Geochemistry and minerals at DSDP Leg 65 Holes

Petrologic studies of mid-ocean ridge basalt (MORB) (e.g., Melson et al., 1975; Flower, et al., 1977; Byerly and Wright, 1978; Melson, 1979; Byerly and Sinton, 1980; Thompson, 1980) show that magmatic liquid-fraction trends are indicated by the compositions of fresh glass selvedges, usually, but not always, associated with pillow basalts. In contrast, whole-rock compositional variation will often reflect the complicating effects of syn- and post-eruptive phenocryst accumulation. Additional variation may be introduced by the reaction of basalts with seawater. While comparatively severe alteration of variable type was noted locally in the young basalts recovered across the mouth of the Gulf of California on Leg 65, most of the basalts were extremely fresh, making them ideal for studies of compositional variation.

Chemical composition of ultrabasite and gabbro from the rift zones of the Arabian-Indian and Western Indian ridges

Results of petrographic studies of ultrabasite and gabbro from the rift zones of the Indian Ocean ridges are discussed using materials of R/V Vityaz Cruise 36. Rocks sampled from two sites 2700 km apart are close to each other in their composition. Petrographically ultrabasic rocks are divided into four subgroups: I - dunite; II - harzburgite, serpentinite; III - plagioclase lherzolite; and IV - metamorphically altered rocks. Petrographic description and chemical composition of basic rock varieties are presented as well as description of rock-forming minerals and their optical properties. Formation of pyroxene and plagioclase is shown to be related to autometasomatosis, which concludes the magmatic phase proper in rock mass formation accompanied by activity of residual intragranular liquid. Formation of ultrabasite in the rift zones is related to complicated processes.

Composition and sorption capacity of oceanic and marine ferromanganese nodules

Experimental data obtained show that oceanic and marine ferromanganese nodules and crusts are natural ion-exchangers. Exchange capacity of oceanic ferromanganese aggregates is much higher than that of shallow-water marine ones, whereas reactivities of exchange cations (Na, K, Ca, and Mg) are almost equal in both.

Chemical composition of soils and rocks from King George Island

Both the olivine-hearing tholeiite basalts of the island and the brown soils which have developed on the basalts contain 2-20% of a swelling clay mineral. It emerges from chemical, optical, X-ray diffraction and differential thermal analytical studies that this clay mineral is a Mg-rich, Fe2+ and AI-bearing tri-octahedral smectite, e. g. Mg-saponite. Due to petrographic and crystal chemical properties the saponite should have been formed by hydrothermal alteration of the primary Mg-Fe-minerals olivine and clinopyroxene. The soils consist of plagioclase, saponite and goethite which has been formed by chemical weathering within the soils. In the uppermost layer some of the soils contain humic substances and phosphatic material, the latter may be related to the recent production of guano.