Cationic and neutral phenylmercury(II) complexes with heterocyclic thione ligands. X-ray structures of [HgPh(dmpymtH)][BF(4)] center dot H(2)O and [{HgPh}(2)(mu-dtu)]

The neutral complex [HgPh(dmpymt)] 1 (dmpymtH = 4,6-dimethylpyrimidine-2(1H)-thione) reacts with HBF(4) to give the cationic complex [HgPh(dmpymtH)][BF(4)] 2. The X-ray molecular structure of the later revealed a [2+1] coordination sphere about the mercury(II) atom (C-Hg-S and Hg center dot center dot center dot N). In the dinuclear complex [(HgPh)(2)(mu-dtu)] 3 [dtuH(2) = 2,4(1H,3H)-pyrimidinedithione or dithiouracil] the coordination spheres are also [2+1] although dissimilar regarding the Hg center dot center dot center dot N secondary bonds. NMR spectroscopy ((1)H, (13)C and (199)Hg) studies were undertaken in solution and the results discussed in the light of the X-ray structures. (C) 2008 Elsevier B. V. All rights reserved.

Graduate School and University Center Archives Finding Aid - Record Group VIII: Doctoral Students' Council

This is part of the finding aid to the Graduate School and University Center (GSUC) Archives. Record Group VIII is the files from the Doctoral Students' Council (DSC).

Graduate School and University Center Archives Finding Aid - Record Group VII: CUNY

This is part of the finding aid to the Graduate School and University Center (GSUC) Archives. Record Group VII is materials about the City University of New York, transferred from the Mina Rees Library and the Provost's Office. Also included in this group are the records of the Research Foundation.

Graduate School and University Center Archives Finding Aid - Record Group VI: Vice-President for Finance and Administration

This is part of the finding aid to the Graduate School and University Center (GSUC) Archives. Record Group VI is the files of the Vice-Presidents for Finance and Administration.

Graduate School and University Center Archives Finding Aid - Record Group V-D: Presidents' Files: Kelly

This is part of the finding aid to the Graduate School and University Center (GSUC) Archives. Record Group V-D is the papers of William P. Kelly from when he was president of the GSUC (2005-2013).

Graduate School and University Center Archives Finding Aid - Record Group V-C: Presidents' Files: Horowitz

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Graduate School and University Center Archives Finding Aid - Record Group V-B: Presidents' Files: Proshansky

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Graduate School and University Center Archives Finding Aid - Record Group V-A: Presidents' Files: Rees

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Graduate School and University Center Archives Finding Aid - Record Group V: Presidents' Files

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Graduate School and University Center Archives Finding Aid - Record Group IV: Committee Records

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Graduate School and University Center Archives Finding Aid - Record Group III: Periodicals

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Graduate School and University Center Archives Finding Aid - Record Group II: Centers and Institutes

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Graduate School and University Center Archives Finding Aid - Record Group I: Subjects

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Center for the Study of Free Reed Instruments Collection, 1947-2011 Finding Aid

The Center for the Study of Free-Reed Instruments Collection is an archival collection at the City University of New York Graduate Center’s Mina Rees Library which contains materials donated by Professor Allan W. Atlas, related to free-reed instruments and the International Concertina Association.