800 resultados para Indicators and Reagents.


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Beef businesses in northern Australia are facing increased pressure to be productive and profitable with challenges such as climate variability and poor financial performance over the past decade. Declining terms of trade, limited recent gains in on-farm productivity, low profit margins under current management systems and current climatic conditions will leave little capacity for businesses to absorb climate change-induced losses. In order to generate a whole-of-business focus towards management change, the Climate Clever Beef project in the Maranoa-Balonne region of Queensland trialled the use of business analysis with beef producers to improve financial literacy, provide a greater understanding of current business performance and initiate changes to current management practices. Demonstration properties were engaged and a systematic approach was used to assess current business performance, evaluate impacts of management changes on the business and to trial practices and promote successful outcomes to the wider industry. Focus was concentrated on improving financial literacy skills, understanding the business’ key performance indicators and modifying practices to improve both business productivity and profitability. To best achieve the desired outcomes, several extension models were employed: the ‘group facilitation/empowerment model’, the ‘individual consultant/mentor model’ and the ‘technology development model’. Providing producers with a whole-of-business approach and using business analysis in conjunction with on-farm trials and various extension methods proved to be a successful way to encourage producers in the region to adopt new practices into their business, in the areas of greatest impact. The areas targeted for development within businesses generally led to improvements in animal performance and grazing land management further improving the prospects for climate resilience.

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The study of green chemistry is dedicated to eliminating or reducing toxic waste. One route to accomplish this goal is to explore alternative reaction conditions and parameters resulting in the development of more benign synthetic routes and reagents. The primary focus of this research is to find optimal reaction conditions for the oxidation of a primary alcohol to an aldehyde. As a case study, the oxidation of benzyl alcohol to benzaldehyde, a common industrial process, was examined. Traditionally carried out using the Jones Reagent, commonly referred to as chromium (IV) oxide or chromium trioxide (CrO3) in sulphuric acid, a great deal of research went into utilizing less toxic reagents, such as MnO2 or KMnO4 supported on a clay base. This research has led to an improvement on these alternatives, using a lithium chloride (LiCl) catalyst in a montmorillonite K10 clay solid phase, together with the oxidizing agent hydrogen peroxide, as even greener alternatives to these traditional oxidizing agents. Experiments were carried out to determine the lifetime of this LiCl/clay system as compared to MnO2 and KMnO4, to investigate its ability to catalyze the oxidation of other aromatic alcohols (such as 4-methoxybenzyl alcohol and diphenylmethanol), and to further improve the system’s adherence to green chemistry principles. Green solvent alternatives were examined by replacing the toluene solvent with dimethylcarbonate (DMC), and reaction conditions were optimized to improve product yield. It was determined that the LiCl/H2O2 system was, in most cases, equally as effective at catalyzing the oxidation of benzyl alcohol to benzaldehyde. Although the catalyst and oxidizing agent eliminated the toxic waste generated from chromium reagents, it offered significant challenges in product isolation, because of an aqueous-organic phase separation.

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Los valores del patrimonio edificado en las tenencias del municipio de Morelia distan mucho de ser los de la zona de monumentos de la capital, ya que tienen que ver con la cultura popular, el saber colectivo y las tradiciones constructivas. El artículo explica que como reflejo de los cambios en la economía, cultura y desarrollo de sus habitantes, las tenencias experimentan un proceso de transformación y hasta la pérdida de su patrimonio edificado. Las unidades de análisis se seleccionaron con el Índice de Accesibilidad e Interacción Espacial; posteriormente se explican los indicadores de Accesibilidad y Urbanización, y finalmente estos datos se correlacionan con el indicador de transformación del patrimonio. Medir y conocer las características de los factores que transforman el patrimonio cultural edificado es una manera anticipada de conservarlo como una manifestación cultural, histórica, de una forma de vida y un elemento de identidad.

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In the first paragraphs of this paper a survey of the most ap- proved paleowind indicators is given. Methods, limitations and Problems of their Interpretation are discussed. The following indicators and their attributes are considered: loess, sandy loess (attributes: Sediment thickness, grain size, mineral compo- sition, sediment structure and morphology), paleosoils, vulcano- eolian Sediments, deep sea Sediments and paleo snowlines. In the second part of this paper the wind regimes predominating in Europe during the Weichselian glacial maximum are recon- structed based on information from more than 170 publications with interpretations of paleowind indicators. The results are presented in two survey maps. The most significant result is to indicate two competing wind regimes existing during the glacial maximum. In the immediate vicinity of the Fennoscandian glaciation and in eastern Europe paleowind indicators document easterly and north easterly anti- cyclonic winds; in central and Western Europe they show westerly winds originated in cyclones coming from the North Atlantic. Some modifications of the wind pattern are induced by local and regional morphological conditions (e.g. the Upper Rhine valley, the east rim of the Carpathian Mountains). In general and compared with previous investigations the study points to a more differentiated pattern of atmospheric circula- tion during the Weichselian Pleniglacial influenced by variing topographical, paleoecological and meteorological factors.

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Over time, humanity began to realize the negative impact that the modern world has caused to the environment. The Atlantic Forest is one of the richest biomes in biodiversity, covering more than 60% of all species on the planet. This biome covered about 15% of the Brazilian territory, leaving currently only 7% of its fully fragmented forest remnants. This was the biome that suffered most from modernization and strong anthropogenic pressures in Brazil. For the account of environmental degradation, in the second half of the nineteenth century there was a shift in thinking, giving greater emphasis on conservation of some natural landscapes, with the intention of removing the man still preserved nature. Based on American models of conservation there were created the Nature Conservation Units. This study aimed to analyze the environmental quality of the State Park Vitório Piassa, a Conservation Unit located in the city of Pato Branco - PR. The environmental quality was measured by use of bio-indicators and some environmental pressures that the Park has suffered over the years also were identified. Beetles of the familiy Scarabaeinae (Coleoptera: Scarabaeidae) were used as the bioindicators. To compare the most conserved areas and the most degraded areas of the Park, three specific sites were defined within the Atlantic Forest fragment, these insects were captured with pitfall traps and identified as to their species and genera. There were two collections in February and March 2015, which resulted in 945 individuals in 22 species and nine different genus. Then the population of beetles in each area were classified based on ecological measures such as species richness, abundance of individuals of each species through diversity index (Shannon and Simpson) to identify the differences between the sampled groups and equitability (Pielou) to measure the distribution of the total abundance of the species in each area. To meet the objective of identifying the environmental pressures that occur in PEVP, evidence were collected through photographs, watching the field, aerial images and conversations with the resident population in the park. Similarly, if made relevant to build on the project running by the municipality for the construction of infrastructure for public viewing. These data served as subsidies to confront the current situation of the park and the current Brazilian legislation for UC's of full protection, highlighting the existing socio-environmental conflicts in the park, involving political issues and the proximity of the Conservation Unit with the urban area of the city.

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1.This report presents the results of a field study conducted in the ECASA test site nOS in the Pertuis Breton, France. The site is located on the Atlantic West coasts. It is open to the bay of Biscay, but is slightly protected against westerly winds. The bay has been exploited by intertidal mussels culture for centuries. 2. Within the bay, mussels (Mytilus edulis) are cultivated either by the traditional pole technique, around the bay or on longlines in the centre of the bay. The area occupied by these longline s represents 250 ha, and the resulting annual production is 1 000 tonnes of mussels. The average depth at mid tide is of 13.8 m. The sediment is sandy, with a small fraction of mud. 3. The site is subject to several regular monitoring through the local implementation of national networks aiming at protecting the environment and marine resources, on pollutants (RNO), microbiological quality of the waters (REMI), phytoplanktonic toxic species (REPHY) and growth and mortality of molluscs (REMORA). Benthic macrofauna was studied in 1976. 4. Five sampling sations were chosen along a line, starting under the longlines, and at distances of 50, 100, 200, and 400 metres from the area cultivated. A reference station was chosen in a different direction at 2300 metres of the cultivated area. Sampling methods are described in the text. _Sediments were sampled for different analyses: grain size, content in organic matter, total organic carbon and nitrogen, and phytic pigments (chlorophyll a and phaeopigments). Redox were measured in cores. The macrofauna living into the sediment was also sampled. The water column was sampled for physical (temperature, transparency) and chemical parametres, including oxygen content, salinity, organic matter, dissolved nitrogen forms, phosphates and silicates. Results from benthic macrofauna surveys indicate that there were no significant differences between the different stations and the reference station, all being classified as slightly disturbed. The bay is submitted to freshwater runoffs from two adjacent rivers. 7. The sediment is slightly modified by the culture of bivalves. Total organic carbon, total nitrogen, Eh values and pheopigments were significantly higher under the trestles than in any other stations. Other stations often did not differ from the reference station. 8. The effects of shellfish culture on the water column were. However, it was observed a small decrease of the food available to the molluscs near the rearing 9. The DEB model was able to describe and predict adequately the growth of oysters, both in the Baie des Veys and in the Loch Creran. The parametres for its use in other environment are given, but a tuning of one parametre should be performed with the help of authors. 10. Among the indicators and models for use in are as of intertidal bivalve culture, it is recommended to use the sediment quality index, TOC (Total Organic Carbon), redox and pheopigments, in surficial sediment, AMBI for the macrofauna, chlorophyll a contents and nitrogen forms in the water column, and models describing the carrying capacity, filtration rate of molluscs, and a DEB model to predict the growth of molluscs.

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El Comité Organizador del XXII Congreso de Geógrafos Españoles, certifica que la siguiente aportación presentada al mencionado congreso, ha sido seleccionada por el Comité Científico "mejor comunicación de autor joven".

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Al testear la situación de la biodiversidad urbana y los espacios verdes en la zona del Yanuncay de Cuenca (Ecuador), se pretendió revelar particularidades de la co-determinación entre la biodiversidad y las áreas verdes al interior de la ciudad. Se calcularon seis indicadores y tres índices que mostraron niveles alarmantemente bajos, que sugieren la necesidad de acciones inmediatas con el fin de recuperar la biodiversidad perdida. Por ejemplo, en el caso del indicador de la Permeabilidad del Suelo Público el 83.53% del suelo no es permeable; en cuanto a la Proximidad a Espacios Verdes el 98.82% del área de estudio no se aproxima al objetivo mínimo; en lo referente al cálculo de la Densidad de Árboles por Tramo de Calle el 98.83% de los tramos tienen arbolado insuficiente. Un aporte importante del trabajo es la construcción del Índice de Verde Urbano (IVU) que conjuga el indicador de Superficie Verde por Habitante con el de Proximidad Simultánea a Tres Tipos de Espacios Verdes, de este modo se puede tener una mirada tanto de la cantidad como de la cobertura e influencia, a distintas escalas, que estas áreas tienen sobre las personas. En este índice se constata que el 91.76% del área no cumple con el valor mínimo. Estos datos nos permiten afirmar que la ciudad actual y su producción de áreas verdes no contribuyen a la sostenibilidad ecológica y por ende a la biodiversidad urbana. Si no se proponen cambios urgentes al modelo de ciudad vigente, estos valores se volverán aún más alarmantes.

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In recent decades the public sector comes under pressure in order to improve its performance. The use of Information Technology (IT) has been a tool increasingly used in reaching that goal. Thus, it has become an important issue in public organizations, particularly in institutions of higher education, determine which factors influence the acceptance and use of technology, impacting on the success of its implementation and the desired organizational results. The Technology Acceptance Model - TAM was used as the basis for this study and is based on the constructs perceived usefulness and perceived ease of use. However, when it comes to integrated management systems due to the complexity of its implementation,organizational factors were added to thus seek further explanation of the acceptance of such systems. Thus, added to the model five TAM constructs related to critical success factors in implementing ERP systems, they are: support of top management, communication, training, cooperation, and technological complexity (BUENO and SALMERON, 2008). Based on the foregoing, launches the following research problem: What factors influence the acceptance and use of SIE / module academic at the Federal University of Para, from the users' perception of teachers and technicians? The purpose of this study was to identify the influence of organizational factors, and behavioral antecedents of behavioral intention to use the SIE / module academic UFPA in the perspective of teachers and technical users. This is applied research, exploratory and descriptive, quantitative with the implementation of a survey, and data collection occurred through a structured questionnaire applied to a sample of 229 teachers and 30 technical and administrative staff. Data analysis was carried out through descriptive statistics and structural equation modeling with the technique of partial least squares (PLS). Effected primarily to assess the measurement model, which were verified reliability, convergent and discriminant validity for all indicators and constructs. Then the structural model was analyzed using the bootstrap resampling technique like. In assessing statistical significance, all hypotheses were supported. The coefficient of determination (R ²) was high or average in five of the six endogenous variables, so the model explains 47.3% of the variation in behavioral intention. It is noteworthy that among the antecedents of behavioral intention (BI) analyzed in this study, perceived usefulness is the variable that has a greater effect on behavioral intention, followed by ease of use (PEU) and attitude (AT). Among the organizational aspects (critical success factors) studied technological complexity (TC) and training (ERT) were those with greatest effect on behavioral intention to use, although these effects were lower than those produced by behavioral factors (originating from TAM). It is pointed out further that the support of senior management (TMS) showed, among all variables, the least effect on the intention to use (BI) and was followed by communications (COM) and cooperation (CO), which exert a low effect on behavioral intention (BI). Therefore, as other studies on the TAM constructs were adequate for the present research. Thus, the study contributed towards proving evidence that the Technology Acceptance Model can be applied to predict the acceptance of integrated management systems, even in public. Keywords: Technology

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The implementation of the WFD in the French overseas takes into account local, morphological, climatic and socioeconomic peculiarities, as well as specificities of their ecosystems. This document provide an up-to-date assessment of the state of characteristics of the coastal water bodies, of development of indicators and of WFD monitoring programs in each of the French overseas departments: Martinique, Guadeloupe, French Guyana, Reunion Island and Mayotte.

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Background Diabetes mellitus is a global public health problem. In Malawi, the prevalence of diabetes is 5.6% but the quality of care has not been well studied. Objective The aim of this study was to assess the quality of care offered to diabetic patients in Mangochi district. Methods This was a cross sectional descriptive study. Quantitative data were collected using a questionnaire from a sample of 75 diabetic patients (children and adults) who attended the Diabetes Clinic at Mangochi District Hospital between 20012 and 2013. Qualitative data were also collected using semi-structured interviews with eight Key Informants from among the District Health Management Team. Frequencies and cross-tabulation were obtained from the quantitative data. Patients’ master cards were checked to validate results. Clinical knowledge about diabetes, care practices and resources were the themes analysed from the qualitative data. Results Among the 75 participants interviewed, 46 were females and 29 males. The overall mean age was 48.3 years (45.6 for females and 53.3 for males). More than half of patients had little or no information about diabetes (40.0 % (n=30) and 22.7 (n=17) respectively. The majority of patients were taking their medicines regularly 98.7% (n=74). Only 17.3% (n=13) reported having their feet inspected regularly. Fifty-six percent of patients were satisfied about services provision. Some nurses and clinicians were trained on diabetes care but most of them left. Guidelines on diabetes management were not accessible. There were shortages in medicines (e.g. soluble insulin) and reagents. Information Education and Communication messages were offered through discussions, experiences sharing and posters. Conclusion Quality of diabetes care provided to diabetic patients attended to Mangochi hospital was sub-optimal due to lack of knowledge among patients and clinicians and resources. More efforts are needed towards retention of trained staff, provision of pharmaceutical and laboratory resources and health education.

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This study is about the institutional self-evaluation in Dimension 4, "Communication with Society", from the National System of Higher Education Evaluation SINAES, mandatory for all universities in Brazil. A multiple cases study was conducted with three institutions from Rio Grande do Norte, and the goal was to know how this evaluation is made, describing the concept for the evaluation of communication proposed by them, identifying controllers or emancipator aspects, categorizing methodological procedures and discussing the difficulties reported in the communication evaluation process. Coordinators of the institutions Evaluating Committees were interviewed and data categorized by means of qualitative content analysis. It was noted characteristics of the current controller, emancipator and hybrid designs in the three institutions for evaluation of communication, revealing the lack of a theoretical corpus that transits in accordance with the systemic perspective and epistemology of complexity from SINAES. It was found that the most frequently reported difficulties in the evaluation processes of communication are in the preparation stage, especially in the definition of indicators and tools and awareness work. The weakness in planning makes their own activities in the sector of communication become targets of assessment, forming goals poorly related with broader organizational goals. It was also concluded that the technical evaluation cannot override the issues associated with the broader issue of the complexity surrounding the assessment paradigm proposed by SINAES because contradictions and imperfections are part of the evaluation process and several references are current in the literature to support this view. Finally, it is said that objectives such as transparency and behavioral changes can rely on methodologies and techniques for research on the question of the construction of meaning

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Objetivo: Investigar os benefícios de um programa de reabilitação psicomotora em pessoas idosas institucionalizadas ao nível de indicadores de saúde e do bem-estar. Metodologia: A amostra integrou 42 participantes (84±6.2 anos), dos quais 21 pertenciam ao grupo experimental (programa de reabilitação) e 21 ao grupo controlo. Os indicadores de saúde e bem-estar foram avaliados pelo Profile of Mood Stats (POMS), pela Escala de Dor (Instrumento P4), pela Perceção de Estado de Saúde (EQVAS) e pelo Índice de Barthel. Resultados: Os testes de comparação evidenciaram melhorias significativas no grupo experimental, nas variáveis depressão, irritação, confusão, principalmente no score total sem e com irritação da avaliação de estados emocionais e de humor, em relação à escala de dor as variáveis escala de dor1 e score total escala de dor foram as que tiveram melhorias significativas, p= <0.05. Conclusão: O programa de reabilitação psicomotora promoveu melhorias ao nível dos indicadores de saúde e do bem-estar das pessoas idosas institucionalizadas, com maior impacto nos estados emocionais e de humor e diminuição de intensidade de dor; Abstract: Effect of a psychomotor rehabilitation intervention in elderly people institutionalized at the level of health indicators and welfare. Objective: The aim is to investigate the benefits of a psychomotor rehabilitation program in orderly people institutionalized at the level of health indicators and welfare. Methodology: The sample consisted of 42 participants (84 ± 6.2 years), 21 of them belonged to the experimental group (rehabilitation program), and the other 21, to the control group. The following surveys were conducted by the Profile of Mood Stats (POMS), the Pain Scale (P4 Instrument), the Perception of Health Status (EQVAS) and the Barthel Index. Results: Significant improvements were observed in the experimental group, in the following dimensions: depression, anger, confusion, mainly in the total score with and without irritation assessment of emotional states and mood, regarding the pain scale, the variables pain scale and total average score were the ones that had higher significant improvements, p = <0.05. Conclusion: The psychomotor rehabilitation program led to improvements in health indicators and well-being of the institutionalized older ones, with greater impact on emotional states and mood and decrease in pain intensity.

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Dissertação (mestrado)—Universidade de Brasília, Centro de Estudos Avançados Multidisciplinares, Programa de Pós-Graduação em Desenvolvimento, Sociedade e Cooperação Internacional, 2016.