996 resultados para 234


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自然光照条件下,高原鼠兔(Ochotonacurzoniae)松果腺褪黑激素(Melatonin,MLT)含量呈现明显的昼夜节律(P<0.001,夜间组含量均值与白天组含量均值差异显著性比较)。在2月份的实验中,对18只鼠兔(体重122—164克)松果腺的采样时间分别为02.00,09.00,12.00,18.00,22.00和24.00时。白天MLT含量波动为56—64微微克/松果腺,夜间波动为113—170微微克/松果腺。夜间MLT含量高峰值出现在24.00时。在10月份的实验中,对60只鼠兔(体重102—153克)松果腺的采样时间分别为03.00,06.00,09.00,12.0...

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A highly selective and accurate method based on derivatization with dansyl chloride coupled with liquid chromatography-mass spectrometry has been developed for identification of natural pharmacologically active phenolic compounds in extracts of Lomatogonium rotatum plants (Tibetan herbal medicine) obtained by solid-phase extraction. The number of hydroxyl groups on the dansylated phenols was estimated by LC-MS-MS analysis in positive-ion mode. Dansyl derivatization of the compounds introduced basic secondary nitrogen into the phenolic core structures and this was readily ionized when acidic HPLC mobile phases were used. MS fragmentation of the derivatives generated intense protonated molecular ions of m/z [MH](+) (phenol aglycones were transformed into the corresponding free phenols by cleavage of an aglycone bond). Collision-induced dissociation of the protonated molecule generated characteristic product ions of m/z 234 and 171 corresponding to the protonated 5-(dimethylamino)naphthalene sulfoxide and 5 -(dimethylamino) naphthalene moieties, respectively. Selected reaction monitoring based on the m/z [MH](+) to 234 and 171 transitions was highly specific for these phenolic compounds. Characteristic ions with m/z values of [MH - 234](+), [MH 2 x 234](+), and [MH - 3 x 234](+) were of great importance for estimation of the presence of multihydroxyl groups on the phenolic backbone.

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Uptake and release of carbon in grassland ecosystems is very critical to the global carbon balance and carbon storage. In this study, the dynamics of net ecosystem CO2 exchange (FNEE) of two grassland ecosystems were observed continuously using the eddy covariance technique during the growing season of 2003. One is the alpine shrub on the Tibet Plateau, and the other is the sem-arid Leymus chinensis steppe in Inner Mongolia of China. It was found that the FNEE of both ecosystems was significantly depressed under high solar radiation. Comprehensive analysis indicates that the depression of FNEE in the L. chinensis steppe was the results of decreased plant photosynthesis and increased ecosystem respiration (R-eco) under high temperature. Soil water stress in addition to the high atmospheric demand under the strong radiation was the primary factor limiting the stomatal conductance. In contrast, the depression of FNEE in the alpine shrub was closely related to the effects of temperature on both photosynthesis and ecosystem respiration, coupled with the reduction of plant photosynthesis due to partial stomatal closure under high temperature at mid-day. The R,c of the alpine shrub was sensitive to soil temperature during high turbulence (u* > 0.2 m s(-1)) but its FNEE decreased markedly when the temperature was higher than the optimal value of about 12 degrees C. Such low optimal temperature contrasted the optimal value (about 20 degrees C) for the steppe, and was likely due to the acclimation of most alpine plants to the long-term low temperature on the Tibet Plateau. We inferred that water stress was the primary factor causing depression of the FNEE in the semi-arid steppe ecosystem, while relative high temperature under strong solar radiation was the main reason for the decrease of FNEE in the alpine shrub. This study implies that different grassland ecosystems may respond differently to climate change in the future. (c) 2006 Elsevier B.V All rights reserved.

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Six domestic yaks aged 6 years, comprising three culling male and three culling female yaks, from the Qinghai Lake area and three male semi-wild yaks aged 6 months from Datong Yak Farm were used to detect the levels of amino acids, mineral elements, residual heavy metals and pesticides in yak meat. The results showed that there was little difference in amino acid levels for different types of yak by age and sex. The meat of the adult male yak was 7.35 mg/kg higher in calcium (P < 0.05) and 124 mg/kg higher in phosphorus (P < 0.01) than that of the adult female yak. There was an obvious difference in zinc content, and there was also a significant difference for copper and sulfur between adult male and female yaks (P < 0.01). Iron was 8.85 mg/kg higher in semi-wild yaks than in domestic yaks, but there were no differences for other minerals. The levels of residual heavy metals and residual pesticides were well within those allowed by the National Standard of China. Furthermore, the data showed that introducing wild yak's blood did not result in a quality change in the domestic yak meat. Yak meat from Qinghai Plateau has the characteristics of being non-polluted and rich in amino acids in comparison with local yellow cattle meat.

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大文以大连港DP-CIMS资管理系统开发为背景,根据港航运输的特点,利用供应链管协调机制与方法,采用CORBA面向对象技术,开展了基于港航运输的供应链管理模设计与实施技术研究,提出了适合企业的供应链管理总体功能的结构框架,并着手在供应链管理系统网络环境下进行模型建立与开发。

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该书以陕西勉(县)-略(阳)-阳(平关)地区铜厂铜金多金属矿田为例,在总结构造成矿动力学的理论和方法基础上,从成矿地质背景、矿床地球化学、矿田地质力学、矿田构造地球化学及矿田构造应力场等方面对研究区进行了系统地构造成矿动力学研究,根据所获研究成果对该区进行了隐伏矿定位预测。全书约35万字,共分7章,其中图¨6幅、表53个、照片62张。陈庆宣院士为该书作了序。

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利用被动微波遥感亮度温度数据反演月壤厚度是“嫦娥”探月工程的科学目标之一,也是人类探测月壤厚度的一种新的尝试。深入研究月表太阳辐射、月球内部热流以及月表温度的分布和变化规律,是解译遥感数据,反演月壤厚度的前提条件,也为进一步开展月球探测、开发利用月球资源乃至建立月球基地相关研究工作提供必要的参考。 本文根据月表有效太阳辐照度与太阳常数、日月距离和太阳辐射入射角的关系,建立了月表有效太阳辐照度的实时模型如下: (1) 其中, (2) (3) 通过对月表有效太阳辐照度实时模型的各个参数分析发现,影响月表有效太阳辐照度变化的主要因素是日地距离和太阳辐射入射角的变化。对模型的误差分析表明,从1950年到2050年的100年内,月表有效太阳辐照度计算结果的误差百分比小于0.28%,能更准确地反映月表有效太阳辐照度的变化情况。从2007年月表有效太阳辐照度的计算结果发现,该年内的月表有效太阳辐照度变化在1321.5~1416.6 W•m-2之间,平均为1368.0 W•m-2,一个月内的变化最小幅度为6.0 W•m-2,最大幅度为23.6 W•m-2。 在月表有效太阳辐照度的实时模型基础上,根据能量守恒和Stefan-Boltzmann定律,本文还得出了月表温度分布模型如下: (4) 其中,初始条件由下式决定, (5) 通过与月表温度实际观测结果的比较发现,当月表反射率、热发射率和热惯量分别取0.127、0.94和125 J•m-2•s-1/2•K-1时,模型的计算结果与实际观测值比较符合,能较好地预测理想条件下的月表温度。 月表热参数研究的一个重要应用就是解译对月被动微波遥感的亮度温度数据。在对月被动微波遥感探测中,辐射计获得的亮度温度反映了月球表层的热辐射特性。月球表层的热辐射与其自身的热状况紧密相关,结合文中建立的月表热参数模型,根据辐射传播理论进一步分析了对月微波遥感探测中,月球表层在不同情况下对亮度温度的贡献,确定了亮度温度随月表温度和月壤厚度的变化关系,对被动微波遥感探测月壤厚度的可能性和可能达到的精度进行了估算。 对月球表层的热辐射传播的分析发现,对月被动微波遥感探测获得的亮度温度受月球表层热辐射的控制,与月壤厚度具有指数相关性,并受到月表温度的影响。当月壤和月岩的复介电常数分别为2 + 0.005 j和9 + 1 j、相对磁导率均为1时,对应3.0GHz、7.8GHz、19.35GHz和37.0GHz四个频率的亮度温度与月壤厚度及月表温度的关系可分别近似表示为, 3.0GHz亮度温度: (6) 7.8GHz亮度温度: (7) 19.35GHz亮度温度: (8) 37.0GHz亮度温度: (9) 当月壤厚度和月表温度分别在0.5m~30m和100K~400K之间变化时,上述四个频率的亮度温度变化范围分别在212.5K~252.8K、207.4 K~266.7K、193.8 K~288.6K和174.0 K~310.9K之间。对于较低频率的被动微波遥感,亮度温度随月壤厚度的增大逐渐增大并趋于稳定;对较高频率的被动微波遥感,亮度温度随月壤厚度的增大会产生起伏波动,不利于用单波段反演月壤厚度。亮度温度梯度在频率较高时梯度较大,在很小的月壤厚度范围内很快就趋于0,不利于厚度较大时的月壤厚度反演,但对于厚度较小时的月壤厚度反演精度较高;同时,除3.0GHz外,7.8GHz、19.35GHz和37.0GHz三个频率的亮度温度梯度随月表温度的升高降幅较大,尤其是19.35GHz,适合在夜间对月壤厚度较小的地区进行更精确的探测。对于3.0GHz,其亮度温度梯度受月表温度变化的影响很小,能反映出较深层月壤厚度的信息,可以对月球进行全球全天时探测。若辐射计的分辨率为0.02K,3.0GHz频率对10m厚月壤的判别精度达到0.07m;对于20m厚月壤的精度为1.4m。当月壤厚度小于0.5m时,随着月壤厚度从0到0.5m增加,月球表层的亮度温度贡献呈先减小后增大的趋势,从而使某一亮度温度值可能对应存在两种不同的月壤厚度。因此,对于月壤厚度小于0.5m的区域,利用单波段被动微波遥感亮度温度反演月壤厚度是比较困难的。 在对月被动微波遥感探测中,可以利用月球夜晚时段的亮度温度数据判别月壤厚度是否小于0.5m。当月表温度为100K时,3.0GHz、7.8GHz、19.35GHz和37.0GHz四个频率的亮度温度判别参考值分别为212.9K、207.4K、193.5K和174.1K;月表温度为240K时,上述四个频率的亮度温度判别参考值分别为220.8K、226.8K、234.1K和237.2K。当亮度温度小于参考值时表示月壤厚度小于0.5m,反之,表示月壤厚度大于0.5m。更进一步地,可以根据月表温度的影响系数对月岩是否裸露于月表进行判断。当3.0GHz、7.8GHz、19.35GHz和37.0GHz四个频率的月表温度影响系数接近0.77、0.82、0.84和0.85时,可以认为月岩直接暴露于月表。

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2009