxygen-iodine laser (COIL) using nitrogen buffer gas has been developed and tested since industrial applications of COIL devices will require the use of nitrogen as the buffer gas. The laser, with a gain length of 11.7 cm, is energized by a square pipe-array jet-type singlet oxygen generator (SPJSOG) and employs a nozzle bank with a designed Mach number of 2.5. The SPJSOG has advantages over the traditional plate-type JSOG in that it has less requirements on basic hydrogen peroxide (BHP) pump, and more important, it has much better operational stability. The SPJSOG without a cold trap and a gas-liquid separator could provide reliable operations for a total gas flow rate up to 450 mmol/s and with a low liquid driving pressure of around 0.7 atm or even lower. The nozzle bank was specially designed for a COIL using nitrogen as the buffer gas. The cavity was designed for a Mach number of 2.5, in order to provide a gas speed and static temperature in the cavity similar to that for a traditional COIL with helium buffer gas and a Mach 2 nozzle. An output power of 2.6 kW was obtained for a chlorine flow rate of 140 mmol/s, corresponding to a chemical efficiency of 20.4%. When the chlorine flow rate was reduced to 115 mmol/s, a higher chemical efficiency of 22.7% was attained. Measurements showed that the SPJSOG during normal operation could provide a singlet oxygen yield Y greater than or equal to 55%, a chlorine utilization U greater than or equal to 85%, and a relative water vapor concentration w = [H2O]/([O-2] + [Cl-2]) less than or equal to 0.1.

国产12种苔藓植物的染色体数目

报道了中国产 1 2种苔藓植物染色体数目 ,结果为 :壶苞苔Blasiapusilla ,n =9;艳绿光苔Cy athodiumsmaragdinum ,n =9;紫背苔Plagiochasmarupestre,n =9;石地钱Rebouliahemisphaerica ,n =9;宽片叶苔Riccardialatifrons,n =1 0 ;尖叶美喙藓Eurhynchiumeustegium ,n =1 1 ;东亚沼羽藓Helodiumsachali nense,n =1 1 ;白齿藓Leucodonsciuroides,n =1 1 ;齿边细枝藓Lindbergiaserrulatus,n =1 1 ;疣小金发藓Pogonatumurnigerum ,n =7;台湾拟金发藓Polytrichastrumformosum ,n =7;金发藓Polytrichumcommune,n=7。其中艳绿光苔、齿边细枝藓和东亚沼羽藓的染色体数目为首次报道。

科尔沁退化草地改良的工程措施及效果

针对草地退化的实际问题,以科尔沁乌兰敖都退化草地为例,采用围栏封育、深翻松土、补播豆科牧草等工程措施对该退化草地进行工程改良,并评价改良措施对土壤性质及草地植被生物多样性的影响。重度退化草地土壤有机碳和全氮含量较低且随土层深度增加而明显降低,土壤pH增高,10～30cm土层深度可溶性盐积累；与重度草地相比,退化改良3年草地土壤有机碳和全氮含量显著提高(P＜0.01),土壤pH降低,其中10～30cm深度土层的差异达到显著水平(P＜0.05)；10～30cm深度电导率呈现出降低的趋势。经过改良,可以缓解土壤盐碱化,提高土壤肥力及物种多样性,达到提高草地质量、改善生态环境的效果。

我国沿海地区水污染区域治理探讨

本文分析了我国当前水污染区域治理的难度，沿海地区水污染的主要问题，探讨了污染区域治理的基本原则，提出了水污染治理的重点区域和水污染区域治理的主要途径，并以浑河流域沈阳地区２０００年水污染物总量控制为例，概述总量控制方法和目标

银杏种子生长特性及其生理变化的研究

从纵径、横径、体积、重量等方面分析了银杏种子的生长特性及其生长过程中水分、糖类物质、脂肪酸、氨基酸的生理变化 .结果表明 ,银杏种子的生长过程曲线为典型的单“S”型 ,种子纵径、横径、体积、重量、绝对含水量随生长过程呈“S”形变化 .各种生理物质含量随种子生长过程呈规律性变化 ,且各有其特点 .其中在种子生长后期糖类物质总量表现出上升的趋势 ,表明它们是种子中主要的营养储存物质 .成熟种子含淀粉 8.4%、葡萄糖 6.7%、果糖 4.2 %、多糖 0 .0 2 %、二糖 0 .0 1% ;含肉豆蔻酸 10 .6%、棕榈烯酸 4.1%、亚麻酸 2 .4%、硬脂酸1.9%、油酸 1.1%、亚油酸 0 .4% .银杏种子富含 15种氨基酸 ,成熟种子中总含量为 1.5 6g·10 0 g-1FW ,其中以赖氨酸、天门冬氨酸、丙氨酸、精氨酸、组氨酸、谷氨酸、异亮氨酸的含量较高 ,它们的含量依次为 0 .2 87%、0 .163 %、0 .13 6%、0 .13 3 %、0 .12 3 %、0 .115 %、0 .0 95 % .

汶川5.12大地震地表次生灾害评价与分析

针对汶川5.12大地震,对由地震引起的地质次生灾害发生的坡度和坡向进行了统计,分析了地表破坏的易发坡度、坡向及其与震中的关系等。另外,分别以不同震中距为缓冲区、以平行中央断裂带的各级缓冲区、以等烈度区为缓冲区对地震引起的地表破坏的空间分布以及发生地表破坏的坡度在各级缓冲区中的变化进行了分析。结果表明:①地震引发的滑坡及滑坡群共5093个,总面积大约958km2;②在30°～44°坡度区间地表破坏发生的数量最大,42°坡度为地表破坏发生概率的拐点。主要的地表破坏发生在迎着地震波传播的坡向上;③随着震中距的增

Microstructure and mechanical properties of Mg-12.3Zn-5.8Y-1.4Al alloy

Microstructure and mechanical properties of as-cast and heat-treated Mg-12.3Zn-5.8Y-1.4Al (ZYA1261) alloy were investigated. The phase compositions of the as-cast alloy are alpha-Mg, Mg3YZn6 (I-phase), Mg(3)y(2)Zn(3) (W-phase), Mg12YZn (Z-phase), Mg24Y5, MgZn and a small quantity of Al-containing phase.

Assembly of 12-tungstosilicic acid and 4-aminobenzo-15-crown-5 ether based on the electrostatic attraction through bridging of oxonium ions on different substrates

Based on the electrostatic attraction Keggin-type polyoxometalate H4SiW12O40 (SiW12) and small molecule 4-aminobenzo-15-crown-5 ether (4-AB15C5) were alternately deposited on poly (allylamine hydrochloride) (PAH)-derived indium tin oxide (ITO) substrate through a layer-by-layer (LBL) self-assembly, forming a supramolecular multilayer film (film-A). SiW12 was also deposited on a glassy carbon electrode (GCE) derived by 4-AB15C5 via covalent bonding in 0.1 M NaCl aqueous solution and formed a composite monolayer film (film-B). UV-vis absorption spectroscopy, X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared (FTIR) spectroscopy measurements demonstrated that the interactions between SiW12 and 4-AB15C5 in both two film electrodes were the same and caused by the bridging action of oxonium ions. But, the nanostructure in the two film electrodes was different. 4-AB15C5 in film-A was oriented horizontally to ITO substrate, however, that in film-B was oriented vertically to GCE. Namely film-A corresponded to a layer structure, and film-B corresponded to an intercalation structure.

Morphology evolutions of organically modified montmorillonite/polyamide 12 nanocomposites

Organically modified montmorillonites (OMMTs) by octadecylammonium chloride with two adsorption levels were dispersed in polyamide 12 (PA12) matrices with two molecular weights for different melt mixing times in order to investigate morphology evolutions and factors influencing fabrication of PA12 nanocomposites. Different adsorption levels of the modifier in the OMMTs provide different environments for diffusion of polymer chains and different attractions between MMT layers. Wide-angle X-ray diffraction (WAXD), transmission electron microscope (TEM) and gas permeability were used to characterize morphologies of the nanocomposites. Both OMMTs can be exfoliated in the PA12 matrix with higher molecular weight, but only OMMT with lower adsorption level can be exfoliated in the PA12 matrix with lower molecular weight. It was attributed to the differences in the levels of shear stress and molecular diffusion in the nanocomposites. The exfoliation of OMMT platelets results from a combination of molecular diffusion and shear. After intercalation of PA12 into interlayer of OMMT in the initial period of mixing, further dispersion of OMMTs in PA12 matrices is controlled by a slippage process of MMT layers during fabricating PA12 nanocomposites with exfoliated structure.

Chemical effects of cationic surfactant and anionic surfactant used in organically modified montmorillonites on degradation and fire retardancy of polyamide 12 nanocomposites

Three kinds of organically modified Na+-montmorillonites (OMMTs), including two kinds of octadecylammonium modified montmorillonite with different contents of octadecylammonium and a kind of sodium dodecylsulfonate (SDSo) modified montmorillonite, were used to prepare polyamide 12 (PA12)/OMMT nanocomposites. Effects of the modifiers on degradation and fire retardancy of PA12/OMMT nanocomposites were investigated. Acid sites formed in cationic surfactant modified MMT via Hoffman decomposition could accelerate degradation of PA12 at high temperature. However, catalytic effect of the acid sites on carbonization of the degradation products promoted char barrier formation, which reduced heat release rate (HRR). Higher content of cationic surfactant in OMMT is beneficial to fire retardancy of PA12 nanocomposites and the dispersion states of OMMT have assistant effects. In contrast, Na+-montmorillonite (Na-MMT) and anionic surfactant modified MMT (a-MMT) could not form acid sites on the MMT layers; in this case, fire retardancy of PA12/Na-MMT appears to have no improvement and PA12/a-MMT appears to have limited improvement.

Surface-appropriate lipophobicity - Application in isobutene oligomerization over Teflon-modified silica-supported 12-silicotungstic acid

A series of silica-supported 12-silicotungstic acid catalysts (H4SiW12O40, abbreviated as HSiW), modified with various loadings of Teflon (HSiW/SiO2-Teflon), were prepared by an impregnation method. The surface properties of the catalysts were studied by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), BET, infrared (IR) spectroscopy, NH3-TPD and the Drop Shape Analysis (DSA). SEM results combined with energy-dispersive X-ray (EDX) measurements of HSiW/SiO2-Teflon revealed that F-compound (Teflon) is effectively coated on the catalyst surface. The contact angles for water and oil of 50 wt% HSiW/SiO2 and HSiW/SiO2-Teflon indicate that HSiW/SiO2-Teflon catalyst enhances not only the surface hydrophobicity but also the surface lipophobicity by means of the addition of Teflon. Silica-supported 12-silicotungstic acid modified with Teflon exhibits higher C-8(=) selectivity and longer lifetime than that of silica-supported 12-silicotungstic acid in isobutene oligomerization. Thus, surface-appropriate lipophobicity of catalysts may be effective for decreasing the interaction between coke precursors and the catalyst surface and for removing deposited coke more easily.

Reactive blending of modified polypropylene and polyamide 12: Effects of compatibilizer content on crystallization and blend morphology

The crystallization behavior and morphology of nonreactive and reactive melt-mixed blends of polypropylene (PP) and polyamide (PA12; as the dispersed phase) were investigated. It Was found that the crystallization behavior and the size of the PA12 particles were dependent on the content of the compatibilizer (maleic anhydride-modified polypropylene) because an in situ reaction occurred between the maleic anhydride groups of the compatibilizer and the amide end groups of PA12. When the amount of compatibilizer was more than 4%, the PA12 did not crystallize at temperatures typical for bulk crystallization. These finely dispersed PA12 particles crystallized co-incidently with the 1313 phase. The changes in domain size with compatibilizer content were consistent with Wu's theory. These investigations showed that crystallization of the dispersed phase Could not be explained solely by the size of the dispersion. The interfacial tension between the polymeric components in the blends may yield information on the fractionation of crystallization.

镧六方铁氧体Ba_(1-x)La_xFe_(12)O_(19)的电磁性能与吸波特性

研究了掺稀土六方铁氧体Ba1-xLaxFe12O19的合成条件,测试了其结构、形貌、电磁性能与吸波特性.结果表明,稀土离子La3+的加入,降低了钡铁氧体的磁化强度、矫顽力和顽磁性,其磁特性接近软磁铁氧体材料;在1.65～2.95GHz的频率范围内,具有良好的吸波性能.