Degradación y recuperación de varistores de ZnO

In the present work it was studied the main aspect that influences on degradation and physical-chemical properties at grain-boundary region of metal oxide varistors and its consequences on microstructure and nonohmic electric properties. Based on the comprehension of the degradation aspects it was proposed some methodologies to recover the varistors nonohmic properties after being failed with long (2000 μs) and short current pulses (8/20 μs). Our analysis shown that one of the cause of degradation process is related to the lowering of oxygen species amount at grain-boundary region. Therefore, it is possible to re-promote oxygen enrichment of such regions by specific thermal treatments in rich oxygen atmospheres (the best condition found in the present work was temperatures around 900°C for 2 h at an oxygen flux of 15 1/h). The proposed nonohmic properties recovering procedure appear to be valid for all kind metal oxide varistors studied and is very important from technological point of view.

Métodos químicos para obtener varistores basados en SnO2

Synthesis of SnO2 ceramic powders was made by coprecipitation method and polymeric precursor method (Pechini) to obtain Sn-Co-Nb-Ti-Al varistor systems. The particles of the obtained ceramic powder presented nanometric size and SnO2 was the principal crystalline phase in them according to X-ray diffraction results. To determine the behavior of the synthesized samples in front of the thermal treatments, thermal analysis (DTA/TG) were made. Dilatometric studies on previously pressed samples were carried out. The optimal conditions of sintering of this raw material were determined. Microstructures and electric properties of sintered samples were studied using scanning electron microscopy (SEM) and I-V characteristics curves. The samples presented varistor behavior independent of the synthesis method used, with high nonlinearity values as 32. The presence of Al3+ favored the concentration of oxygen vacancies, and the grain growth.

Respuesta eléctrica de películas gruesas del sistema SnO2-TiO2, conformadas con polvos cerámicos obtenidos a través del método pechini

Tin oxide is the compound more used in the gas sensor production, mainly to reduce gases like CO and H2. Their electrical properties are strongly dependent of its surface. For this is of great importance to synthesize nanoscale tin oxide particles to use they later in the films conformation. The synthesis of SnO2-TiO2 nanoparticles by polymeric precursor method is reported in this work. The particles were characterized by DTA/TG, FT-IR, XRD and SEM. Also, the electrical response of thick films measured under oxygen and carbon monoxide atmospheres is was analyzed.

Influencia del TiO2 y Al2O3 sobre las propiedades eléctricas y microestructurales de cerámicas de SnO2 obtenidas por el método Pechini

Tin oxide has wakened up great scientific and technological interest for its potential use in varistors production and as gas sensor. In order to improve the microstructural and electrical properties in SnO varistor ceramics, the influence of differents dopants used, like TiO2 and Al2O3, is under research. The effect of TiO2 and Al2O3 on the properties of Sn-Co-Nb varistor Systems obtained by the Pechini method has been investigated in this work. Characterization of synthesized raw material was performed by X-Ray Diffraction (XRD) and Scanning Electronic Microscopy (SEM). The microstructural and electrical characterization of sintered samples show that the TiO2 favors the grain growth and the Al2O3, contributes to the decrease it, effect that is manifested in the Sn-Co-Nb varistor systems. Breakdown field increase up to 6300V/cm with increasing Al2O3 content and non-linear coefficients with α=22 were obtained.

Anelastic characterization and superconducting properties of RuSr2GdCu2O8+δ

Since the discovery of the high Tc superconductors, many researches have been carried out on the different properties of these materials, especially on the transition temperature into the superconducting state. The rutheno-cuprates belong to a new class of composites, which were synthesized for the first time by Bauernfeind in 1995. Bernhard and collaborators discovered, in 1999, the coexistence of the ferromagnetism and the superconductivity in this phase, which is known as antagonistic phenomenon in the electromagnetism due to spin-charge interactions established in these states. However, the physical nature of the superconducting and magnetic states is still very obscure. The non-stoichiometric (interstitial) oxygen is considered as a possible cause for the non-uniformity of the sample properties. In this paper, results of mechanical spectroscopy in Ru-1212 samples are presented showing complex anelastic spectra, which were attributed to the mobility of the interstitial oxygen atoms in the Ru-1212 lattice.

Estudio digital radiográfico y densitométrico en mandíbulas de cerdos sometidos a osteotomía con alta y baja velocidad, con refrigeración líquida

The influence of the type of rotary cutting instrument on bone repair after osteotomy in swine jaw, was evaluated using digital and densitometric radiographic examinations, at controlled times. Two cross-sectional dissections were made through the base of the right jaw, one using a high speed rotary instrument and the other using low speed, both with liquid cooling. After established periods the animals were sacrificed and their jaws removed for direct and indirect digital radiographic and densitometric studies using the CROMOX, DIGORA and ODR systems. In the initial periods (7 and 28 days) the bone density was higher in osteotomy areas performed with high rotation speeds, and in the final periods (60 and 90 days) the bone density was higher in the osteotomies performed with low rotation, indicating a better final bone repair with the use of low rotation. The qualitative analysis of the repair process was made by the ODR system which obtained three-dimensional and coloured digital images, which enable the bone thickness to be measured using an aluminium wedge. This showed that by twenty-eight days the bone repair was already apparently complete. © 2010 SECOM.

Estudio histológico comparativo de la reparación ósea entre hueso alveolar y extra-alveolar en los cerdos sometidos a osteotomía con alta y baja velocidad, con refrigeración líquida

Taking into account the bone repair process in pigs has shown a greater similarity among the histological variables studied compared to other biological models, the present study has as its aim to evaluate the histological bone repair process of osteotomy performed on alveolar and extra-alveolar bones, using drilling tools with liquid refrigeration. Material and method: Eighteen Large White pigs weighing between 20 and 25 Kg were divided into three groups of six animals in order to evaluate the osteotomy repairs with low and high speed in the alveolar bone and threes in the extra-alveolar area, study periods of 7, 14 and 28 days. Results: It was observed that in the alveolar bone at the postoperative times of 14 and 28 days, the best repair results were in the osteotomy performed with low speed, while in the 7 day postoperative period, the results with high speed were slightly better, in alveolar areas as well as extra-alveolar areas. There no statistically significant differences between the alveolar and extra-alveolar bone repair process. Conclusions: The repair process, by means of microscopic analysis in the alveolar and extra-alveolar areas, are similar with better results observed in osteotomies performed with low speed drills in the 14 and 28 day study periods, and at 7 days postoperative the results with high speed drills and refrigeration were slightly better. Research works using pigs as an animal model are perfectly viable. © 2011 SECOM.

O romance-projeto: um estudo de Lucinde (1799), de Friedrich Schlegel

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Busca de princípios para uma atuação a partir de estudos sobre o griots africanos e os jograis medievais europeus

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Harry Clarke e a literatura: da pintura em vitrais à ilustração de livros

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Arte e formação de educadores: metodologia para compreender e dizer

Pós-graduação em Artes - IA

Antonio Dias: imagens, palavras e diagramas

Pós-graduação em Artes - IA

A revista Artéria: uma amostragem das poéticas intersemióticas dos anos 70 aos 90

Pós-graduação em Artes - IA

A viola amplificada de Leo Canhoto e Robertinho: a trilha sonora do Brasil em transição

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)