The ecology of paper mill by-product and its evaluation as a casing medium in the culture of Agaricus bisporus (Lange) Pilat

Effluent from pulp and paper production at the Kemsley mill of Bowaters U.K. Paper Company Limited passes through two treatment stages before its discharge into the Swale estuary. Suspended material removed during treatment is deposited on wasteground as a thin sludge. The solids it contains are mainly wood components lost during pulp production, whilst it also has a high salt content, derived from chemicals used in pulping processes. After deposition the sludge undergoes an ageing process during which it dries out and its salt content is reduced. This ageing can be reproduced and accelerated by improved drainage under controlled conditions. The paper mill sludge was investigated as a casing medium in the culture of Agaricus bisporus (Lange) Pilat, the cultivated mushroom. It was unsuitable up to one year from deposition due largely to the inhibitory effect of its salt content on fruiting. Material eighteen months or more in age gave yields comparable to standard peat casing. Before use as a casing the material must be shredded to a satisfactory structure, neutralised with chalk, and pasteurised to eliminate organisms harmful to the crop. The prepared medium has a high water holding capacity and a structure resilient to management procedures, important requirements of a good casing. A passive movement of salts from the compost to the casing was shown to occur during culture, capable of enhancing the natural decline in cropping if sufficiently great. The ions chloride, potassium, sodium and sulphate were shown to be responsible, their damaging effects being due to high conductivity created in the casing. Studies of elements available during culture suggested phosphate availability in the compost could limit crop potential, whilst iron released by mycelium of A.bisporus in the casing may be utilised by associated micro-organisms.

The intermediate pyrolysis of de-inking sludge to produce a sustainable liquid fuel

De-inking sludge is a waste product generated from secondary fibre paper mills who manufacture recycled paper into new paper sheets; it refers directly to the solid residues which evolve during the de-inking stage of the paper pulping process. The current practice for the disposal of this waste is either by land-spreading, land-filling or incineration which are unsustainable. This work has explored the intermediate pyrolysis of pre-conditioned de-inking sludge pellets in a recently patented 20 kg/h intermediate pyrolysis reactor (The Pyroformer). The reactor is essentially two co-axial screws which are configured in such a way as to circulate solids within the reactor and thus facilitate in the cracking of tars. The potential application of using the volatile organic vapours and permanent gases evolved would be to generate both combined heat and power (CHP) located at paper making sites. The results show that de-inking sludge could be successfully pyrolysed and the organic vapours produced were composed of a mixture of aromatic hydrocarbons, phenolic compounds and some fatty acid methyl esters as detected by liquid GC-MS. The calorific value of the oil after condensing was between 36 and 37 MJ/kg and the liquid fuel properties were also determined, permanent gases were detected by a GC-TCD and were composed of approximately 24% CO, 6% CH and 70% CO (v/v%). The solid residue from pyrolysis also contained a small residual calorific value, and was largely composed of mainly calcium based inert metal oxides. The application of applying intermediate pyrolysis to de-inking sludge for both CHP production and waste reduction is in principle a feasible technology which could be applied at secondary fibre paper mills. © 2013 Elsevier B.V. All rights reserved.

Multi-Channel-Management im Spannungsfeld von Kundenzufriedenheit und Organisation

Technologische Entwicklungen wie der massenhafte Einzug des Internets haben dazu geführt, die gewachsenen Absatzketten insbesondere im Handel zumindest teilweise außer Kraft zu setzen. Das Management von Kundenkontakten stellt Unternehmen vor neue Herausforderungen, da der multioptionale Konsument zur Realität geworden ist. Vor diesem Hintergrund wird mittels dreier empirischer Studien, durchgeführt vom Institut für Handelsmanagement und Netzwerkmarketing, ein Modell der Zufriedenheit von Konsumenten im Internet hergeleitet, welches den Unternehmen neue Ansatzpunkte präsentiert, um erfolgreich im Markt zu bestehen.

Fixed bed downdraft gasification of paper industry wastes

The two main wastes generated from secondary fibre paper mills are rejects (composed mainly of plastics and fibres) and de-inking sludge, both of which are evolved from the pulping process during paper manufacture. The current practice for the disposal of these wastes is either by land-spreading or land-filling. This work explores the gasification of blends of pre-conditioned rejects and de-inking sludge pellets with mixed wood chips in an Imbert type fixed bed downdraft gasifier with a maximum feeding capacity of 10kg/h. The producer gases evolved would generate combined heat and power (CHP) in an internal combustion engine. The results show that as much as 80wt.% of a brown paper mill's rejects (consisting of 20wt.% mixed plastics and 80wt.% paper fibres) could be successfully gasified in a blend with 20wt.% mixed wood chips. The producer gas composition was 16.24% H, 23.34% CO, 12.71% CO 5.21% CH and 42.49% N (v/v%) with a higher heating value of 7.3MJ/Nm. After the removal of tar and water condensate the producer gas was of sufficient calorific value and flow rate to power a 10kWe gas engine. Some blends using rejects from other mill types were not successful, and the limiting factor was usually the agglomeration of plastics present within the fuel.

The intermediate pyrolysis of de-inking sludge to produce a sustainable liquid fuel

De-inking sludge is a waste product generated from secondary fibre paper mills who manufacture recycled paper into new paper sheets; it refers directly to the solid residues which evolve during the de-inking stage of the paper pulping process. The current practice for the disposal of this waste is either by land-spreading, land-filling or incineration which are unsustainable. This work has explored the intermediate pyrolysis of pre-conditioned de-inking sludge pellets in a recently patented 20 kg/h intermediate pyrolysis reactor (The Pyroformer). The reactor is essentially two co-axial screws which are configured in such a way as to circulate solids within the reactor and thus facilitate in the cracking of tars. The potential application of using the volatile organic vapours and permanent gases evolved would be to generate both combined heat and power (CHP) located at paper making sites. The results show that de-inking sludge could be successfully pyrolysed and the organic vapours produced were composed of a mixture of aromatic hydrocarbons, phenolic compounds and some fatty acid methyl esters as detected by liquid GC-MS. The calorific value of the oil after condensing was between 36 and 37 MJ/kg and the liquid fuel properties were also determined, permanent gases were detected by a GC-TCD and were composed of approximately 24% CO, 6% CH and 70% CO (v/v%). The solid residue from pyrolysis also contained a small residual calorific value, and was largely composed of mainly calcium based inert metal oxides. The application of applying intermediate pyrolysis to de-inking sludge for both CHP production and waste reduction is in principle a feasible technology which could be applied at secondary fibre paper mills. © 2013 Elsevier B.V. All rights reserved.

Aproveitamento sustentável do bagaço de cana de açúcar para obtenção do acetato de celulose

The sustainable use of waste resulting from the agribusiness is currently the focus of research, especially the sugar cane bagasse (BCA), being the lignocellulosic waste produced in greater volume in the Brazilian agribusiness, where the residual biomass has been applied in production energy and bioproducts. In this paper, pulp was produced in high purity from the (BCA) by pulping soda / anthraquinone and subsequent conversion to cellulose acetate. Commercial cellulose Avicel was used for comparison. The obtained cellulose acetate was homogeneous acetylation reaction by modifying the variables, the reaction time in hours (8, 12, 16, 20 and 24) and temperature in ° C (25 and 50). FTIR spectra showed characteristic bands identical to cellulosic materials, demonstrating the efficiency of separation by pulping. The characterization of cellulose acetate was obtained and by infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG / DTG / DSC), scanning electron microscopy (SEM) and determining the degree of substitution (DS ) for the cellulose acetate to confirm the acetylation. The optimal reaction time for obtaining diacetates and triacetates, at both temperatures were 20 and 24 h. Cellulose acetate produced BCA presented GS between 2.57 and 2.7 at 25 ° C and 50 ° C GS obtained were 2.66 and 2.84, indicating the actual conversion of cellulose BCA of di- and triacetates. Comparative mode, commercial cellulose Avicel GS showed 2.78 and 2.76 at 25 ° C and 2.77 to 2.75 at 50 ° C. Data were collected in time of 20 h and 24 h, respectively. The best result was for the synthesis of cellulose acetate obtained from the BCA GS 2.84 to 50 ° C and 24 hours, being classified as cellulose triacetate, which showed superior result to that produced with the commercial ethyl cellulose Avicel, demonstrating converting potential of cellulose derived from a lignocellulosic residue (BCA), low cost, prospects of commercial use of cellulose acetate

Remoção de metais utilizando o hexadecanoato de sódio

Industrial activities like mining, electroplating and the oil extraction process, are increasing the levels of heavy metals such as Cu, Fe, Mg and Cd in aquatic ecosystems. This increase is related to the discharge of effluents containing trace of this elements above the maximum allowed by law. Methods such as ion exchange, membrane filtration and chemical precipitation have been studied as a means of treatment of these metals contamination. The precipitation of metals using anionic surfactants derived from carboxylic acids emerged as an alternative for the removal of metals from industrial effluents. The reaction between bivalent ions and these types of surfactants in aqueous solution leads to the formation of metal carboxylates, which can precipitate in the form of flakes and are subsequently removed by a process of decantation or simple filtration. In this work the metals extraction is performed by using the surfactant sodium hexadecanoate as extracting agent. The main purpose was to study the effect of temperature, solution pH, and concentration of surfactant in the metal removal process. The statistical design of the process showed that the process is directly dependent to changes in pH and concentration of surfactant, but inversely proportional and somewhat dependent to temperature variation, with the latter effect being considered negligible in most cases. The individual study of the effect of temperature showed a strong dependence of the process with the Kraft point, both for the surfactant used as extracting agent, as for the surfactant obtained after the reaction of this surfactant with the metal. From data of temperatures and concentrations of the surfactant was possible to calculate the equilibrium constant for the reaction between sodium hexadecanoate and copper ions. Later, thermodynamic parameters were determined, showing that the process is exothermic and spontaneous.

Associations between smoking behavior-related alleles and the risk of melanoma.

Several studies have reported that cigarette smoking is inversely associated with the risk of melanoma. This study further tested whether incorporating genetic factors will provide another level of evaluation of mechanisms underlying the association between smoking and risk of melanoma. We investigated the association between SNPs selected from genome-wide association studies (GWAS) on smoking behaviors and risk of melanoma using 2,298 melanoma cases and 6,654 controls. Among 16 SNPs, three (rs16969968 [A], rs1051730 [A] and rs2036534 [C] in the 15q25.1 region) reached significance for association with melanoma risk in men (0.01 < = P values < = 0.02; 0.85 < = Odds Ratios (ORs) <= 1.20). There was association between the genetic scores based on the number of smoking behavior-risk alleles and melanoma risk with P-trend = 0.005 among HPFS. Further association with smoking behaviors indicating those three SNPs (rs16969968 [A], rs1051730 [A] and rs2036534 [C]) significantly associated with number of cigarettes smoked per day, CPD, with P = 0.009, 0.011 and 0.001 respectively. The SNPs rs215605 in the PDE1C gene and rs6265 in the BDNF gene significantly interacted with smoking status on melanoma risk (interaction P = 0.005 and P = 0.003 respectively). Our study suggests that smoking behavior-related SNPs are likely to play a role in melanoma development and the potential public health importance of polymorphisms in the CHRNA5-A3-B4 gene cluster. Further larger studies are warranted to validate the findings.

Mineralcomposition of beach sediments from the area "Fähre Großenbrode-Kliff Wulfen" on Fehmarn

Um die Insel Fehmarn und an der Nordküste Wagriens wurden rund 2500 Strand-, Flachwasser- und Seesandproben zum Erkennen der Materialtransportwege sedimentpetrographisch untersucht. Für die Schwermineralbestimmung wurde hauptsächlich die Fraktion 0,2-0,1 mm herangezogen, da diese für die vorliegenden Sedimente charakteristisch ist. Da die Mineralzusammensetzung der Sedimente im gesamten Untersuchungsgebiet gleich ist, also nirgends örtlich sog. Leitminerale zugeführt werden, wurden bei der Auswertung der Analysenergebnisse die hydrographischen Verhältnisse der westlichen Ostsee und die Abhängigkeit des Sedimentes von der Kraft des bewegten Meerwassers beachtet. Bezüglich der Abhängigkeit des transportierten Materials von der Wasserkraft werden drei voneinander abweichende Systeme, nämlich der Strand, die Brandungszone und das tiefere Wassergebiet, erkannt. Am Strand ist die angewandte Untersuchungsmethode sowohl an langgestreckten Küsten als auch in stark untergliederten Ufergebieten zum Erkennen der Sandwanderbahnen geeignet. Erosion und Neuzuführung von Material auf dem Transportwege zeigen das gleiche mineralische Bild, und eine Entscheidung, welcher dieser beiden Fälle tatsächlich vorliegt, kann nur im Gelände getroffen werden. Die Korngrößenanalyse allein ist zur Beantwortung vorliegender Fragestellungen nicht brauchbar, weil durch gegebene hydrographische Bedingungen die Korngröße in Transportrichtung sowohl abnehmen als auch zunehmen kann. In Strandgebieten mit veränderter natürlicher Beschaffenheit der Sedimente und an Küsten mit ausgedehnten vorgelagerten materialliefernden Abrasionsflächen ist die Grenze der Methode aufgezeigt. Höfte, Haken und Sandinseln zeigen jeweils typische mineralische Zusammensetzungen ihres Strandes, aus welchen die Entstehung der betreffenden Anlandungsformen abgeleitet werden kann. Quer über die Brandungszone weisen die Sedimente auf engem Raum wechselnde Mineralzusammensetzung auf, aus der auf die örtlichen hydrographischen Verhältnisse geschlossen werden kann. Zum Vergleich sedimentpetrographischer Ergebniswerte sind nur Sande, die unter gleichen Ablagerungsbedingungen entstanden sind, geeignet. Zum Erkennen der Materialwanderwege wurden entweder Sandproben von den Riffkämmen oder aus den Rinnen zwischen zwei Sandanhäufungszonen untersucht. In beiden Fällen wurden die Transportrichtungen erkannt. In Gebieten, in denen die Strandsanduntersuchungen negativ verliefen, ließen die Riffsandproben Schlüsse auf die Materialschüttungsrichtungen zu. An exponierten Küsten mit mehreren wirksamen Windrichtungen darf jedoch nicht von dem einen auf das andere Wandersystem geschlossen werden. Eine Umkehr der Materialvertriftung zwischen Flachwasser und Strand kann vorliegen. Im tieferen Wasser ist es möglich, mit gleicher Methode unter Berücksichtigung der Morphologie des Meeresgrundes die Materialschüttungsrichtung zu erkennen. Zur Sedimentuntersuchung auf Linienprofilen sind nur Proben gleicher Wassertiefe geeignet; die Sonderung des Materials nach der Tiefe muß beachtet werden. Aus den ermittelten sedimentpetrographischen Werten lassen sich eine Reihe von Beziehungen ablesen, die zur Deutung der Mineralgesellschaft und für die Auswertung der Untersuchungsergebnisse herangezogen werden können. Als regionales Ergebnis der vorstehenden Untersuchung kann eine Karte der Küsten Fehmarns und Nordoldenburgs vorgelegt werden, in der die Sandwanderungswege am Strand, in der Flachwasserzone und in den daran anschließenden tieferen Wassergebieten dargestellt sind.

Identification of independent association signals and putative functional variants for breast cancer risk through fine-scale mapping of the 12p11 locus

BACKGROUND: Multiple recent genome-wide association studies (GWAS) have identified a single nucleotide polymorphism (SNP), rs10771399, at 12p11 that is associated with breast cancer risk. METHOD: We performed a fine-scale mapping study of a 700 kb region including 441 genotyped and more than 1300 imputed genetic variants in 48,155 cases and 43,612 controls of European descent, 6269 cases and 6624 controls of East Asian descent and 1116 cases and 932 controls of African descent in the Breast Cancer Association Consortium (BCAC; http://bcac.ccge.medschl.cam.ac.uk/ ), and in 15,252 BRCA1 mutation carriers in the Consortium of Investigators of Modifiers of BRCA1/2 (CIMBA). Stepwise regression analyses were performed to identify independent association signals. Data from the Encyclopedia of DNA Elements project (ENCODE) and the Cancer Genome Atlas (TCGA) were used for functional annotation. RESULTS: Analysis of data from European descendants found evidence for four independent association signals at 12p11, represented by rs7297051 (odds ratio (OR) = 1.09, 95 % confidence interval (CI) = 1.06-1.12; P = 3 × 10(-9)), rs805510 (OR = 1.08, 95 % CI = 1.04-1.12, P = 2 × 10(-5)), and rs1871152 (OR = 1.04, 95 % CI = 1.02-1.06; P = 2 × 10(-4)) identified in the general populations, and rs113824616 (P = 7 × 10(-5)) identified in the meta-analysis of BCAC ER-negative cases and BRCA1 mutation carriers. SNPs rs7297051, rs805510 and rs113824616 were also associated with breast cancer risk at P < 0.05 in East Asians, but none of the associations were statistically significant in African descendants. Multiple candidate functional variants are located in putative enhancer sequences. Chromatin interaction data suggested that PTHLH was the likely target gene of these enhancers. Of the six variants with the strongest evidence of potential functionality, rs11049453 was statistically significantly associated with the expression of PTHLH and its nearby gene CCDC91 at P < 0.05. CONCLUSION: This study identified four independent association signals at 12p11 and revealed potentially functional variants, providing additional insights into the underlying biological mechanism(s) for the association observed between variants at 12p11 and breast cancer risk

Sustainability, creativity and innovation in project management – Model development for assessing organizational performance through projects

Today a number of studies are published on how organizational strategy is developed and how organizations contribute to local and regional development through the realization of these strategies. There are also many articles dealing with the success of a project by identifying the criteria and the factors that influence them. This article introduces the project-oriented strategic planning process that reveals how projects contribute to local and regional development and demonstrates the relationship between this approach and the regional competitiveness model as well as the KRAFT concept. There is a lot of research that focuses on sustainability in business. These studies argue that sustainability is very important to the success of a business in the future. The Project Excellence Model that analyses project success does not contain the sustainability criteria; the GPM P5 standard consists of sustainability components related either to the organizational level. To fill this gap a Project Sustainability Excellence Model (PSEM) was developed. The model was tested by interviews with managers of Hungarian for-profit and non-profit organizations. This paper introduces the PSEM and highlights the most important elements of the empirical analysis.

De nya EU-direktiven om hållbarhetsrapportering : En fallstudie genomförd på Stora Enso

Bakgrund Denna uppsats behandlar de nya EU-kraven som föreslås träda i kraft från och med det räkenskapsår som inleds närmast efter den 31 december 2016. Uppsatsen har undersökt hur Stora Enso arbetar med hållbarhetsrapportering enligt Global Reporting Initiatives riktlinjer. Detta eftersom att Stora Enso var det första börsnoterade företaget i Sverige vars hållbarhetsrapportering granskats av en tredje part. Vidare siktar denna uppsats på att ge de företag som ej tidigare har erfarenhet från hållbarhetsrapportering en inspirationskälla, som stöd i upprättningen av egna hållbarhetsrapporter. Syfte Syftet med den här fallstudien är att beskriva hur ett företag som redan innan EU-kraven börjat tillämpats rapporterat i enlighet med dessa, och hur de aktivt arbetar med hållbarhetsrapportering. Metod Fallstudie: intervjuer och dokumentanalys. Slutsats Det är viktigt att hela tiden fortsätta förbättra företagets hållbara utveckling och dess mål. Stora Ensos hållbarhetsrapportering kopplades ihop med den hållbara utvecklingen i stort, och här sågs att rapporteringen har hjälpt Stora Enso att uppnå och utveckla sina hållbarhetsmål. Utan hållbarhetsrapporteringen skulle Stora Ensos positiva utveckling inte varit lika omfattande. Utifrån de intervjuer som genomfördes konstaterades det att GRI:s riktlinjer medför både en fördel och en nackdel: de är väldigt omfattande.

Bruch und Kontinuität. Zum Modernisierungseffekt der Reformpädagogik

Untersucht wird die Frage, ob, und wenn ja, in welchem Sinne die internationale Reformpädagogik nach 1890 eine neue Ära gewesen ist. Anhand einer vergleichenden Literaturanalyse werden zunächst die Modernisierungsbehauptungen verschiedener reformpädagogischer Autoren nachgewiesen, bevor dann die Kontinuierung der Tradition beschrieben und am Schluß die typische reformpädagogische Semantik mit tatsächlichen Modernisierungseffekten im Bildungssystem zusammengebracht wird. Die These definiert einen paradoxen Tatbestand: Sehr traditionelle Motive und Denkbilder der Pädagogik des 19. Jahrhunderts werden in theoretisch wie empirisch neue Kontexte urbaner Großstadterfahrung übersetzt, ohne ihre reformprägende Kraft zu verlieren. (DIPF/Orig.)

Estimates of genetic parameters for growth and wood properties in Eucalyptus pellita F. Muell. to support tree breeding in Vietnam

Eucalyptus pellita demonstrated good growth and wood quality traits in this study, with young plantation grown timber being suitable for both solid and pulp wood products. All traits examined were under moderate levels of genetic control with little genotype by environment interaction when grown on two contrasting sites in Vietnam. Eucalyptus pellita currently has a significant role in reforestation in the tropics. Research to support expanded of use of this species is needed: particularly, research to better understand the genetic control of key traits will facilitate the development of genetically improved planting stock. This study aimed to provide estimates of the heritability of diameter at breast height over bark, wood basic density, Kraft pulp yield, modulus of elasticity and microfibril angle, and the genetic correlations among these traits, and understand the importance of genotype by environment interactions in Vietnam. Data for diameter and wood properties were collected from two 10-year-old, open-pollinated progeny trials of E. pellita in Vietnam that evaluated 104 families from six native range and three orchard sources. Wood properties were estimated from wood samples using near-infrared (NIR) spectroscopy. Data were analysed using mixed linear models to estimate genetic parameters (heritability, proportion of variance between seed sources and genetic correlations). Variation among the nine sources was small compared to additive variance. Narrow-sense heritability and genetic correlation estimates indicated that simultaneous improvements in most traits could be achieved from selection among and within families as the genetic correlations among traits were either favourable or close to zero. Type B genetic correlations approached one for all traits suggesting that genotype by environment interactions were of little importance. These results support a breeding strategy utilizing a single breeding population advanced by selecting the best individuals across all seed sources. Both growth and wood properties have been evaluated. Multi-trait selection for growth and wood property traits will lead to more productive populations of E. pellita both with improved productivity and improved timber and pulp properties.