Maximizing the utility of bio-based diisocyanate and chain extenders in crystalline segmented thermoplastic polyester urethanes: effect of polymerization protocol

High molecular weight semi crystalline thermoplastic poly(ester urethanes), TPEUs, were prepared from a vegetable oil-based diisocyanate, aliphatic diol chain extenders and poly(ethylene adipate) macro diol using one-shot, pre-polymer and multi-stage polyaddition methods. The optimized polymerization reaction achieved ultra-high molecular weight TPEUs (>2 million as determined by GPC) in a short time, indicating a very high HPMDI diol reactivity. TPEUs with very well controlled hard segment (HS) and soft segment (SS) blocks were prepared and characterized with DSC, TGA, tensile analysis, and WAXD in order to reveal structure property relationships. A confinement effect that imparts elastomeric properties to otherwise thermoplastic TPEUs was revealed. The confinement extent was found to vary predictably with structure indicating that one can custom engineer tougher polyurethane elastomers by "tuning" soft segment crystallinity with suitable HS block structure. Generally, the HPMDI-based TPEUs exhibited thermal stability and mechanical properties comparable to entirely petroleum-based TPEUs. (C) 2014 Elsevier Ltd. All rights reserved.

Caracterização de juntas soldadas em PAW e GTAW de chapas finas em aço maraging 300 submetidas a vários reparos

Pós-graduação em Engenharia Mecânica - FEG

Efeito da incorporação do trimetafosfato de sódio microparticulado e nanoparticulado ao cimento de ionômero de vidro nas propriedades físico-mecânicas e na desmineralização do esmalte

Pós-graduação em Ciência Odontólogica - FOA

Evaluation of quality of life related to i-131 therapy in patients with well-differentiated thyroid cancer and emphasis in salivary morbidity: a follow up study after treatment

To evaluate the impact of iodine-131 therapy received during childhood and adolescence and correlate it with the quality of life in these patients. Methods: We studied 19 patients diagnosed with cancer in childhood or adolescence who underwent thyroidectomy and supplemental therapy with I-131. We also recruited a control group of healthy subjects with the same demographic parameters. All patients were subjected to a scintigraphy examination of the salivary glands, and were also asked to complete a questionnaire in order to assess their overall quality of life. In addition, a more specific questionnaire for patients with head and neck cancer was also given to all study participants. Results: The quantitative and qualitative analyses of the salivary glands showed functional deficits with greater involvement of the parotid gland for volume, concentration and excretion. The right submandibular gland showed significant changes for volume in the patient group. The questionnaires made it possible to observe significant differences between the patient and control groups for symptoms such as thick saliva, dry mouth and speech problems. Conclusion: In spite of being very effective and widely used, iodine radionuclide therapy is correlated with a lower quality of life in young people.

Avaliação do soro de leite como coagulante do látex de borracha natural

Pós-graduação em Ciência dos Materiais - FEIS

Características do aço API X70 utilizado em tubos de transporte de petróleo e gás

Having in mind that petroleum's history presents a huge growth, the exploration and production areas have been receiving lots of investments, in order to attend the increasing demand for gas and petroleum. Looking through that scenario, new technologies have been evolving in favor of discovering new natural petroleum deposits and act with effectiveness in truly deep waters without giving up the worldwide best operational security practices. The use of rigid pipes in marine installations have been rising quickly and, thanks to this reality, the many storage and pipe launching forms became study objects and are getting improved. The analysis of steel API X70 characteristics, proving that they are suitable for use in pipes developed to transport gas and petroleum is the theme of this presentation. A tensile test was conducted to determine the base metal's mechanical properties, draining's tension, traction's resistance, elasticity's modulus and maximum tension. An aspect that is concerning too is the metallographic analysis, in order to determine the studied iron's microstructure. Results of analyzes showed that the steel has high resistance, with good capacity for deformation and well defined yield point, concluding suitable for the application in question

Estudo do efeito Bauschinger em tubos de aço API 5l x70 aplicados no transporte de petróleo e gás

Despite the growing concern in seeking more sustainable energy sources, oil demand is likely to grow in coming years. To keep up with this growth, the oil industry has increasingly invested in innovation and efficiency. Knowing that, new technologies have been developed to explore deeper waters, without giving up the best practices in worldwide operational safety. The use of rigid pipelines in deepwater offshore facilities is increasing quickly and because of this, the ways of storing and launching pipe have been studied and perfected. In this paper the Bauschinger effect on API 5L X70 steel was analyzed proving that there was a reduction in yield strength when an effort was applied in a previous direction, then an effort was then applied in the opposite direction. To observe this phenomenon, the tensile test was conducted to determine the mechanical properties of the base metal, such as yield stress, tensile strength, elasticity and maximum tensile, so then compare it with the results obtained in the Bauschinger Effect Test. The analysis results showed that the steel had high resistance, with good plastic deformation capacity without failing, well-defined yield point, showing itself appropriate for the operation of oil and gas pipes

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs.

Morphology and Deformation Mechanisms and Tensile Properties of Tetrafunctional Multigraft Copolymers

Morphology and deformation mechanisms and tensile properties of tetrafunctional multigraft (MG) polystrene-g-polyisoprene (PS-g-PI) copolymers were investigated dependent on PS volume fraction and number of branch points. The combination of various methods such as TEM, real time synchrotron SAXS, rheo-optical FTIR, and tensile tests provides comprehensive information at different dimension levels.TEMand SAXS studies revealed that the number of branch points has no obvious influence on the microphase-separated morphology of tetrafunction MG copolymers with 16 wt % PS. But for tetrafunctional MG copolymers with 25 wt % PS, the size and integrity of PS microdomains decrease with increasing number of branch point. The deformation mechanisms ofMGcopolymers are highly related to the morphology. Dependent on the microphase-separated morphology and integrity of the PS phase, the strain-induced orientation of the PS phase is at different size scales. Polarized FT-IR spectra analysis reveals that, for all investigated MG copolymers, the PI phase shows strain-induced orientation along SD at molecular scale. The proportion of the PI block effectively bridging PS domains controls the tensile properties of the MGcopolymers at high strain, while the stress-strain behavior in the low-mediate strain region is controlled by the continuity of PS microdomains. The special molecular architecture, which leads to the higher effective functionality of PS domains and the higher possibility for an individual PI backbone being tethered with a large number of PS domains, is proposed to be the origin of the superelasticity for MG copolymers.

Well-Defined Poly(4-vinylbenzocyclobutene): Synthesis by Living Anionic Polymerization and Characterization

Living anionic polymerization of 4-vinylbenzocylobutene was performed in benzene at room temperature using sec-butyllithium as the initiator. Results of the kinetic studies indicated the termination- and transfer-free nature of the polymerization. Homopolymers with predictable molecular weights and narrow molecular weight distributions were produced, excluding the interference of the cyclobutene rings during initiation and propagation. Thermogravimetric analysis of poly(4-vinylbenzocyclobutene) in air showed a small weight gain at ~200 °C, a rapid decomposition at ~455 °C, and a gradual decomposition at ~566 °C. This behavior was attributed to the formation of radicals from the pendent benzocyclobutene functionality through o-quinodimethane intermediates and simultaneous decomposition/cross-linking reactions at high temperature. The living nature of the polymerization was also examined via sequential copolymerization with butadiene to form diblock copolymers.

An Artesian Well System in Beaver Crossing, Nebraska- It's Development and Demise

ABSTRACT Nebraska has a veritable wealth of groundwater. The High Plains Aquifer underlies most of the state, and within its sand and gravel deposits, many interconnected aquifers provide fresh water for a variety of uses. One of the most spectacular examples of this resource is the artesian well. Beaver Crossing, Nebraska was once home to one of the most prolific artesian systems in the state before its demise. Founded in the 1880’s, Beaver Crossing soon became known for its many artesian wells, that provided leisure activities and supported profitable business ventures such as small farming, ice production and aquiculture. Eventually these wells would dry up and the town of Beaver Crossing would never see the level of commerce and activity that it saw during its early years. I decided to research this subject because I lived in Beaver Crossing for twelve years. While I lived there I heard stories about the artesian wells, the nationally recognized lily pond, and the large public pool fed by underground water that was plentiful around town. I was interested in knowing what happened to the water, the wells, the pool and businesses. . . And, in the wake of their disappearance, what happened to the town. To research this topic I looked at accounts of the history of Seward County and Beaver Crossing. I also studied the basic geology underlying the Great Plains, as well as local geology and issues pertaining to groundwater levels, such as rainfall amounts, drought and irrigation. As irrigation became a factor in rural Nebraska and through several documented droughts, groundwater levels all over the state declined. At the same time the artesian system in Beaver Crossing all but disappeared.

Características do aço API X70 utilizado em tubos de transporte de petróleo e gás

Having in mind that petroleum's history presents a huge growth, the exploration and production areas have been receiving lots of investments, in order to attend the increasing demand for gas and petroleum. Looking through that scenario, new technologies have been evolving in favor of discovering new natural petroleum deposits and act with effectiveness in truly deep waters without giving up the worldwide best operational security practices. The use of rigid pipes in marine installations have been rising quickly and, thanks to this reality, the many storage and pipe launching forms became study objects and are getting improved. The analysis of steel API X70 characteristics, proving that they are suitable for use in pipes developed to transport gas and petroleum is the theme of this presentation. A tensile test was conducted to determine the base metal's mechanical properties, draining's tension, traction's resistance, elasticity's modulus and maximum tension. An aspect that is concerning too is the metallographic analysis, in order to determine the studied iron's microstructure. Results of analyzes showed that the steel has high resistance, with good capacity for deformation and well defined yield point, concluding suitable for the application in question

Estudo do efeito Bauschinger em tubos de aço API 5l x70 aplicados no transporte de petróleo e gás

Despite the growing concern in seeking more sustainable energy sources, oil demand is likely to grow in coming years. To keep up with this growth, the oil industry has increasingly invested in innovation and efficiency. Knowing that, new technologies have been developed to explore deeper waters, without giving up the best practices in worldwide operational safety. The use of rigid pipelines in deepwater offshore facilities is increasing quickly and because of this, the ways of storing and launching pipe have been studied and perfected. In this paper the Bauschinger effect on API 5L X70 steel was analyzed proving that there was a reduction in yield strength when an effort was applied in a previous direction, then an effort was then applied in the opposite direction. To observe this phenomenon, the tensile test was conducted to determine the mechanical properties of the base metal, such as yield stress, tensile strength, elasticity and maximum tensile, so then compare it with the results obtained in the Bauschinger Effect Test. The analysis results showed that the steel had high resistance, with good plastic deformation capacity without failing, well-defined yield point, showing itself appropriate for the operation of oil and gas pipes

Plasmodium vivax Duffy binding protein: baseline antibody responses and parasite polymorphisms in a well-consolidated settlement of the Amazon Region

Objective To investigate risk factors associated with the acquisition of antibodies against Plasmodium vivax Duffy binding protein (PvDBP) a leading malaria vaccine candidate in a well-consolidated agricultural settlement of the Brazilian Amazon Region and to determine the sequence diversity of the PvDBP ligand domain (DBPII) within the local malaria parasite population. Methods Demographic, epidemiological and clinical data were collected from 541 volunteers using a structured questionnaire. Malaria parasites were detected by conventional microscopy and PCR, and blood collection was used for antibody assays and molecular characterisation of DBPII. Results The frequency of malaria infection was 7% (6% for P. vivax and 1% for P. falciparum), with malaria cases clustered near mosquito breeding sites. Nearly 50% of settlers had anti-PvDBP IgG antibodies, as detected by enzyme-linked immunosorbent assay (ELISA) with subjects age being the only strong predictor of seropositivity to PvDBP. Unexpectedly, low levels of DBPII diversity were found within the local malaria parasites, suggesting the existence of low gene flow between P. vivax populations, probably due to the relative isolation of the studied settlement. Conclusion The recognition of PvDBP by a significant proportion of the community, associated with low levels of DBPII diversity among local P. vivax, reinforces the variety of malaria transmission patterns in communities from frontier settlements. Such studies should provide baseline information for antimalarial vaccines now in development.

The Effects of Processing Non-Timber Forest Products and Trade Partnerships on People's Well-Being and Forest Conservation in Amazonian Societies

This study evaluated whether processing non-timber forest products (NTFPs) and establishing trade partnerships between forest communities and companies enhance the outcomes of NTFP commercialization. In particular, we evaluated whether product processing, partnerships, or their combination was associated with a number of outcomes related to the well-being of forest inhabitants and forest conservation. We based our analyses on ethnographic and quantitative data (i.e., survey and systematic observations) gathered at seven communities from five societies of the Brazilian and Bolivian Amazon. Our results indicated that product processing and partnerships do not represent a silver bullet able to improve the results of NTFP commercialization in terms of well-being and conservation indicators. Compared with cases without interventions, households adopting partnerships but not product processing were most often associated with improved economic proxies of well-being (total income, NTFP income, food consumption and gender equality in income). In comparison, the combination of product processing and partnerships was associated with similar outcomes. Unexpectedly, product processing alone was associated with negative outcomes in the economic indicators of well-being. All of the investigated strategies were associated with less time spent in social and cultural activities. With respect to forest conservation, the strategies that included a partnership with or without processing produced similar results: while household deforestation tended to decrease, the hunting impact increased. Processing alone was also associated with higher levels of hunting, though it did not reduce deforestation. Our results indicate that establishing partnerships may enhance the outcomes of NTFP trade in terms of the financial outcomes of local communities, but practitioners need to use caution when adopting the processing strategy and they need to evaluate potential negative results for indicators of social and cultural activities. With respect to conservation, the three strategies are promising for reducing deforestation, but more pervasive impacts, such as hunting, might increase.