Estudo de compostos orgânicos em lixiviado de aterros sanitários por EFS e CG/EM

The main purpose of this work was the qualitative study of organic compounds in landfill leachate. The samples were collected from a sanitary landfill located at Gravataí, a southern Brazilian city, that receive both, industrial and domestic refuse. The samples were submitted to solid phase extraction (SPE) with XAD-4 resin as the stationary phase. The instrumental analysis was performed by Gas Chromatography with a Mass Spectrometry Detector (GC/MSD). The compounds achieved in the SPE extracts were tentatively identified by the GC/MS library. It was found several oxygen and nitrogen compounds like carboxylic acids, ketones, amines and amides. Sulfur compounds and phthalate esters are also identified.

Extração por fluido supercrítico de alguns inseticidas carbamatos em amostras de batata, com determinação por HPLC/fluorescência e confirmação por HPLC/espectrometria de massas

Six supercritical fluid extraction (SFE) methods were tested, by varying the following operational parameters: CO2 pressure, time and temperature of extraction, type and proportion of static modifier, and Hydromatrix®/sample rate into cell. Firstly, insecticide carbamates were extracted from spiked potatoes samples (fortification level of 0,5 mg.Kg-1) by using SPE procedures, and then final extracts were analyzed HPLC/fluorescence. Good performance was observed with SFE methods that operated with values of temperature and CO2 pressure of 50 ºC and 350 bar, respectively. Best efficiency was obtained when it was used acetonitrile as a modifier (3% on the cell volume), and Hydromatrix®/sample rate of 2:1. Static time was of 1 min; total extraction time was of 35 min; dynamic extraction was performed with 15 mL of CO2, and it was used methanol (2 mL) for the dissolution of the final residue. In such conditions, pesticide recoveries varied from 72 to 94%, depending on the analyzed compound. In higher extraction temperatures, a rapid degradation was observed for some compounds, such as aldicarb and carbaryl; presence of their metabolites was further confirmed by HPLC-APCI/MS in positive mode. Detection limits for chromatographic analysis varied from 0,2 to 1,3 ng.

Encuadernaciones Mudéjares de la Biblioteca de Alfonso el Magnánimo: Ms. 574 y 576 Biblioteca de la Universitat de Barcelona

This work expect to prove relations between the bookbinding of two manuscripts conserved in the Library of the University of Barcelona and the bookbinding to realise in the workshop of bookbinding of the Library of Alfonso el Magnanimous in this court Neapolitan, across over the study of this elements and architecture, and give the denomination of bookbinding mudejar neapolitan, because they are to make in this workshop or in this defect in Italy in the middle of the XV century.

Os primeiros desenvolvimentos do conceito helmontiano de gás: parte II

This paper focuses on the early interpretations of the concept of gas, originally created by J. B. Van Helmont (1579 ¾ 1644). Our main interest is on the ideas of English physicians and chemical philosophers of the seventeenth century. Gas was usually associated with the material cause of diseases, with the vital spirit, or with a volatile spirit produced in some kinds of material transformations. As a general trend, however, the authors who did not want to embrace the details of the medico-chemical system proposed by Van Helmont preferred to use more well-known words (such as vapours, exhalations, effluvia, odours, spirits), avoiding the use of the neologism.

El lado más oscuro de la modernidad occidental

Ressenya de: Walter D. Mignolo, The Darker Side of Western Modernity. Global Futures, Decolonial Options. Duke University Press 2011.

Sistema de alimentação gás-líquido para medidas de atividade catalítica

This note has as objective to present the advantages of the use of syringe-type pumps for the feeding of liquid reactants, together with mass flow controllers for gases, instead of the saturators, as it is generally accomplished. Among the advantages, the system with syringe pumps presents a greater flexibility in flow control as well as in composition compared with the system that uses saturator. In addition, the flow of the liquid reactants is known with precision in the syringe pump system.

Doctors més enllà de la Universitat i els centres de recerca

Les causes d'aquest desajust no només estan a la Universitat i l'empresa, també l'administració hi té la seva part de responsabilitat. La Universitat i l'empresa s'han de conèixer, saber que fa cadascuna i col·laborar, però l'administració ha de propiciar i fomentar-ne la relació i això només es pot fer coneixent quins són els dèficits estructurals que ho dificulten i crear un marc i condicions per eliminar-los o, si més no, reduir-los. Una altra variable explicativa de la mala situació de la competitivitat és la nostra relativa poca producció de doctors respecte a d'altres països del nostre entorn que són més competitius

La universitat funciona més bé que la política i l'empresa

La universitat catalana actual, deixant de banda els econòmics, té dos problemes. Un és la lentitud a adaptar-se i respondre a les demandes ciutadanes. El segon és la manca d'un sistema ben definit i sistemàtic de retiment de comptes a la societat. Resolts ambdós problemes, la universitat faria en poc temps un gran canvi per bé. La resposta a aquests problemes pot donar-se amb petites modificacions de la norma externa i algunes de més profundes en la interna que aportin més flexibilitat i autonomia

Extração de esteróides em frutos de Ottonia martiana Miq., Piperaceae, com gás liqüefeito

A new extraction method for sterols was tested in fruits of Ottonia martiana Miq., a shrub belonging to the family Piperaceae, popularly known as "anestésica" due to the use of its roots and aerial parts, in alcoholic preparations, in treatment of odontological problems. For this purpose, a portable extraction equipment was developed, to operate with liquified gases, which showed to be practical, fast and effective, besides being economical and ecological. In the chromatographic analysis of the extracts obtained in this equipment, it was demonstrated the presence of two sterols, isomers of b-sitosterol and stigmasterol.

Achillea filipendulina Lam. nueva para Andalucía, más algunas observaciones sobre las Achillea andaluzas.

La preparación de la síntesis de Achillea L. para Flora Iberica ha llevado a examinar algunas cuestiones críticas en relación con la flora de Andalucía oriental (Blanca, 2011). Para ello, se ha revisado la información bibliográfica disponible, así como los materiales de herbario de referencia; se ha contado asimismo con la colaboración del autor de la síntesis de dicha obra. Como resultado, se plantea la adición al catálogo de la flora andaluza de una nueva especie alóctona, Achillea filipendulina Lam., así como la exclusión de A. ligustica All., a la que se habían atribuido inicialmente algunos ejemplares de A. millefolium [...].

Análise de praguicidas organofosforados em água por extração em fase sólida (SPE) utilizando discos C18 e cromatografia em fase gasosa: avaliação da contaminação do reservatório de Furnas (MG-Brasil)

Solid phase extraction (SPE) in C18 disks has been optimized and validated for extraction of 5 organophosphorus (OP) pesticides in water. Extraction has been followed by separation and detection by gas chromatography/flame photometry. Excellent linearity was obtained for all compounds (r greater than 0.99), with CVs between 1.0-6.9%, recoveries between 73-95% and quantification limits between 2.5-5.0 µg L-1. Samples from Furnas dam were analyzed monthly during one year and 10% showed OP pesticide residues.

Estudo do nitrogênio na combustão do gás natural

Nitrogen content in natural gas was studied in experimental and computational investigations to identify its influence on the emission level of exhaust gases from combustion facilities. Changes in natural gas composition with different N2 concentrations may result from introducing a new source gas into the system. An industrial burner fired at 75 kW, housed in a laboratory-scale furnace, was employed for runs where the natural gas/N2 proportion was varied. The exhaust and in-furnace measurements of temperature and gas concentrations were performed for different combustion scenarios, varying N2 content from 1-10 %v. Results have shown that the contamination of natural gas with nitrogen reduced the peak flame temperature, the concentration of unstable species, the NO X emission level and the heat transfer rate to the furnace walls, resulting from the recombination reactions.

El secret del càncer més resistent

En la lluita contra el càncer, la recerca de nous fàrmacs cada cop més efectius i específics sovint troba un escull important: en molts tumors hi ha una petita fracció de cèl·lules resistents, que no es poden eliminar fàcilment. Tanmateix, el principal problema no és aquest, sinó que, a més, acostumen a respondre als fàrmacs incrementant la taxa de proliferació i la capacitat de fer metàstasi. Això fa que alguns tractaments no acabin de ser del tot efectius a llarg termini, per la presència cada cop més nombrosa i dispersa d'aquestes cèl·lules canceroses resistents. L'equip de recerca de Joan Massagué, al Memorial Sloan Kettering Cancer Center de Nova York, ha demostrat que aquest efecte a llarg termini induït pels mateixos fàrmacs és perquè les cèl·lules sensibles, abans de morir, preparen un ambient molt favorable per a les resistents.

Síntese e caracterização de perovskitas LaNi(1-x)Co xO3 como precursores de catalisadores para a conversão do metano a gás de síntese pela reforma com CO2

LaNiO3 perovskite was modified by partial substitution of nickel by cobalt in order to increase the stability and resistance to carbon deposition during the methane CO2 reforming. The results showed that a suitable combination of precipitation and calcination steps resulted in oxides with the desired structure and with important properties for application in heterogeneous catalysis. The partial substitution of Ni by Co resulted in lower rates of conversion of both the reactants, but the catalyst stability was highly increased. The LaNi0.3Co0.7O3 catalyst, calcined at 800 ºC, was the most active under the reaction conditions.

Més enllà de la necessitat de treballar existeix el desig d'estar en relació en llibertat = Más allá de la necesidad de trabajar existe el deseo de estar en relación en libertad

En el monografic que presentem, hi publiquem les ponencies sorgides del seminari de primavera, que, com cada any, organitzem les dones de Duoda. El seminari portava el títol Les relacions d'autoritat i de llibertat en el mercat de treball. Desitjavem donar a conèixer el pensament i els sabers de les dones fruit de la recerca de dotar de sentit la seva experiència femenina en el món del treball, des de la consciencia del que aportem les dones al món amb la nostra diferencia sexual