991 resultados para Leg
Resumo:
The ocean history of reactive phosphorus (P) (i.e., dissolved P available to fuel oceanic primary productivity) is of interest because of the role of P as a biolimiting nutrient, and knowledge of P burial in marine sediments is key to testing hypotheses about temporal changes in P input or output fluxes. Our understanding of the history of the P cycle over the Cenozoic has increased substantially with temporal records of reactive P mass accumulation rates from open-ocean Pacific and Atlantic equatorial sites. However, questions about the relative importance of nutrient burial in ocean-margin sediments relative to burial in open-ocean sediments and about the extent of P remobilization in organic-rich, reducing environments characteristic of margin sediments remain unresolved. Nutrient burial in oceanic boundary current systems has been suggested to have a controlling role in oceanic nutrient budgets in certain time intervals (Vincent and Berger, 1985, doi:10.1029/GM032p0455), with higher sediment accumulation rates balancing the limited spatial extent of these sediments. Some investigators suggest that remobilization of P from reducing sediments in margin settings is a significant positive feedback to primary productivity (e.g., Van Cappellan and Ingall, 1994, doi:10.1029/94PA01455), whereas other results indicate that both P uptake and P release may occur in these settings depending on the balance of organic carbon and iron supply to the sediments and on the oxygenation of bottom waters (McManus et al., 1997, doi:10.1016/S0016-7037(97)00138-5). It is important to quantitatively understand the geochemistry of reactive P in margin sediments, where productivity and delivery of organic-rich material to the sediments in relatively shallow-water settings is often sufficient to promote anoxia in interstitial waters. To address these questions, we determined the P concentrations and geochemistry in sediment samples from eight sites drilled during Ocean Drilling Program (ODP) Leg 167, California margin (Sites 1010-1012, 1014, 1016-1017, and 1021-1022). These results are the first records of reactive P concentrations on long time scales-required for the calculation of P accumulation rates-for sediments from a highly productive eastern boundary current setting. In addition, we determined calcium carbonate contents and biogenic silica concentrations to define the environments of sedimentary production, burial, and diagenesis.
Resumo:
Hydrogen isotope compositions have been measured on pore waters from sediments of Leg 129 sites in the Pigafetta and East Mariana basins (central western Pacific). Total water (pore + sorbed waters) contents and their dD have been analyzed for three samples that contain smectite but no zeolite so that sorbed water can be attributed to interlayer water. The H budget for pore and total waters implies that interlayer water is 20 per mil to 30 per mil depleted in D compared to pore water. Because the interlayer/total water molar ratio (0.25 to 0.5) in smectitic sediments is very high, interlayer water represents an important reservoir of D-depleted water in sediments. dD depth profiles for pore water at Sites 800 and 801 show breaks related to chert and radiolarite layers and are relatively vertical below. Above these chert units, pore waters are similar to modern seawater but below, they are between -10 per mil and -5.5 per mil. These values could represent little modified pre-Miocene seawater values, which were D-depleted because of the absence of polar caps, and were preserved from diffusive exchange with modern seawater by the relatively impermeable overlying chert layers. At Site 802, dD values of the pore waters show a decrease in the Miocene tuffs from 0 per mil values at the top to -8 per mil at 250 mbsf. Below, dD values are relatively uniform at about -8ë. Miocene tuffs are undergoing low water/rock alteration. A positive covariation of dD and Cl content of pore water in the tuffs suggests that the increase of dD values could result from secondary smectite formation. Low diffusive exchange coupled with D enrichment due to alteration of preglacial waters could explain the observed profile.
Resumo:
Carbon, hydrogen, and oxygen isotope ratios determined on 32 squeezed interstitial fluid samples show remarkable variations with depth. For the most part these variations are related to diagenetic and alteration reactions taking place in the sediments, and in the underlying basalts. delta13C SumCO2 depth distributions at Sites 642 and 643 are the result of mixing of original SumCO2 of the paleo bottom water with SumCO2 released by remineralization of organic matter. At Site 644, where sulfate exhaustion occurs, the processes of methanogenesis by CO2 reduction and anaerobic methanotrophy strongly influence the delta13C SumCO2 distribution. Hydrogen and oxygen isotopes roughly covary, and become enriched in 16O and1H with depth. This effect is most pronounced at Sites 642 and 643, possibly due to the influence of the directly underlying basalts. Isotope depletions at Site 644 are much lower, corresponding to the greater sediment depth to basement. The alternative, that the O, H isotope shifts are due primarily to autochthonous diagenetic and exchange reactions, is not supported by the data available.
Resumo:
Diatoms occur sporadically in lower Miocene to Holocene sediments recovered at ODP Site 645 and in upper Pliocene to Holocene sediments at ODP Site 646. The diatom assemblage at Site 645 contains rare stratigraphic indicators. Fragmentation of frustules and the occurrence of species characteristic of high-latitude shelf, upper-slope environments suggest current transportation from the shelf. The diatom abundance and preservation at Site 646 probably reflect climatic changes and are also affected by dissolution, but it is not possible to detect the dominant factor. Therefore, the stratigraphic ranges of the primary and secondary biostratigraphic indicators are often unreliable.
Resumo:
Leg 65 of the Deep Sea Drilling Project successfully recovered basalts from four sites in the mouth of the Gulf of California, thus completing a transect begun during Leg 64 from the continental margin of Baja California to the east side of the East Pacific Rise (EPR). Sixty-three whole-rock samples from Sites 482, 483, and 485 have been analyzed by X-ray fluorescence techniques, and a further eleven samples by instrumental neutron-activation techniques, in order to assess magma variability within and between sites. Although the major element compositions and absolute hygromagmatophile (HYG) element abundances are quite variable, all of the basalts are subalkaline tholeiites exhibiting strong more-HYG element (e.g., Rb, La, Nb, Ta) depletion (LaN/YbN ~ 0.4; Nb/Zr ~ 0.02; Ba/Zr ~ 0.23; Th/Hf ~ 0.05). These ratios, together with La/Ta ratios of 20 and Th/Ta ratios of 1.25, demonstrate that the Leg 65 basalts resemble the depleted "N-type" ocean ridge basalts recovered from the Mid-Atlantic Ridge (MAR) at 22 °N and other sections of the EPR. Zr/Ti, Zr/Y, and La/Yb ratios increase with increasing fractionation. It is clear that the basalts recovered from Sites 482, 483, and 485 were all derived from a compositionally similar source and that the compositional differences observed between lithological units can be explained by varying degrees of open system fractional crystallization (magma mixing) in subridge magma chambers. The basaltic rocks recovered from Site 474 near the margin of Baja California, and Sites 477, 478, and 481 in the Guaymas Basin, all drilled during Leg 64, have consistently higher Th/Hf, La/Sm, Zr/Ti, and Zr/Y ratios and higher absolute Sr contents than the Leg 65 basalts. While some of these variations may be explained by different conditions of partial melting, it is considered more likely that the mantle source underlying the Guaymas Basin is chemically distinct from that feeding the EPR at the mouth of the Gulf. These source variations probably reflect the complex tectonic setting of the Gulf of California, the magmas formed at the inception of spreading and in the central part of the Gulf containing a minor but significant component of sub-continental (calc-alkaline) material.
Resumo:
With this study, we investigate the mineralogical variations associated with the low-temperature (<100°C) alteration of normal tholeiitic pillow basalts varying in age from 0.8 to 3.5 Ma. Their alteration intensity varies systematically and is related to several factors, including (1) the aging of the igneous crust, (2) the increase of temperatures from the younger to the older sites, measured at the sediment/basement interface, (3) the local and regional variations in lithology and primary porosity, and (4) the degree of pillow fracturing. Fractures represent the most important pathways that allow significant penetration of fluids into the rock and are virtually the only factor controlling the alteration of the glassy rim and the early stages of pillow alteration. Three different alteration stages have been recognized: alteration of glassy margin, oxidizing alteration through fluid circulation in fracture systems, and reducing alteration through diffusion. All the observed mineralogical and chemical variations occurring during the early stages of alteration are interpreted as the result of the rock interaction with "normal," alkaline, and oxidizing seawater, along preferential pathways represented by the concentric and radial crack systems. The chemical composition of the fluid progressively evolves while moving into the basalt, leading to a reducing alteration stage, which is initially responsible for the precipitation of Fe-rich saponite and minor sulfides and subsequently for the widespread formation of carbonates. At the same time, the system evolved from being "water dominated" to being "rock dominated." No alteration effects in pillow basalts were observed that must have occurred at temperatures higher than those measured during Leg 168 at the basement/sediment interface (e.g., between 15° and 64°C).
Resumo:
Sediment cores recovered from three holes drilled during Ocean Drilling Program Leg 136 include volcaniclastics probably derived from the Hawaiian islands. The volcaniclastics shallower than 10 meters below seafloor are fresh and are composed of basaltic glass (sideromelane), basaltic fragments (mainly tachylite), plagioclase, olivine, pyroxene, and opaque minerals. Most of these glasses are probably products of hydrovolcanism. Visibly, some of these volcaniclastics are recognized as bedded ash layers having thicknesses that range from 5 to 10 cm. However, many volcaniclastics are disrupted by bioturbation to some degree, and are sometimes totally mixed with ambient brown clays. No visible correlative ash layer among these holes was found. It seems that many ash layers thinner than the bedded layers were disrupted by bioturbation because of the low sedimentation rate of volcaniclastics. The volcaniclastics were probably transported one of two ways: through air fall and pelagic settling or through turbidity-current transport. Other archipelagic apron volcaniclastic sediments of volcanic seamounts suggest that turbidite transport is the favored explanation of origin.
Resumo:
The abundance and composition of the upper Cenozoic terrigenous coarse-sand fraction (250 µm-2 mm) at ODP Sites 642, 643, and 644 were investigated to date the onset of significant ice-rafting in the Norwegian Sea, establish the regional chronology of ice-rafting, and determine the relative importance of global vs. regional controls on ice-rafting in this area. The first input of ice-rafted debris (IRD) occurs at approximately 2.9 Ma, with significant ice-rafting beginning at about 2.5 Ma. IRD abundances increase significantly in sediments younger than 0.9 Ma at all three holes, indicating climatic deterioration in the late Pleistocene. Differences in the timing of this IRD increase between holes result from regional patterns of IRD supply and surface circulation. Variations in IRD sources and dispersal patterns may also explain the slightly higher background level of IRD abundance at Hole 642B, a seaward site. Major peaks in the generalized IRD records from the Norwegian Sea are tentatively correlated to glacial stages or glacial-to-interglacial transitions in the globally defined oxygen isotope record. This correlation indicates the effect of global conditions on the regional climate of the Norwegian Sea, although the detailed IRD records at these sites are also affected by local/regional processes (e.g., circulation patterns and source area differences).
Resumo:
Cores recovered from three sites of Leg 116 were studied for radiolarians. Generally, radiolarians were absent from most samples prepared for examination. Moderate to well-preserved radiolarian assemblages are found only in the uppermost one or two cores that were the focus of this study. All of the radiolarian assemblages in the upper cores belong to the Buccinosphaera invaginata Zone of latest Quaternary age. However, there is one stratum where a few Miocene radiolarians are reworked into the modern assemblages. Local seamounts are suggested sources for the reworked radiolarians.