绿色食品的态势

<正> "绿色食品"系指经"中国绿色食品发展中心"认定,许可使用"绿色食品"标志的无污染、安全、优质、营养类食品。它具有三个显著的特点:1.出自良好的生态环境; 2.有规范的"从土地到餐桌"全程质量控制措施和标准;3.其标志受法律保护,是集社会效益、环境效益和经济效益为一体的产物,赋予极强的时代特征和浓厚的食品文化内涵.1.绿色食品的开发是社会与经济发展的必然产物,有重要的现实意义现代大工业和城市的发展和进

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本文通过人工模拟酸雨试验小区置木招引的研究方法,对马尾松次期性害虫进行了招引试验,并对样木中16种氨基酸含量进行了分析。结果表明,马尾松样木在人工模拟酸雨条件下比对照都易招次期性害虫的入侵,样木中氨基酸含量也比对照高。但在强酸(pH=2)条件下其氨基酸含量比对照低,其原因还有待进一步探讨。

森林流域洪涝灾害成因分析与防治对策

森林流域洪涝灾害成因分析与防治对策孙铁珩，裴铁璠张吉娜（中国科学院沈阳应用生态研究所）（辽宁省生态学会）本文所述的森林流域是广义的，系指我国典型敏感带以东广大地区。典型敏感带始于东北西部内蒙东部向西南一直延伸到青藏高原东南部。它是干旱、半干旱与湿润、...

携带叠氮和氨侧基的脂肪族聚酯的合成和表征

含有功能侧基生物降解聚合物的制备在近几年中受到广大研究者的极大关注[1,2].目前已经通过环状碳酸酯与丙交酯(LA)和ε-己内酯(CL)等共聚的方法合成了带有羧基[3~5]和羟基[6,7]等的脂肪族聚酯,并在靶向载体、药物控释及组织工程方面得到了应用[2,8].但有关含侧链氨基的聚合物研究的报道很少,且主要集中在氨基酸NCA单体与LA的嵌段共聚方面[9,10],很少得到侧链氨基的无规共聚物.本文通过丙交酯(LA)与环状碳酸酯单体共聚的方法制备了一种侧链带有溴原子的脂肪族聚酯,并将溴原子用叠氮基团取代,通过Cu(Ⅰ)催化的Click反应将其氨基化,得到了侧链带有氨基的脂肪族聚酯.

Poly(L-lysine)-graft-chitosan copolymers: Synthesis, characterization, and gene transfection effect

Polypeptide/polysaccharide graft copolymers poly(L-lysine)-graft-chitosan (PLL-g-Chi) were prepared by ring-opening polymerization (ROP) of epsilon-benzoxycarbonyl L-lysine N-carboxyanhydrides (Z-L-lysine NCA) in the presence of 6-O-triphenylmethyl chitosan. The PLL-g-Chi copolymers were thoroughly characterized by H-1 NMR, C-13 NMR, Fourier transform infrared (FT-IR), and gel permeation chromatography (GPC). The number-average degree of polymerization of PLL grafted onto the chitosan backbone could be adjusted by controlling the feed ratio of NCA to 6-O-triphenylmethyl chitosan. The particle size of the complexes formed from the copolymer and calf thymus DNA was measured by dynamic light scattering (DLS). It was found in the range of 120 similar to 340 nm. The gel retardation electrophoresis showed that the PLL-g-Chi copolymers possessed better plasmid DNA-binding ability than chitosan. The gene transfection effect in HEK 293T cells of the copolymers was evaluated, and the results showed that the gene transfection ability of the copolymer was better than that of chitosan and was dependent on the PLL grafting ratio. The PLL-g-Chi copolymers could be used as effective gene delivery vectors.

金属离子对鞘磷脂脂双层极性头构象的影响

稀土毒理学以及稀土离子作为钙离子的探针的研究受到普遍关注,人们对稀土离子的生物化学性质进行了广泛研究.作者曾报到了金属离子对DPPC脂质体的极性头构象的影响.鞘磷脂是神经组织细胞膜的重要磷脂组分,和DPPC有相似的极性头.本文利用核磁共振结合Raman光谱研究了金属离子对鞘磷脂脂双层的极性头构象的影响.1 材料和方法

CHEMICAL-IONIZATION MASS-SPECTROMETRY OF BENZOYL PEROXIDE - A RADICAL AROMATIC-SUBSTITUTION RESULTING IN BIPHENYLCARBOXYLIC ACID IN THE GAS-PHASE

A radical aromatic substitution resulting in biphenylcarboxylic acid is inferred for the decomposition of benzoyl peroxide from the chemical ionization and collision-induced dissociation mass spectra. The thermolysis of benzoyl peroxide gives rise to a benzoyloxy radical, which undergoes rapid decarboxylation and hydrogen abstraction leading to phenyl radical and benzoic acid, respectively. Attack of the resulting phenyl radical on the benzoic acid results in bipbenylcarboxylic acid. On the other hand, the phenyl radical abstracts a hydrogen atom to yield benzene, which is then subjected to the attack of a benzoyloxy radical, affording phenyl benzoate. This substitution reaction rather than the recombination of benzoyloxy and phenyl radicals is found to be responsible for the formation of phenyl benzoate under the present conditions.