Planktonic foraminifera stratigraphy and datums of ODP Site 184-1143 and Hole 184-1146A, South China Sea

The biostratigraphy of Miocene-age sediment samples recovered from Ocean Drilling Program Sites 1143 and 1146, South China Sea, is presented. The preservation of the planktonic foraminifers recovered from both sites varies widely, from poor to very good. The volume of biogenic sediment in the >63-µm size fraction also varies considerably, with many samples being dominated by mud. In comparison to shipboard biostratigraphy, based on core catcher analyses with a depth resolution of ~10 m, we analyzed samples from the two stratigraphic columns every 2-3 m (~45- to 93-k.y. resolution). The placement of planktonic foraminifer zonal boundaries was made at a resolution of ~1.5 m at Site 1146 and ~3.0 m at Site 1143. The higher resolution has resulted in significant changes in biostratigraphic zonal boundary locations compared to shipboard results. For the time interval of 5.54-10.49 Ma, the changes in zonation reveal similar age-depth models at both sites, with three segments of changing sedimentation rate through the upper Miocene, though the differences in sedimentation rates at Site 1146 are subtler than those at Site 1143. The boundary between lithologic Units II and III at Site 1146 corresponds to a sharp change in sedimentation rate (58 to 21 m/m.y.) at 15.1 Ma (the first occurrence of Orbulina suturalis). At this site, the interval from 16.4 to 15.1 Ma is characterized by very high mass accumulation rates in the noncarbonate fraction. Above this interval the carbonate fraction becomes increasingly important in the sediment flux to the South China Sea. At Site 1143, sedimentation rates increase from 8 to 99 m/m.y. at 8.6 Ma. This corresponds to a dramatic increase in both carbonate and noncarbonate mass accumulation rates at the site, but no change in lithology.

Range charts of stratigraphically important radiolarian species in sediments of ODP Leg 165 sites

The Paleogene sequences from three sites in the Caribbean were examined for radiolarians. In general, samples are highly lithified, requiring lengthy and repetitive cleaning procedures, and the assemblages are usually fragmented and/or partially dissolved. Both abundances and preservation of the assemblages vary considerably from site to site and within a single site; even within a single sample more than one degree of preservation was observed. It was possible, however, to construct at least partial stratigraphies for each of the three sites. Because the abundance of radiolarians is high even in extremely poorly preserved assemblages, we conclude that the differences in biogenic silica preservation are the result of postdepositional processes and not productivity. In both Sites 999 and 1001, near the Paleocene/Eocene boundary (Bekoma bidartensis Zone [RP7]), there is a short interval in which the abundance and preservation state of the radiolarians improves relative to overlying and underlying assemblages. In each case the intervals corresponds to the level, identified by calcareous microfossils, as representing changes in paleoceanographic conditions associated with the late Paleocene thermal maximum.

Isotopic survey of diagenetic carbonates, at DSDP Leg 63 Holes

Authigenic carbonates, principally calcium-rich dolomites, with extremely variable isotopic compositions were recovered in organic-rich marine sediments during Leg 63 drilling off southern California and Baja California. These carbonates occur as thin layers in fine-grained, diatomaceous sediments and siliceous rocks, mostly deposited during the Neogene. A combination of textural, geochemical, and isotopic evidence indicates these dolomites formed as cements and precipitates in shallow subsurface zones of high alkalinity spawned by abundant CO2 and methane production during progressive microbial decay of organic matter. Depths and approximate temperatures of formation estimated from oxygen isotopes are 87 to 658 meters and 10°C to 50°C, respectively. Within any sedimentary section, dolomites may form simultaneously at several depths or at different times within the same interval. Highly variable carbon isotopes (-30 to +16 per mil) reflect the isotopic reservoir in which the carbonates formed. Oxidation of organic matter through microbial reduction of sulfate at shallow depths favors light-carbon carbonates such as those at Sites 468 and 471; heavy-carbon carbonates at Site 467 most likely formed below this zone where HC**12O3**- is preferentially removed by reduction of CO2 to methane during methanogenesis. An important controlling factor is the sedimentation rate, which dictates both the preservation of organic matter on the sea floor and depth distribution of subsurface zones of organic-matter decay.

Occurrence and estimated abundance of planktonic foraminifers at DSDP Leg 85 holes

Tropical planktonic foraminifers occur throughout the sequences at all sites of Leg 85, and the standard planktonic foraminiferal zonation of Blow (1969) is applicable to most of the recovered sequences. However, the abundance and state of preservation of foraminifers decline markedly in certain intervals because of the effects of dissolution. Although siliceous microfossils studied on this leg indicate recovery of nearly complete records for the Pleistocene to Oligocene interval, the planktonic foraminiferal biostratigraphy is interrupted by strongly dissolved sections at all sites. Particularly, faunas assignable to Zone N7 (early Miocene) and Zone N15-16 (early late Miocene) are almost totally unrecognizable throughout the eastern equatorial Pacific. Well-preserved and diverse planktonic foraminifers occur in the lower middle Miocene, where the evolutionary developments of Orbulina universa d'Orbigny and Globorotalia fohsi Cushman and Ellisor are well represented. The Orbulina first appearance datum is observed to be nearly coincident with the last occurrence level of the diatom Annellus californicus Tempère, thus .establishing an age of 15 Ma for this datum by using the paleomagnetic calibration of the diatom datum. Moderately well-preserved late Eocene planktonic foraminifers occur in the carbonate sediments immediately overlying the basalt basement at Sites 573 and 574. The Eocene-Oligocene faunal transition, however, is masked at both sites by an intercalation of metalliferous layers containing no planktonic foraminifers.

Phosphate d18O pore-water profiles of sediment core GeoB11807-2 and GeoB11804-4

Phosphorus cycling in the ocean is influenced by biological and geochemical processes that are reflected in the oxygen isotope signature of dissolved inorganic phosphate (Pi). Extending the Pi oxygen isotope record from the water column into the seabed is difficult due to low Pi concentrations and small amounts of marine porewaters available for analysis. We obtained porewater profiles of Pi oxygen isotopes using a refined protocol based on the original micro-extraction designed by Colman (2002). This refined and customized method allows the conversion of ultra-low quantities (0.5 - 1 µmol) of porewater Pi to silver phosphate (Ag3PO4) for routine analysis by mass spectrometry. A combination of magnesium hydroxide co-precipitation with ion exchange resin treatment steps is used to remove dissolved organic matter, anions, and cations from the sample before precipitating Ag3PO4. Samples as low as 200 µg were analyzed in a continuous flow isotope ratio mass spectrometer setup. Tests with external and laboratory internal standards validated the preservation of the original phosphate oxygen isotope signature (d18OP) during micro extraction. Porewater data on d18OP has been obtained from two sediment cores of the Moroccan margin. The d18OP values are in a range of +19.49 to +27.30 per mill. We apply a simple isotope mass balance model to disentangle processes contributing to benthic P cycling and find evidence for Pi regeneration outbalancing microbial demand in the upper sediment layers. This highlights the great potential of using d18OP to study microbial processes in the subseafloor and at the sediment water interface.

Magnetostratigraphic synthesis of ODP Leg 123 sites

During ODP Leg 123, Sites 765 and 766 were drilled to examine the tectonic evolution, sedimentary history, and paleoceanography of the Argo Abyssal Plain and lower Exmouth Plateau. At each site, the quality of magnetostratigraphic and biostratigraphic records varies because of complicating factors, such as the predominance of turbidites, the presence of condensed horizons, or deposition beneath the CCD. Based primarily on the presence of nannofossils, the base of the sedimentary section at Site 765 was dated as Tithonian. A complete Cretaceous sequence was recovered at this site, although the sedimentation rate varies markedly through the section. The Cretaceous/Tertiary boundary is represented by a condensed horizon. The condensed Cenozoic sequence at Site 765 extends from the upper Paleocene to the lower Miocene. A dramatic increase in sedimentation rate was observed in the lower Miocene, and a 480-m-thick Neogene section is present. The Neogene section is continuous, except for a minor hiatus in the lower Pliocene. The base of the sedimentary section at Site 766 is Valanginian, in agreement with the site's position on marine magnetic anomaly Mil. Valanginian to Barremian sediments are terrigenous, with variable preservation of microfossils, and younger sediments are pelagic, with abundant well-preserved microfossils. Sedimentation rate is highest in the Lower Cretaceous and decreases continually upsection. Upper Cenozoic sediments are condensed, with several hiatuses.

Silt grain-size analysis of ODP holes from the western equatorial Atlantic

Grain-size records of the terrigenous and calcareous silt fraction, preservation of planktic foraminifera, and benthic foraminiferal stable-isotope data (delta13C, delta18O values of C. wuellerstorfi) at ODP Site 927 on the Ceará Rise (5°27.7'N, 44°28.8'W), are used to reconstruct variations in the history of bottom current strength, ventilation, and carbonate corrosiveness of deep waters during the time interval from 0.8 to 0.3 Ma. Glacial periods are characterized by generally smaller mean sizes of the terrigenous sortable silt fraction (mean(SS)), lower delta13C values, and poorer preservation of planktic foraminifera compared to interglacials. This indicates lower bottom current speeds, larger nutrient contents and more corrosive deep water. By contrast, larger mean(SS) sizes, higher delta13C values, and well preserved planktic foraminifera indicate strong circulation and a well ventilated deep-water mass during interglacials. The observed changes are most likely related to the weakening and strengthening of circulation of Lower North Atlantic Deep Water (LNADW). Cross-spectral analysis between the mean(SS) and benthic delta18O records reveals that minima in mean(SS) occur about 7.6 k.y. after the maximum in ice volume. This indicates a considerable lag time between ice-shield induced changes in LNADW production and subsequent changes in the velocity of LNADW flow in the western equatorial Atlantic. Striking changes in bottom current speed occur regularly during glacial to interglacial transitions. Extremely fine mean(SS) minima point to an almost complete shutdown of bottom current vigor in response to a cessation of LNADW production caused by an enhanced melt water release during the initial phases of deglaciation. However, each of the fine minima extremes is followed by a rapid shift to very high mean(SS) values that indicate strong bottom currents, and hence, vigorous LNADW flow during the early interglacials. After the onset of glacial Stage 12, generally poorer carbonate preservation and higher variability is registered. This coincides with a global decrease in carbonate preservation during the mid-Brunhes (mid-Brunhes dissolution event). Detailed grain-size analysis of the calcareous fine fraction (<63 µm) revealed a considerable reduction of particles in the fraction from 7 to 63 µm during periods of enhanced dissolution. This indicates a preferential dissolution of larger planktic foraminiferal fragments which leads to an enrichment of coccoliths in the calcareous fine fraction.

Planktonic foraminifers from Oligocene to Pleistocene sediments of DSDP Leg 92 sites

Leg 92 of the Deep Sea Drilling Project cored sediments containing calcareous microfossils at six sites along 19°S latitude in the South Pacific Ocean. Shipboard examination of these sediments revealed planktonic foraminifers of uppermost Oligocene through Pleistocene age that were identified and assigned to biostratigraphic zones according to the tropical zonation scheme of Blow (1969). Preservation of planktonic foraminifers in the sites from Leg 92 has been affected by the position of each site with respect to the lysocline and calcium carbonate compensation depth (CCD) at the time of deposition, depth of burial, and sediment accumulation rate (rate of burial). An additional factor may also be important, especially in the sediments deposited immediately above basement. Evidence of poor preservation in basal sediments of Holes 600C and 601, which have always been shallower than both the lysocline and the CCD, suggests that hydrothermal solutions circulating within young oceanic crust may penetrate the overlying sediments and affect the preservation of calcareous microfossils deposited there.

Radiolarians of the Celebes Sea

Two sites were drilled in the Celebes Sea as part of Ocean Drilling Program Leg 124; Site 767 and Site 770. Radiolarians are preserved in Paleogene pelagic claystones with minor occurrences in certain Neogene successions. The brown clays that immediately overlie basalt at both sites contain radiolarians of the late middle Eocene Podocyrtis chalara Zone. Late Eocene radiolarians are not found, due to dissolution and probable hiatus. The Oligocene is represented by the Theocyrtis tuberosa and Dorcadospyris ateuchus Zones. Oligocene sediments are strongly dominated by abundant and diverse radiolarians of the TristylospyrislDorcadospyris lineage. Preservation of Paleogene radiolarian assemblages ranges from good to very poor. Late Miocene radiolarians of the Didymocyrtis antepenultima Zone are found only in Site 770. Other Neogene sediments are barren of radiolarian remains, with the exception of latest Pleistocene and Holocene sediments.

Pliocene to Pleistocene calcium carbonate and organic carbon record of ODP Hole 117-722B

Site 722 provides high resolution records of percent CaCO3, magnetic susceptibility, d18O, organic carbon, and coarse fraction for the past 3.4 m.y. from the crest of the Owen Ridge, northwestern Arabian Sea. Within this time interval, most of the carbonate percent variations can be attributed to terrigenous dilution and do not reflect changes in the carbonate system. From the late Pliocene to Present, the average rate of calcium carbonate accumulation increases from 1 to 3 g/cm**2/k.y. and the average accumulation of organic carbon decreases from 75 to 30 mg/cm**2/k.y. The carbonate component is more dissolved in the older interval. The long-term variations in carbonate accumulation may reflect a greater input of organic matter in the late Pliocene, which decomposes to produce CO2 and dissolve carbonate. Magnetic susceptibility and % noncarbonate (100 - CaCO3%) reflect changes in the amount of the lithogenic component in the sediments. The period of variation of lithogenic material is the same period as the original forcing of the regional summer monsoon, however, the timing matches global aridity patterns and global ice volume (sea level) changes. This preliminary analysis suggests that the high frequency variation of lithogenic material persists for at least the last 3.4 m.y. Within the last million years, calcium carbonate accumulation has a large amplitude signal that covaries with major changes in ice volume. Both calcium carbonate and noncarbonate (mostly terrigenous) accumulation are greatest during glacial stages. Interglacial intervals are characterized by low mass accumulation rates, increased foraminifer fragmentation, and increased opal concentration. The accumulation of organic carbon matches the high frequency changes in sedimentation rates. We attribute this high correlation to enhanced preservation of organic carbon by increased sedimentation rate. Of the three major biological components studied, only opal exhibits the variations expected for a biological productivity system forced by monsoonal upwelling driven by changes in northern hemisphere summer radiation.

Calcareous nannofossil abundances in Mesozoic sediments of ODP Leg 129 holes

Calcareous nannofossils were studied from Jurassic and Cretaceous sediments drilled in the western Pacific during Ocean Drilling Program Leg 129. Mesozoic sediments at Sites 800, 801, and 802 are dominated by volcaniclastic turbidites, claystones, porcellanites, and radiolarites. Pelagic limestones are limited to the middle Cretaceous, and a few calcareous claystones were recovered in the Upper Jurassic section at Site 801. We documented the distribution of nannofossils, their total abundance, preservation, and relative species abundance based on semiquantitative and qualitative studies. Preservation of the calcareous nannofloras is poor to moderate, and the total abundance fluctuates from rare to very abundant. Marker species proposed for the middle and Late Cretaceous were recognized, allowing the application of standard nannofossil biozonations. At Site 800 calcareous nannofloras are abundant and moderately preserved in the Aptian-Cenomanian, and nannofossil biostratigraphy constitutes the basic stratigraphic framework for this interval. Radiolarians are the most abundant and persistent group throughout the sequence drilled at Site 801. Long intervals are barren of nannofloras and assemblages are usually characterized by low abundance and poor preservation. Nannofossil biostratigraphy was applied to the upper Aptian-Cenomanian interval and a few marker species were recognized for the late Tithonian. At Site 802 Cretaceous biostratigraphy is mainly based on calcareous nannofossil biozones corroborated by radiolarian and palynomorph events in the late Aptian-Coniacian age interval. A hiatus was indicated between the Santonian and the late Campanian, and another is suspected in the interval between the Cenomanian and the Coniacian.

General descriptions, organic contents and ratios of geolipid components at DSDP Leg 74 Holes

Two samples of Miocene sediments from Site 525 and four samples of sediments ranging in age from Pleistocene to Miocene from Site 528 have been analyzed for concentrations of organic and carbonate carbon, carbon/nitrogen ratios of organic matter, and extractable hydrocarbons and fatty acids. Organic carbon concentrations average 0.32% and show a diagenetic decrease with greater sediment age. Distributions of n-alkanes and n-alkanoic acids give evidence of considerable microbial reworking and of eolian contributions of terrigenous components. Organic contents of these sediments reflect a history of low marine productivity and poor preservation of organic matter in the eastern South Atlantic since middle Miocene times.