Protein partitioning in poly(ethylene glycol)/sodium polyacrylate aqueous two-phase systems

The partition of hemoglobin, lysozyme and glucose-6-phospate dehydrogenase (G6PDH) in a novel inexpensive aqueous two-phase system (ATPS) composed by poly(ethylene glycol) (PEG) and sodium polyacrylate (NaPA) has been studied. The effect of NaCl and Na2SO4, pH and PEG molecular size on the partitioning has been studied. At high pH (above 9), hemoglobin partitions strongly to the PEG-phase. Although some precipitation of hemoglobin occurs, high recovery values are obtained particularly for lysozyme and G6PDH. The partitioning forces are dominated by the hydrophobic and electrochemical (salt) effects, since the positively charged lysozyme and negatively charged G6PDH partitions to the non-charged PEG and the strongly negatively charged polyacrylate enriched phase, respectively. (c) 2007 Elsevier B.V. All rights reserved.

Dependence of anuran diversity on environmental descriptors in farmland ponds

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Electromagnetic field at finite temperature: A first order approach

In this work we study the electromagnetic field at finite temperature via the massless DKP formalism. The constraint analysis is performed and the partition function for the theory is constructed and computed. When it is specialized to the spin 1 sector we obtain the well-known result for the thermodynamic equilibrium of the electromagnetic field. (c) 2006 Elsevier B.V. All rights reserved.

Bose-Einstein condensation and free DKP field

The thermodynamical partition function of the Duffin-Kemmer-Petiau theory is evaluated using the imaginary-time formalism of quantum field theory at finite temperature and path integral methods. The DKP partition function displays two features: (i) full equivalence with the partition function for charged scalar particles and charged massive spin 1 particles; and (ii) the zero mode sector which is essential to reproduce the well-known relativistic Bose-Einstein condensation for both theories. (C) 2003 Published by Elsevier B.V.

Black hole entropy associated with the supersymmetric sigma model

By means of an identity that equates the elliptic genus partition function of a supersymmetric sigma model on the N-fold symmetric product (SX)-X-N of X ((SX)-X-N=X-N/S-N, where S-N is the symmetric group of N elements) to the partition function of a second-quantized string theory, we derive the asymptotic expansion of the partition function as well as the asymptotic for the degeneracy of spectrum in string theory. The asymptotic expansion for the state counting reproduces the logarithmic correction to the black hole entropy.

Quantum states, thermodynamic limits, and entropy in M theory

We discuss the matching of the BPS part of the spectrum for a (super) membrane, which gives the possibility of getting the membrane's results via string calculations. In the small coupling limit of M theory the entropy of the system coincides with the standard entropy of type IIB string theory (including the logarithmic correction term). The thermodynamic behavior at a large coupling constant is computed by considering M theory on a manifold with a topology T-2 x R-9. We argue that the finite temperature partition functions (brane Laurent series for p not equal 1) associated with the BPS p-brane spectrum can be analytically continued to well-defined functionals. It means that a finite temperature can be introduced in brane theory, which behaves like finite temperature field theory. In the limit p --> 0 (point particle limit) it gives rise to the standard behavior of thermodynamic quantities.

Entropy and thermodynamic limits in M-theory

The matching of the BPS part of the (super) membrane's spectrum enables one to obtain membrane's results via string calculations. We compute the thermodynamic behavior at large coupling constant by considering M-theory on a manifold with topology T-2 X R-9. In the small coupling limit of M-theory the entropy coincides with the standard entropy of type IIB strings. We claim that the finite temperature partition functions associated with BPS p-brane spectrum can be analytically continued to well-defined functionals. This means that finite temperature can be introduced in brane theory. For the point particle limit (p --> 0) the entropy has the standard behavior of thermodynamic quantities.

Strings in horizons, dissipation and a possible interpretation of the Hagedorn temperature

We consider the entanglement of closed bosonic strings intersecting the event horizon of a Rindler spacetime, and, by using some simplified (rather semiclassical) arguments and some elements of the string field theory, we show the existence of a critical temperature beyond which closed strings cannot be in thermal equilibrium. The order of magnitude of this critical value coincides with the Hagedorn temperature, which suggests an interpretation consistent with the fact of having a partition function that is ill defined for temperatures higher than it. Possible implications of the present approach for the microscopical structure of stretched horizons are also pointed out.

Matsubara-Fradkin thermodynamical quantization of Podolsky electrodynamics

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Thermal phase transitions for Dicke-type models in the ultrastrong-coupling limit

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Path integral approach to the full Dicke model

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

On semiclassical analysis of pure spinor superstring in an AdS(5) x S-5 background

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Measurement of jet fragmentation into charged particles in pp and PbPb collisions at root s(NN)=2.76 TeV

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Radon in groundwater contaminated by dissolved hydrocarbons in Santa Barbara d'Oeste, São Paulo State, Brazil

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Biosorption and desorption of lanthanum(III) and neodymium(III) in fixed-bed columns with Sargassum sp.: Perspectives for separation of rare earth metals

Rare earth (RE) metals are essentials for the manufacturing of high-technology products. The separation of RE is complex and expensive; biosorption is an alternative to conventional processes. This work focuses on the biosorption of monocomponent and bicomponent solutions of lanthanum(III) and neodymium(III) in fixed-bed columns using Sargassum sp. biomass. The desorption of metals with HCl 0.10 mol L-1 from loaded biomass is also carried out with the objective of increasing the efficiency of metal separation. Simple models have been successfully used to model breakthrough curves (i.e., Thomas, Bohart-Adams, and Yoon-Nelson equations) for the biosorption of monocomponent solutions. From biosorption and desorption experiments in both monocomponent and bicomponent solutions, a slight selectivity of the biomass for Nd(III) over La(III) is observed. The experiments did not find an effective separation of the RE studied, but their results indicate a possible partition between the metals, which is the fundamental condition for separation perspectives. (C) 2012 American Institute of Chemical Engineers Biotechnol. Prog., 2012